Article
Chemistry, Physical
Xu Guo, Xing Liu, Junqing Yan, Shengzhong (Frank) Liu
Summary: In this study, colloidal ZnO/CdS heterostructure catalysts were successfully obtained using a two-step heteroepitaxial growth strategy. By optimizing the molar ratio of the ZnO and CdS components, the catalyst exhibited a high hydrogen generation rate and excellent photocatalytic stability. The nanoscale ZnO/CdS heterostructure showed superior photocatalytic performance compared to bulk ZnO/CdS heterostructures.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Environmental
Guotai Sun, Jian-Wen Shi, Siman Mao, Dandan Ma, Chi He, Hongkang Wang, Yonghong Cheng
Summary: A new photocatalyst, tri-arm CdS/ZnS core-shell nanorod, shows significantly enhanced photocatalytic performance with improved quantum efficiency and hydrogen evolution rate. This enhancement is attributed to the win-win situation between the CdS/ZnS heterojunction and the H+ adsorption resulting from DDA molecules.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Zige Tai, Guotai Sun, Ting Wang, Zhiyu Fang, Xiaoxiong Hou, Fan Li, Yuqian Qiu, Qian Ye, Lichao Jia, Hongqiang Wang
Summary: By heterostructuring 1D CdS with defective WS2, an efficient strategy is demonstrated to enhance interfacial carrier separation and transfer, leading to high-yield hydrogen production. The optimized sample exhibits a high photocatalytic H2 evolution rate, among the top records for CdS-based photocatalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Engineering, Environmental
Zhanfen Chen, Jiaqi Pan, Jie Mei, Qi Yu, Panhong Wang, Peipei Wang, Jingjing Wang, Changsheng Song, Yingying Zheng, Chaorong Li
Summary: A ternary Co3O4/CdS/SrTiO3 core-shell pn junction is fabricated by depositing a CdS shell on the surface of a SrTiO3 nanosphere, followed by growing p-type Co3O4 lamellas on the CdS/SrTiO3 core-shell heterojunction surface. The resulting structure shows a 15-fold enhancement in hydrogen evolution ability compared to single SrTiO3 nanospheres, attributed to the narrow band gaps of CdS and Co3O4 increasing visible light response and efficient charge carrier transfer into water. Additionally, the core-shell structure provides active sites and shortens the photoelectron transport path to improve photocatalytic stability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Nanoscience & Nanotechnology
Kazi M. Alam, Charles E. Jensen, Pawan Kumar, Riley W. Hooper, Guy M. Bernard, Aakash Patidar, Ajay P. Manuel, Naaman Amer, Anders Palmgren, David N. Purschke, Narendra Chaulagain, John Garcia, Phillip S. Kirwin, Lian C. T. Shoute, Kai Cui, Sergey Gusarov, Alexander E. Kobryn, Vladimir K. Michaelis, Frank A. Hegmann, Karthik Shankar
Summary: A potential solution to the extraction of photogenerated holes from CdS nanocrystals and nanowires was presented by constructing CdS-C3N5 heterostructures, which improved photocatalytic degradation and photocatalytic decolorization performance while providing control over the reaction pathways.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Chemical
Xiangbo Feng, Lvwei Sun, Wei Wang, Yuzhen Zhao, Jian-Wen Shi
Summary: A new CdS@ZnO core-shell nanorod array was successfully constructed by atomic layer deposition (ALD) for efficient H2 evolution from photoelectrochemical water splitting. The CdS@ZnO200 obtained after 200 ALD cycles showed a significantly enhanced PEC H2 evolution rate of 21.64 μmol·h-1·cm-2, which was about 9.4 times higher than pristine CdS NRAs. The improved performance could be attributed to the Z-scheme charge transfer mechanism between CdS core and ZnO shell, as well as the reduction of charge carrier transfer resistance due to the close contact between the two semiconductors.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Na Jin, Yonglei Sun, Wenwu Shi, Ping Wang, Yasutaka Nagaoka, Tong Cai, Rongzhen Wu, Lacie Dube, Hawi N. Nyiera, Yuzi Liu, Tomoyasu Mani, Xinzhong Wang, Jing Zhao, Ou Chen
Summary: The decoration of Au satellite-type domains on the surface of CdS/ZnS quantum dots effectively overcomes the energy barrier and improves the photocatalytic reaction rate by over 400 fold. Transient absorption spectroscopy studies showed that charges can be efficiently extracted and transferred to surrounding molecular substrates in a subpicosecond time scale in such hybrid nanocrystals.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Engineering, Electrical & Electronic
Hui Liang, Junwei Mei, Han Sun, Lixin Cao
Summary: CdS@CuS core-shell nanorods constructed via cation exchange method exhibited remarkable photocatalytic activity for hydrogen evolution under visible light, with a rate 8.3 times higher than that of pristine CdS.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2023)
Article
Chemistry, Physical
Lili Deng, Ningjie Fang, Shilin Wu, Song Shu, Yinghao Chu, Jiaxiu Guo, Wanglai Cen
Summary: This study successfully prepared a highly efficient and cost-effective photocatalyst system by constructing NiCoP core-shell structure on the surface of hollow CdS. The results demonstrated that NiCoP acted as an excellent co-catalyst, promoting the photocatalytic activity and stability of H-CdS.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Qi Hu, Jiantao Niu, Ke-Qin Zhang, Mu Yao
Summary: This study enhances the hydrogen production in photocatalytic reactions by constructing SrTiO3/CdS heterojunctions. The loading of CdS nanospheres enhances the visible light absorption capacity of the composite catalyst, promotes rapid carrier separation and migration, and significantly improves the photocatalytic activity.
Article
Chemistry, Physical
Lixin Que, Lei Lu, Yunlong Xu, Xiaoqing Xu, Hui Li, Jun Cao, Mei Zhu, Chaorong Li, Jiaqi Pan
Summary: The ZnIn2S4/CdS hollow core-shell nanoheterostructure with bimetallic synergism was successfully synthesized using a hybrid chemical method. The ZnIn2S4/CdS hollow core-shell nanoheterostructure exhibited remarkable visible light photocatalytic hydrogen evolution performance, achieving a hydrogen evolution rate of -5209.43 mmol center dot g-1 center dot h-1 and an AQE of -20.26%. It also demonstrated good photocatalytic stability with an average hydrogen evolution rate of -5056.80 mmol center dot g-1 center dot h-1.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Materials Science, Multidisciplinary
Weijie Zhang, Xizhong Zhou, Jinzhao Huang, Shouwei Zhang, Xijin Xu
Summary: In this study, a new and efficient Z-scheme CdS/FePc core-shell nanostructure composite material was prepared, which showed improved performance as a photocatalyst. The composite material exhibited enhanced photocatalytic hydrogen evolution activity and cycling stability, attributed to the formation of a Z-scheme heterojunction, the light absorption capability of FePc, and the large core-shell contact area.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Benteng Sun, Pengyuan Qiu, Zhangqian Liang, Yanjun Xue, Xiaoli Zhang, Lei Yang, Hongzhi Cui, Jian Tian
Summary: The study prepared unique 1D/2D CdS nanorod@Ti3C2 MXene composites photocatalysts, achieving suitable band structure and superior electronic reduction capability of CdS to enhance photocatalytic performance. Ti3C2 MXene NSs with good electronic transfer capability prevented carrier recombination, while the multilayer structure provided more reactive sites. The CdS@Ti3C2-15 composite showed excellent photocatalytic performance, with higher AQE and long-term stability.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Zhe Zhang, Fanhao Kong, Bizhen Yuan, Yinnian Liao, Xiue Ren, Yu Hou
Summary: In this study, CdO decorated CdS nanorods were prepared for visible light driven CO2 reduction. The introduction of CdO enhanced the separation and transfer of photoinduced charge carriers and acted as an active site for adsorption and activation of CO2 molecules. Compared to pristine CdS, CdO/CdS exhibited a nearly 5-fold higher CO generation rate. This research highlights the pivotal effect of CdO on photogenerated carrier transfer and CO2 adsorption in photocatalysis, providing a facile way to enhance photocatalytic efficiency.
Article
Chemistry, Multidisciplinary
Wei Li, Jiayuan Li, Tenghao Ma, Guocheng Liao, Fanfan Gao, Wen Duan, Keling Luo, Chuanyi Wang
Summary: The formation of a uniform mesoporous CdS shell on the surface of Sb2S3 nanorods (NRs) via a surface cationic displacement strategy constructs the core-shell Sb2S3@CdS heterojunction with high BET surface area and excellent near-infrared light harvesting capacity. The Sb-S-Cd bonding interaction and van der Waals force significantly enhance the stability and synergy of Sb2S3/CdS heterointerface throughout the entire surface of Sb2S3 NRs, promoting the Sb2S3-to-CdS electron transfer due to the formation of built-in electric field. Therefore, the optimized Sb2S3@CdS catalyst achieves highly enhanced simulated sunlight-driven Cr(VI) reduction and decomplexation of complexed Cr(III), resulting in effective chromium-containing wastewater treatment.
Article
Materials Science, Multidisciplinary
Longzhu Li, Honglei Zhang, Changhai Liu, Penghua Liang, Naotoshi Mitsuzaki, Zhidong Chen
JOURNAL OF MATERIALS SCIENCE
(2019)
Article
Engineering, Environmental
Changhai Liu, Yu Xu, Heng Luo, Wenchang Wang, Qian Liang, Zhidong Chen
CHEMICAL ENGINEERING JOURNAL
(2019)
Article
Engineering, Electrical & Electronic
Ke Wang, Changhai Liu, Wenchang Wang, Naotoshi Mitsuzaki, Zhidong Chen
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Article
Chemistry, Physical
Changhai Liu, Yangyang Qiu, Jin Zhang, Qian Liang, Naotoshi Mitsuzaki, Zhidong Chen
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2019)
Article
Chemistry, Physical
Longzhu Li, Penghua Liang, Changhai Liu, Honglei Zhang, Naotoshi Mitsuzaki, Zhidong Chen
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Engineering, Electrical & Electronic
Changhai Liu, Yu Xu, Heng Luo, Chao Zhang, Wenchang Wang, Zhidong Chen
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Article
Engineering, Environmental
Changhai Liu, Heng Luo, Yu Xu, Zhihui Zhang, Qian Liang, Wenchang Wang, Zhidong Chen
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Chemistry, Physical
Changhai Liu, Lili Zhang, Lei Sun, Wenchang Wang, Zhidong Chen
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Engineering, Environmental
Qian Liang, Wen Gao, Changhai Liu, Song Xu, Zhongyu Li
JOURNAL OF HAZARDOUS MATERIALS
(2020)
Article
Engineering, Electrical & Electronic
Changhai Liu, Tingting Zhang, Dengxiaojiang Zhao, Chao Zhang, Guofu Ou, Haozhe Jin, Zhidong Chen
Summary: A novel strategy of constructing an amorphous nickel-borate thin layer on Ti-doped α-Fe2O3 photoanode was developed to significantly enhance the water oxidation kinetics and improve the photocurrent density, showing potential for practical photoelectrochemical applications.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Nanoscience & Nanotechnology
Changhai Liu, Chao Zhang, Ge Yin, Tingting Zhang, Wenchang Wang, Guofu Ou, Haozhe Jin, Zhidong Chen
Summary: A novel strategy was developed to construct a 3D branched TiO2 photoanode with an ultrathin Al2O3 passivation layer and NiOOH cocatalyst for photoelectrochemical water splitting, showing improved light absorption ability and enhanced stability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Changhai Liu, Lei Sun, Linlin Luo, Wenchang Wang, Huilong Dong, Zhidong Chen
Summary: A facile method for preparing molybdenum carbide on nitrogen-doped carbon has been developed, resulting in Ni-0.5@MoCx/NC with superior HER performance and stability. Theoretical simulation confirmed the mechanism behind its excellent activity.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Inorganic & Nuclear
Tingting Zhang, Changhai Liu, Shishi Zhu, Chao Zhang, Xiaohui Chen, Zhidong Chen
Summary: Hydrogen production through photoelectrochemical water splitting process has attracted attention for its carbon-free and economically sustainable features. The designed CdS/Au/TNRs photoanode demonstrates high photocurrent density and negatively shifted onset potential, with CdS and Au effectively enhancing charge separation and carrier transport conductivity. This work may pave the way for designing better functional materials.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Dingwei Ji, Changhai Liu, Yanhua Yao, Linlin Luo, Wenchang Wang, Zhidong Chen
Summary: Perovskite oxides, specifically Ce-doped LaCoO3, synthesized using microwave/ultrasound-assisted hydrothermal methods, exhibit efficient catalytic performance in oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The excellent electrocatalytic activity and long-term durability in alkaline conditions are attributed to the synergistic effects of excellent conductivity and enriched active sites resulting from A-site substitution.
Article
Nanoscience & Nanotechnology
Changhai Liu, Chao Zhang, Dingwei Ji, Ge Yin, Wenchang Wang, Zhidong Chen
ACS APPLIED NANO MATERIALS
(2020)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)