4.7 Article Proceedings Paper

Depth profiling and photometric characteristics of Pr3+ doped BaMoO4 thin phosphor films grown using (266 nm Nd-YAG laser) pulsed laser deposition

Journal

APPLIED SURFACE SCIENCE
Volume 488, Issue -, Pages 783-790

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2019.05.258

Keywords

PLD; XPS; Crystal structure; Depth profiling; Phosphors; BaMoO4:Pr3+

Funding

  1. South African Research Chairs Initiative of the Department of Science and Technology [84415]

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Pr3+ doped BaMoO4 nano thin films have been deposited by pulsed laser deposition on a glass substrate using a Nd-YAG laser (lambda = 266 nm). The thin phosphor films were deposited in an ultra-high vacuum at a substrate temperature of 400 degrees C at different oxygen partial pressures. The crystal structure, surface morphology, film thickness and composition were examined by X-ray diffraction patterns, scanning electron microscope and energy-dispersive X-ray spectroscopy, respectively. The binding energy of the core levels, chemical state, atomic fractions, depth profiling of the thin film were investigated by X-ray photo-electron spectroscopy. The photoluminescence excitation, emission spectra and energy transfer process involved in Pr3+ doped BaMoO4 thin films were analyzed. The color chromaticity co-ordinates, fluorescence decay time and the photometric properties of the as-deposited thin phosphor films were examined.

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