Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics

Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime

(2019) Rasha Hamze et al.   SCIENCE

Carborane-Induced Excimer Emission of Severely Twisted Bis-o -Carboranyl Chrysene

(2018) Adam V. Marsh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

(2018) Kang Zhang et al.   CHEMICAL COMMUNICATIONS

Atomically precise copper nanoclusters and their applications

(2018) Xiang Liu et al.   COORDINATION CHEMISTRY REVIEWS

Isolation of an acetylide-Cu I 3 -tris(triazolylmethyl)amine complex active in the CuAAC reaction

(2018) Haoqing Chen et al.   JOURNAL OF CATALYSIS

A Tetradecanuclear Organometallic Copper(I)-Alkynide Cluster: Synthesis, Crystal Structure, and Luminescent Property

(2018) Hong-Yan Zhuo et al.   JOURNAL OF CLUSTER SCIENCE

Photoinduced Electron Transfer in a BODIPY-ortho-Carborane Dyad Investigated by Time-Resolved Transient Absorption Spectroscopy

(2018) So-Yoen Kim et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Dinuclear Ag(I) Complex Designed for Highly Efficient Thermally Activated Delayed Fluorescence

(2018) Marsel Z. Shafikov et al.   Journal of Physical Chemistry Letters

Dual emission via remote control of molecular rotation of o-carborane in the excited state by the distant substituents in tolane-modified dyads

(2018) Kenta Nishino et al.   NEW JOURNAL OF CHEMISTRY

Cage carbon-substitute does matter for aggregation-induced emission features of o-carborane-functionalized anthracene triads

(2018) Xueyan Wu et al.   Journal of Materials Chemistry C

Stimuli-responsive solid-state emission from o-carborane–tetraphenylethene dyads induced by twisted intramolecular charge transfer in the crystalline state

(2018) Junfeng Li et al.   Journal of Materials Chemistry C

Structurally Precise Dichalcogenolate-Protected Copper and Silver Superatomic Nanoclusters and Their Alloys

(2018) Sachil Sharma et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

(2018) Furong Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

(2018) Kent O. Kirlikovali et al.   ORGANOMETALLICS

Thermally Activated Delayed Fluorescence from Ag(I) Complexes: A Route to 100% Quantum Yield at Unprecedentedly Short Decay Time

(2017) Marsel Z. Shafikov et al.   INORGANIC CHEMISTRY

Gold(I) Alkynyls Supported by Mono- and Bidentate NHC Ligands: Luminescence and Isolation of Unprecedented Ionic Complexes

(2017) Alexander A. Penney et al.   INORGANIC CHEMISTRY

Cationic Copper Hydride Clusters Arising from Oxidation of (Ph3P)6Cu6H6

(2017) Shuo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atomically Precise Bimetallic Au19Cu30 Nanocluster with an Icosidodecahedral Cu30 Shell and an Alkynyl–Cu Interface

(2017) Xian-Kai Wan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition

(2017) Micah S. Ziegler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry

(2017) Andrew W. Cook et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deboronation-Induced Turn-on Phosphorescent Sensing of Fluorides by Iridium(III) Cyclometalates with o-Carborane

(2017) Nguyen Van Nghia et al.   ORGANOMETALLICS

Biphenyl- and Fluorene-Based o-Carboranyl Compounds: Alteration of Photophysical Properties by Distortion of Biphenyl Rings

(2017) Nara Shin et al.   ORGANOMETALLICS

Direct observation of the photoinduced electron transfer processes of bis(4-arylphenylamino benzo)-ortho-carborane using transient absorption spectroscopic measurements

(2017) Mi Rang Son et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Using highly emissive and environmentally sensitive o-carborane-functionalized metallophosphors to monitor mitochondrial polarity

(2017) Xiang Li et al.   Chemical Science

Fluorescent carborane–vinylstilbene functionalised octasilsesquioxanes: synthesis, structural, thermal and photophysical properties

(2017) Justo Cabrera-González et al.   Journal of Materials Chemistry C

Synthesis, optical properties and applications of light-emitting copper nanoclusters

(2017) Zhenguang Wang et al.   Nanoscale Horizons

Unprecedented Efficient Structure Controlled Phosphorescence of Silver(I) Clusters Stabilized by Carba-closo -dodecaboranylethynyl Ligands

(2016) Michael Hailmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solid-State Emission of the Anthracene-o -Carborane Dyad from the Twisted-Intramolecular Charge Transfer in the Crystalline State

(2016) Hirofumi Naito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Bis(silylene)-Substituted ortho -Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes

(2016) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tethered N-heterocyclic carbene–carboranes: unique ligands that exhibit unprecedented and versatile coordination modes at rhodium

(2016) Jordan Holmes et al.   CHEMICAL COMMUNICATIONS

Boron clusters in luminescent materials

(2016) Sanjoy Mukherjee et al.   CHEMICAL COMMUNICATIONS

Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

(2016) Rosario Núñez et al.   CHEMICAL REVIEWS

Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis

(2016) Manoj B. Gawande et al.   CHEMICAL REVIEWS

High-Nuclear Organometallic Copper(I)-Alkynide Clusters: Thermochromic Near-Infrared Luminescence and Solution Stability

(2016) Hong-Yan Zhuo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unprecedented flexibility of the 1,1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀Ru interactions

(2016) Laura E. Riley et al.   DALTON TRANSACTIONS

Anionic and zwitterionic carboranyl N-heterocyclic carbene Au(i) complexes

(2016) Steven P. Fisher et al.   DALTON TRANSACTIONS

Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]

(2016) Andrew W. Cook et al.   INORGANIC CHEMISTRY

Synthesis, Structural Characterization, and Gas-Phase Unimolecular Reactivity of Bis(diphenylphosphino)amino Copper Hydride Nanoclusters [Cu3(X)(μ3-H)((PPh2)2NH)3](BF4), Where X = μ2-Cl and μ3-BH4

(2016) Jiaye Li et al.   INORGANIC CHEMISTRY

C2-Symmetric P,N Ligands Derived from Carborane-Based Diphosphetanes: Synthesis and Coordination Chemistry

(2016) Peter Coburger et al.   INORGANIC CHEMISTRY

Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters

(2016) Li-Min Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands

(2016) Jonathan C. Axtell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low-Nuclearity Alkynyl d10 Clusters Supported by Chelating Multidentate Phosphines

(2016) Andrey Belyaev et al.   ORGANOMETALLICS

Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling

(2016) Allen L. Chan et al.   ORGANOMETALLICS

Blue-shifted emission and enhanced quantum efficiency via π-bridge elongation in carbazole–carborane dyads

(2016) Zhaojin Wang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Polyhydrido Copper Clusters: Synthetic Advances, Structural Diversity, and Nanocluster-to-Nanoparticle Conversion

(2015) Rajendra S. Dhayal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes

(2015) Vivian Wing-Wah Yam et al.   CHEMICAL REVIEWS

Metal nanoclusters: novel probes for diagnostic and therapeutic applications

(2015) Yu Tao et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and Characterization of a Cu14Hydride Cluster Supported by Neutral Donor Ligands

(2015) Thuy-Ai D. Nguyen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboranes as a Tool to Tune Phosphorescence

(2015) Xiang Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboranes in the chemist's toolbox

(2015) Russell N. Grimes   DALTON TRANSACTIONS

A Cu25 Nanocluster with Partial Cu(0) Character

(2015) Thuy-Ai D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction"

(2015) L. Jin et al.   Science Advances

Fusing N-Heterocyclic Carbenes with Carborane Anions

(2014) Ahmad El-Hellani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Characterization of the Hydrides in Stryker’s Reagent: [HCu{P(C6H5)3}]6

(2014) Elliot L. Bennett et al.   INORGANIC CHEMISTRY

Polymorphic Copper Iodide Clusters: Insights into the Mechanochromic Luminescence Properties

(2014) Quentin Benito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal nanoclusters: New fluorescent probes for sensors and bioimaging

(2014) Libing Zhang et al.   Nano Today

Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis

(2013) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Update 1 of: Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

(2013) Christos Douvris et al.   CHEMICAL REVIEWS

Transition metal complexes based on carboranyl ligands containing N, P, and S donors: Synthesis, reactivity and applications

(2013) Zi-Jian Yao et al.   COORDINATION CHEMISTRY REVIEWS

A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H2 from Solar Energy

(2013) Rajendra S. Dhayal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Evidence of a Dinuclear Copper Intermediate in Cu(I)-Catalyzed Azide-Alkyne Cycloadditions

(2013) B. T. Worrell et al.   SCIENCE

Modulation of Metallophilic Bonds: Solvent-Induced Isomerization and Luminescence Vapochromism of a Polymorphic Au–Cu Cluster

(2012) Igor O. Koshevoy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I) Alkyne and Alkynide Complexes

(2012) Heinrich Lang et al.   ORGANOMETALLICS

Tetrahedral Gold(I) Clusters with Carba-closo-dodecaboranylethynido Ligands: [{12-(R3PAu)2CC-closo-1-CB11H11}2]

(2011) Alexander Himmelspach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

(2011) Gereon M. Yee et al.   CHEMICAL COMMUNICATIONS

Intramolecular d10–d10 interactions in heterometallic clusters of the transition metals

(2011) Sabrina Sculfort et al.   CHEMICAL SOCIETY REVIEWS

A coordination chemistry dichotomy for icosahedral carborane-based ligands

(2011) Alexander M. Spokoyny et al.   Nature Chemistry

Structural Characterization and Luminescence Properties of a Triphosphine-Stabilized Ag16Cu9 Heterometallic Alkynyl Cluster

(2011) Zhong-Hui Chen et al.   ORGANOMETALLICS

Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(i) acetylides

(2010) Jason E. Hein et al.   CHEMICAL SOCIETY REVIEWS

Homoleptic transition metal acetylides

(2010) Roy Buschbeck et al.   COORDINATION CHEMISTRY REVIEWS

H+, CH3+, and R3Si+Carborane Reagents: When Triflates Fail

(2009) Christopher A. Reed   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Dinitrogen and Acetylide Complexes of Low-Valent Chromium

(2008) Louise A. Berben et al.   INORGANIC CHEMISTRY