Article
Engineering, Environmental
Taylor J. Glattke, Sarajeen Saima Hoque, Martha L. Chacon-Pat, Thomas E. Ennis, Steve Greason, Alan G. Marshall, Ryan P. Rodgers
Summary: Pavement sealants, especially coal tar-derived ones, are a concern due to their high concentrations of toxic/carcinogenic substances and their harmful effects on waterways and aquatic ecosystems. This study compares the molecular compositions of different sealants and evaluates the toxicity of their water-soluble products. The results show that coal tar sealants contain higher amounts of harmful compounds compared to asphalt sealants.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Biochemical Research Methods
Matthias Hoyer, Juergen H. Gross
Summary: Atmospheric pressure field desorption mass spectrometry (APFD-MS) is a new contribution to the field of ambient desorption/ionization (ADI). It has been demonstrated that ionic and polar analytes can deliver positive and negative ions depending on the selected polarity applied to the field emitter. The present work on APFD-MS shows the abundant formation of positive molecular ions from polycyclic aromatic compounds.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Biochemical Research Methods
Konstantin O. Nagornov, Anton N. Kozhinov, Natalia Gasilova, Laure Menin, Yury O. Tsybin
Summary: This paper highlights the importance of isotopic beat patterns in the accurate interpretation of FTMS data, introduces a new FTMS data simulation tool for mAbs analysis, and evaluates the isotopic beat characteristics in typical instruments for mAbs analysis. The results demonstrate a significant impact of isotopic beat patterns on the analytical characteristics of mass spectra.
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
(2022)
Article
Chemistry, Analytical
Yi Yu, Jichun Jiang, Lei Hua, Yiqian Xu, Chuang Chen, Yi Chen, Haiyang Li
Summary: The ion conversion processes in CH2Cl2-enhanced vacuum ultraviolet photoionization of oxygenated volatile organic compounds (OVOCs) were studied by regulating pressure, humidity, and reaction time in the ionization source. The main characteristic ions changed with varying pressure, and interconversion between ions through ion-molecule reactions was observed with increasing humidity. The intensity of protonated methanol/ethanol ion was linearly correlated with the intensity of hydrated hydronium ions, indicating a proton transfer reaction mechanism. The reaction time was regulated by the electric field strength, and step-by-step ion-molecule reactions were observed. This study provides insights into the formation mechanism of intermediate product ions and hydrated hydronium ions in dopant-enhanced VUV photoionization and helps optimize experimental conditions for enhancing the sensitivity of OVOCs.
ANALYTICAL CHEMISTRY
(2023)
Article
Energy & Fuels
Alessandro Vetere, Daniel Profrock, Wolfgang Schrader
Summary: The article focuses on the molecular analysis of crude oil and its fractions, with a particular emphasis on the challenging task of quantifying sulfur. The proposed method combines sulfur-selective chromatographic separation and mass spectrometry detection for both qualitative and quantitative analysis of sulfur compounds in complex heavy crude oil fractions.
Article
Chemistry, Analytical
Junnan Liu, Min Zhao, Shuang Zhang, Jiaonan Liu, Chunjie Zhao, Miao Wang
Summary: A rapid and straightforward analytical method was established to identify the chemical constituents of Wangbi Capsule, a compound preparation widely used in the treatment of rheumatoid arthritis. The method successfully identified 140 compounds in the capsule, including nucleosides, alkaloids, organic acids, flavonoids, and other chemical components. This method has potential significance for characterizing other Chinese medicine components and lays the foundation for further pharmacological and in vivo studies of Wangbi Capsules.
MICROCHEMICAL JOURNAL
(2022)
Article
Instruments & Instrumentation
Elise L. Gjelsvik, Martin Fossen, Anders Brunsvik, Kristian H. Liland, Kristin Tondel
Summary: Crude oils are complex mixtures with various components, and traditional analytical techniques may not be sufficient for detailed characterization. Fourier transform ion cyclotron resonance mass spectrometry and infrared spectroscopy can be used for crude oil analysis. This study compared different regression models (single block PLSR, multiblock PLSR, and SO-PLSR) to predict crude oil density, and found that combining multiple blocks of data improved the prediction performance.
APPLIED SPECTROSCOPY
(2023)
Article
Chemistry, Analytical
Sonia Abreu, Sylvie Heron, Audrey Solgadi, Florent Joffre, Alain Tchapla, Pierre Chaminade
Summary: A new analytical approach for triacylglycerol fatty acyls distribution analysis using NPLC coupled with APPI(+)-HRMS was presented in this study. The method showed high efficiency in separating lipid classes and accurately determining fatty acyl composition in complex lipid extracts.
ANALYTICA CHIMICA ACTA
(2021)
Article
Biochemical Research Methods
Juergen H. Gross
Summary: Recent research has shown that field desorption and field ionization can be performed at atmospheric pressure using activated field emitters. This method, known as atmospheric pressure field desorption mass spectrometry, allows for the analysis of highly polar or ionic compounds and the generation of positive molecular ions of polycyclic aromatic compounds. In this study, negative-ion atmospheric pressure field desorption was used to analyze anionic surfactants in commercial detergent products. The surfactants were characterized using accurate mass-based formula assignments and tandem mass spectrometry.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Biochemical Research Methods
Juergen H. Gross
Summary: Recent work has demonstrated the analysis of anionic surfactants in commercial detergent products using atmospheric pressure field desorption and field ionization. The method allows for accurate characterization of the surfactant compounds and can be compared to negative-ion electrospray ionization results.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Yaxin Wu, Huiting Ma, Yongfan Li, Lijun Zhang, Meina Liu, Yidan Geng, Zhenwen Dai
Summary: The magnetic dipole hyperfine structure (HFS) constants A of neutral and singly ionized europium (Eu I and Eu II) were determined using the emission spectra recorded by the Fourier transform spectrometer. The study identified 29 levels of Eu I and 15 levels of Eu II for the first time, and reported new results for the HFS constants and isotope shifts of Eu I and Eu II. This work significantly expands the knowledge on HFS constants and isotope shifts for Eu I and Eu II.
RESULTS IN PHYSICS
(2023)
Article
Environmental Sciences
Cuiping Ning, Yuan Gao, Haijun Zhang, Haoran Yu, Rong Cao, Jiping Chen
Summary: This study investigated the molecular characteristics of water-soluble organic matter (WSOM) in atmospheric PM in the range of 0.010-18 μm. A bimodal distribution of PM mass concentrations was found, with saturated fatty acids and their oxidized derivatives identified as the main carriers of CHO compounds. In hazy days, significant increases in S-containing compounds were observed, promoting particle agglomeration and haze formation.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
Prerona Das, Abhijit Mukherjee, Dan J. Lapworth, Kousik Das, Sumitro Bhaumik, Mrinal K. Layek, Ashok Shaw, Martin Smith, Probal Sengupta, Alan M. MacDonald, Joy Sen
Summary: Groundwater resources in South Asian cities are under immense stress due to over-extraction, while the mega rivers of Himalayas play a crucial role in supporting food and water security in the region. The study reveals that infiltrating river water during the monsoon season plays a primary role in controlling aquifer storage, although it also contaminates the groundwater.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Multidisciplinary Sciences
Heather O. LeClerc, Geoffrey A. Tompsett, Alex D. Paulsen, Amy M. McKenna, Sydney F. Niles, Christopher M. Reddy, Robert K. Nelson, Feng Cheng, Andrew R. Teixeira, Michael T. Timko
Summary: Food waste is a promising resource for renewable fuel production. The use of hydroxyapatite catalyst in hydrothermal liquefaction can increase biocrude yields and promote condensation reactions. Economic and environmental analysis shows that this technology can reduce greenhouse gas emissions and produce renewable diesel.
Article
Biochemical Research Methods
Kaili He, Chao Chen, Jiewei Deng, Ya-Jun Hou, Zhangmin Xiang, Yunyun Yang
Summary: A rapid, simple, and efficient MALDI-FTICR-MS imaging method was developed in this study for accurate identification and clear visualization of the spatial distribution of LPLs in zebrafish tissues.
JOURNAL OF MASS SPECTROMETRY
(2021)
Article
Chemistry, Analytical
Sergey Silkin, Eugen E. Kulikov, Igor A. Popov, Stanislav Pekov
Summary: We developed a computational environment to model the mineral composition of natural water based on the elemental and cation-anion content of the sample. The calculated models were validated through experiments and comparisons with natural water samples, demonstrating the capability to accurately predict water quality indicators for water monitoring.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2023)
Article
Biochemical Research Methods
Lidiia Rumiantseva, Sergey Osipenko, Ilya I. Podolskiy, Dmitry A. Burmykin, Oxana Kovaleva, Evgeny N. Nikolaev, Yury Kostyukevich
Summary: In this paper, a method that combines oxygen isotope exchange reaction with mass spectrometry is presented, which allows to increase the reliability of identification of individual compounds. The method was tested on pharmaceutical substances and human urine samples, showing its effectiveness.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Anna E. Bugrova, Polina A. Strelnikova, Maria I. Indeykina, Alexey S. Kononikhin, Natalia V. Zakharova, Alexander G. Brzhozovskiy, Evgeny P. Barykin, Stanislav I. Pekov, Maria S. Gavrish, Alexey A. Babaev, Anna M. Kosyreva, Anna Y. Morozova, Daniil A. Degterev, Vladimir A. Mitkevich, Igor A. Popov, Alexander A. Makarov, Evgeny N. Nikolaev
Summary: Alzheimer's disease is a major cause of dementia in the elderly, characterized by the deposition of beta-amyloid (Aβ) peptides in senile plaques. This study monitored the accumulation dynamics of Aβ proteoforms in a widely used amyloid-based mouse model and found evidence supporting a possible mechanism for the progression of AD-like pathology.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Biochemical Research Methods
Sergey Osipenko, Alexander Zherebker, Lidiia Rumiantseva, Oxana Kovaleva, Evgeny N. Nikolaev, Yury Kostyukevich
Summary: LC-MS is a key technique for identifying small molecules in complex samples. This study proposes an implementation of 16O/18O isotope exchange to highlight various functional groups, and evaluates its potential as a descriptor for filtering database candidates in untargeted LC-MS-based workflows.
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
(2022)
Article
Energy & Fuels
Vinod Kumar, Prateek Gururani, Afreen Parveen, Monu Verma, Hyunook Kim, Mikhail Vlaskin, Anatoly Grigorenko, Kirill G. Rindin
Summary: Valorization of dairy-industry wastewater and stormwater energy is a new approach to sustainable agriculture. Cultivating yeast-algae consortium using diluted dairy wastewater proved effective in removing nitrogen, phosphorus, and organic compounds, as well as increasing lipid content and unsaturated fatty acids. This method also reduces bacterial load.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Energy & Fuels
Bhawna Bisht, Prateek Gururani, Shivam Pandey, Krishna Kumar Jaiswal, Sanjay Kumar, Mikhail S. Vlaskin, Monu Verma, Hyunook Kim, Vinod Kumar
Summary: This study investigates the effect of Multi-Stage HTL on different feedstocks and finds that kitchen wastewater sludge is the most suitable for producing high-energy bio-oil. The study also analyzes the compound variations in bio-oils and bio-chars derived from different biomasses using various testing methods.
Article
Engineering, Chemical
Nadezhda Chernova, Anatolii Grigorenko, Sophia Kiseleva, Olga M. Larina, Vinod Kumar, Mikhail S. Vlaskin
Summary: This study compared the effectiveness of pyrolysis and hydrothermal liquefaction in obtaining biofuel from microalgal biomass, with hydrothermal liquefaction showing higher bio-oil yield. Both technologies produced similar bio-coal yields, which can serve as an alternative strategy for CO2 absorption and storage.
Article
Energy & Fuels
Elizaveta A. Chunzhuk, Anatoly V. Grigorenko, Nadezhda I. Chernova, Sofya V. Kiseleva, Kirill G. Ryndin, Oleg S. Popel, Sergey Ya Malaniy, Olga V. Slavkina, Fabio de Farias Neves, Lijian Leng, Vinod Kumar, Mikhail S. Vlaskin
Summary: This study conducted a direct observation of CO2 capture efficiency in the cultivation of microalgae Arthrospira platensis at high CO2 concentrations. The microalgae were grown in a 90 L photobioreactor using Zarrouk's medium. Three experiments were carried out with different initial CO2 concentrations: 1, 5, and 9 vol.%. The decrease in CO2 concentration due to microalgae growth was highest at 0.10 vol.% (CO2)/day in the experiment with an initial CO2 concentration of 5 vol.%. The biomass density growth rate was 79.4, 76.3, and 48.4 (mg/L)/day at 1, 5, and 9 vol.% CO2 concentrations, respectively. The viability of Arthrospira platensis was found to be good at 1% and 5% CO2 concentrations, but mass death of cells occurred at 9% CO2 concentration. Biochemical analysis showed a decrease in lipid and protein content with increasing CO2 concentration.
Article
Chemistry, Physical
Olesya A. Buryakovskaya, Mikhail S. Vlaskin
Summary: This study proposed an alternative solution for utilizing aluminum-plastic multilayer waste through separating layers and generating hydrogen using an alkali solution. The process effectively separated different types of aluminum-plastic sandwich materials, making them ready for further recycling.
Article
Chemistry, Physical
Olesya A. Buryakovskaya, Mikhail S. Vlaskin
Summary: A method has been developed to transform magnesium scrap into highly efficient hydroreactive material. The addition of Devarda's alloy during ball milling can accelerate the reaction and improve the production of hydrogen gas and reaction rates.
Article
Materials Science, Multidisciplinary
Olesya A. Buryakovskaya, Musi Zh. Suleimanov, Mikhail S. Vlaskin, Vinod Kumar, Grayr N. Ambaryan
Summary: An effective combination of oxidation medium, ball milling parameters, and copper additive disperstiy ensuring fast aluminum scrap reaction with high hydrogen yield was suggested. The best results were obtained with 15 mm balls (1 h) which provided the second-finest powder and best preservation of the original Cu and Al phases.
Article
Chemistry, Physical
Olesya A. Buryakovskaya, Grayr N. Ambaryan, Musi Zh. Suleimanov, Alexey B. Tarasenko, Mikhail S. Vlaskin
Summary: Composite materials were prepared by high energy ball milling of mixed scrap of Mg-based alloys and low melting point Sn-Pb eutectic, and their hydrogen generation performance was tested in NaCl solution. The effects of ball milling duration and additive content on microstructure and reactivity were investigated. SEM analysis showed significant structural transformations during ball milling, and XRD analysis confirmed the formation of new intermetallic phases Mg2Sn and Mg2Pb to enhance galvanic corrosion of the base metal. The reactivity of the material exhibited a non-monotonic dependency on activation time and additive content. Among all tested samples, milling for 1 hour and a composition with 5 wt.% Sn-Pb alloy showed the highest hydrogen generation rates and yields compared to other conditions.
Article
Chemistry, Multidisciplinary
Grayr N. Ambaryan, Olesya A. Buryakovskaya, Vinod Kumar, Georgii E. Valyano, Elena A. Kiseleva, Anatoly V. Grigorenko, Mikhail S. Vlaskin
Summary: This study investigates the hydrothermal oxidation of aluminum, a exothermic process that produces hydrogen and aluminum oxide (or hydroxide). The chemical purity of aluminum was found to significantly affect the oxidation kinetics, with more pure aluminum oxidizing much faster.
APPLIED SCIENCES-BASEL
(2023)
Article
Plant Sciences
Elizaveta A. Chunzhuk, Anatoly V. Grigorenko, Sophia V. Kiseleva, Nadezhda I. Chernova, Mikhail S. Vlaskin, Kirill G. Ryndin, Aleksey V. Butyrin, Grayr N. Ambaryan, Aleksandr O. Dudoladov
Summary: This study aims to investigate the effect of light intensity on the biomass growth and biochemical composition of five different microalgae strains, and found that increasing light intensity can enhance microalgae biomass productivity, showing potential for biodiesel applications.
Article
Chemistry, Multidisciplinary
Mikhail S. Vlaskin, Anatoly V. Grigorenko, Aleksandr O. Dudoladov, Matvey S. Galtsov-Tsientsiala, Vinod Kumar, George E. Valyano, Leonarda Liotta
Summary: The effect of capillary tube material on the process of thermal decomposition of methane was studied, and it was found that corundum showed the highest efficiency while stainless steel showed the lowest efficiency.
APPLIED SCIENCES-BASEL
(2023)