Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 33, Issue 6, Pages -Publisher
WILEY
DOI: 10.1002/aoc.4912
Keywords
diarylmethane synthesis; homogeneous catalysis; N-donor; NHC-palladium complex; Suzuki-Miyaura reaction
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Funding
- Ministry of Science and Technology of Taiwan [MOST 107-2113-M-126-001-MY2]
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A family of N-heterocyclic carbene-palladium(II)-N,N-dimethylbenzylamine complexes ((NHC)LPdCl2; L=N,N-dimethylbenzylamine) were synthesized as well as characterized using single-crystal X-ray diffraction and spectroscopic data. These complexes exhibited higher catalytic activities for the Suzuki reaction of benzyl chlorides to afford diarylmethanes under milder conditions than other efficient (NHC)LPdCl2 complexes. Using the optimum conditions, the expected coupling products were obtained in moderate to high yields. All reactions were carried out in air and all starting materials were used as supplied without purification.
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