4.8 Article

Opening the Band Gap of Graphene via Fluorination for High-Performance Dual-Mode Photodetector Application

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 24, Pages 21702-21710

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b04389

Keywords

fluorinated graphene; band gap opening; photoconductive photodetector; photodiode; broadband

Funding

  1. Natural Science Foundation of China [61675062, 61575059, 21501038]
  2. Fundamental Research Funds for the Central Universities [JZ2018HGPB027, JZ2018HGXC0001, JZ2018HGTA0220]
  3. Open Foundation of Key Laboratory of Advanced Functional Materials and Devices of the Anhui Province [4500-411104/011]

Ask authors/readers for more resources

Fluorination is an effective process to open the band gap of graphene (Gr), which is beneficial to the development of optoelectronic devices working in wide wave-length. Herein, we report a dual-mode broadband photodetector (PD) by integrating fluorinated graphene (F-Gr) with silicon (Si). It is found that when working in photoconductive mode, the F-Gr/Si heterojunction exhibited a remarkable photoresponse over a wide spectral region from ultraviolet (UV), visible to near infrared (NIR) light with a high responsivity (R) of 1.9 x 10(7) A and specific detectivity (D*) of 4.4 x 10(12) Jones at 650 nm. Nonetheless, both parameters will be considerably reduced when the F-Gr/Si heterojunction works in the photodiode mode. In this mode, the I-light/I-dark ratio is as high as 2.0 x 10(5) and the response speed is accelerated by more than 3 orders of magnitude from about 5 ms to 6.3 mu s. Notably, the responsivity of the device in the UV and NIR regions was remarkably enhanced in comparison with that of pristine Gr/Si-heterojunction-based devices. Considering the F-coverage-dependent band gap of the F-Gr revealed by the first-principle calculations, we believe that the enhancement was ascribed to the opening of the band gap in the partially fluorinated Gr, which is stabilized due to the configuration entropy as the temperature increases. The dual-mode PD enabled the simultaneous weak light detection and fast photodetection, which overcome the limitation of the traditional monomode PD.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Multidisciplinary

Fabrication of a Periodic Inverse Micropyramid (PIMP)-Si/In2Se3 Heterojunction Photodetector Array for RGB-IR Image Sensing Application

Chao Zhang, Chen-Yue Zhu, Zhen Yang, Di-Hua Lin, Chun-Yan Wu, Shi-Rong Chen, Yi-Zhong Yang, Li Wang, Yu-Xue Zhou, Lin-Bao Luo

Summary: An addressable 8 x 8 photodetector array is fabricated by combining In2Se3 nanofilm with periodic inverse micropyramid-Si (PIMP-Si). The device exhibits excellent self-powered photoresponse, competitive performance, and satisfactory pixel-to-pixel uniformity, showing potential applications in full-color image sensing and video capturing.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Article Chemistry, Multidisciplinary

A Simple-Structured Perovskite Wavelength Sensor for Full-Color Imaging Application

Can Fu, Zhi-Yuan Li, Jiang Wang, Xiang Zhang, Feng-Xia Liang, Di-Hua Lin, Xiao-Feng Shi, Qun-Ling Fang, Lin-Bao Luo

Summary: In this study, simple-structured wavelength sensors were developed using Au/MAPbI3/Au photodetectors deposited on an MAPbI3 single crystal. The sensors could accurately distinguish incident-light wavelengths ranging from 265 to 860 nm with a resolution of less than 1.5 nm. The high-performance MAPbI3 wavelength sensor has the potential to drive research progress in perovskites for wavelength recognition and full-color imaging.

NANO LETTERS (2023)

Article Nanoscience & Nanotechnology

Ultrahigh-Sensitivity and Fast-Speed Solar-Blind Ultraviolet Photodetector Based on a Broken-Gap van der Waals Heterodiode

Li Zhang, Zhenhua Wei, Xiuxiu Wang, Luoyu Zhang, Yi Wang, Chao Xie, Tao Han, Feng Li, Wei Luo, Dongxu Zhao, Mingsheng Long, Lei Shan

Summary: Metal mirror-enhanced Ta0.01W0.99Se2/SnS2 (TWS) heterodiode-based SBUV photodetector has a high photoresponsivity and fast response speed, making it suitable for a wide range of applications such as missile plume tracking, flame detection, environmental monitoring, and optical communication. This study provides an alternative method for designing fast-speed SBUV photodetectors with great potential in applications.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Multidisciplinary

Bias-Selectable Si Nanowires/PbS Nanocrystalline Film n-n Heterojunction for NIR/SWIR Dual-Band Photodetection

Chen-hao Xu, Sheng-Hui Luo, Yang Wang, Xiao-Feng Shi, Can Fu, Jiang Wang, Chun-Yan Wu, Lin-Bao Luo

Summary: This study presents a solution method for a dual-band photodetector (PD) based on silicon nanowires /PbS nanocrystalline film n-n heterojunction. The device exhibits bias-selectable spectral response in the near-infrared (NIR) and short-wave infrared (SWIR) bands by adjusting the polarity of the bias voltage. It achieves high responsivities and detectivity in the NIR region, comparable to or even better than some commercial PDs, due to improved optical absorption and charge separation and collection efficiency through the heterojunction geometry. The study demonstrates the potential of detecting two distinct IR regions with the same pixel for future optoelectronic systems.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Engineering, Electrical & Electronic

Fluorine Plasma Treatment for AlGaN/GaN HEMT-Based Ultraviolet Photodetector With High Responsivity and High Detectivity

Kunnan Zhou, Longqiang Shan, Yuliang Zhang, De Lu, Yuanming Ma, Xing Chen, Linbao Luo, Chunyan Wu

Summary: In this study, an AlGaN/GaN HEMT-based ultraviolet photodetector (UVPD) was fabricated by fluorine plasma treatment using C4F8 gas. The device exhibited a significantly reduced dark current and effectively suppressed the persistent photoconductivity (PPC) effect, resulting in a high responsivity of 1.3 x 10(4) A W-1 and a high specific detectivity of 1.8 x 10(15) Jones. This work provides a facile and cost-effective strategy for the fabrication of high-performance AlGaN/GaN HEMT-based UVPDs.

IEEE ELECTRON DEVICE LETTERS (2023)

Article Engineering, Electrical & Electronic

Filterless and High-Speed InP Near-Infrared Photodetector With an Ultra-Small Full-Width at Half Maximum

Li Wang, Xiu-Dong He, Quan-You Wang, Ning Qi, Song-Yun Tian, Mo-Lin Wang, Chun-Yan Wu, Ji-Gang Hu, Lin-Bao Luo

Summary: The state of each flow is crucial for many network functions. This paper focuses on per-flow cardinality and presents a new problem: online query of per-flow cardinality. Three solutions, On-vHLL, Ton-vHLL, and Aton-vHLL, are proposed with O(1) time complexity for query operation. These techniques involve the redesign of vHLL with incremental update units (IUUs) to reduce time complexity, the application of TailCut compression technique to save memory cost, and the addition of a prefilter based on min-heap for better accuracy in Ton-vHLL.

IEEE TRANSACTIONS ON ELECTRON DEVICES (2023)

Article Materials Science, Multidisciplinary

Sensitive and Broadband Wavelength Sensor Based on Two Graphene/Si/Graphene Heterojunctions

Yue Xing, Jiang-Xu Yang, Guang-Yong Zou, Can Fu, Yan Pan, Yu-Tian Xiao, Jiang Wang, Yan Wang, Lin-Bao Luo

Summary: Researchers have developed a high-resolution wavelength sensor by assembling two back-to-back monolayer graphene/Si/monolayer graphene heterojunctions. This device shows excellent photoelectric properties and can accurately estimate the wavelength of incident light in the range from 260 to 1050 nm, demonstrating a high resolution of 1 nm across a broadband wavelength from 260 to 1000 nm. This study provides potential promise for future spectral sensing applications.

ADVANCED OPTICAL MATERIALS (2023)

Article Nanoscience & Nanotechnology

Visible-Light-Enhanced NO2 Sensing Based on the Hybrid Orthorhombic/Monoclinic-PdSe2 Nanostructures

Jinle Fan, Xuefeng Hu, Weiwei Qin, Ming Zhou, Zhi-Yuan Liu, Shou-Jing Gao, Li-Ping Tan, Lin-Bao Luo, Wei Zhang

Summary: By precisely controlling the selenization engineering, orthorhombic PdSe2 and monoclinic PdSe2 crystals were successfully integrated. The hybrid O/M-PdSe2 nanostructures were fabricated for the first time, and they exhibited high responsivity as a broadband photodetector and fast response and recovery times as a gas sensor.

ACS APPLIED NANO MATERIALS (2023)

Article Engineering, Electrical & Electronic

Surface State Induced Filterless SWIR Narrow-Band Si Photodetector

Li Wang, Yan Pan, Jia-Le Xing, Jian-Bo Mao, Yong-Jin Ba, Lu Cao, Mo-Lin Wang, Chun-Yan Wu, Xiang Zhang, Lin-Bao Luo

Summary: In this study, a planar type self-powered short wavelength infrared narrowband Si photodetector was developed using a simple Schottky structure. The distance between the Schottky electrode and the light irradiation region was increased to enhance the device sensitivity and reduce the size. With the assistance of a pyramid microstructure, the required distance for sub 100 nm narrowband detection was effectively decreased. The obtained photodetector exhibited high wavelength selectivity and sensitivity due to the large number of surface states and pronounced light confinement effect of the pyramid microstructure. This work opens up a new avenue for achieving planar-type narrowband photodetectors with better integration capabilities for on-chip applications than vertical devices.

IEEE ELECTRON DEVICE LETTERS (2023)

Article Engineering, Electrical & Electronic

Periodic Inverted Micropyramid-Si/Graphene Self-Powered Photodiode With Excellent Current Stability for Fourier Single-Pixel Imaging

Chunyan Wu, Xishen Guo, Xia Wu, Jinxulong Gao, Jun Wang, Yizhong Yang, Li Wang, Yuxue Zhou, Linbao Luo

Summary: In this study, a self-powered periodic inverse micropyramid (PIMP)-Si/graphene photodiode with high responsivity, specific detectivity, and fast response speed was reported. The rise/fall time at zero bias upon 880 nm illumination were found to be 226/364 μs, respectively. The introduction of an ultrathin interfacial oxide layer was shown to passivate surface states and improve current stability, enabling high-quality Fourier single-pixel imaging.

IEEE ELECTRON DEVICE LETTERS (2023)

Article Engineering, Electrical & Electronic

A Narrowband Perovskite Photodetector for Blue Light Hazard Detection

Zhen-Yu Zhang, Zhi-Xiang Zhang, Meng Shen, Cui-Yun Zhang, Can Fu, Xiang An, Jiang Wang, Xiang Zhang, Lin-Bao Luo

Summary: The study reports a narrowband blue light photodetector based on CH3NH3PbBrCl2 single crystal and its filterless application in blue light hazard detection. The photodetector is only sensitive to light between 400 and 500 nm, allowing for accurate detection of blue light hazard levels. With the introduction of back-end circuits, the photodetector has been applied to a portable blue light hazard detection system, showing potential applications in the future healthcare field.

IEEE TRANSACTIONS ON ELECTRON DEVICES (2023)

Article Materials Science, Multidisciplinary

Two-dimensional vertical-lateral hybrid heterostructure for ultrasensitive photodetection and image sensing

Na Zhang, Fakun Wang, Pengyu Li, Yi Liang, Hao Luo, Decai Ouyang, Linbao Luo, Jinsong Wu, Yinghe Zhao, Yuan Li, Tianyou Zhai

Summary: In this study, a novel 2D hybrid heterostructure of bismuth selenide/oxyselenide with the coexistence of lateral and vertical interfaces is reported. The hybrid structure provides a large interface area and a wide depletion region, significantly improving the device's optoelectronic performances. The photodetectors exhibit reduced dark current and ultrafast photoresponse rate, and demonstrate outstanding image sensing capability over a wide spectral range.

MATERIALS TODAY (2023)

Article Materials Science, Multidisciplinary

High-Performance Broadband Flexible Photodetectors Based on Ti3C2Tx MXene/Pyramidal Thin Si Heterostructures with Light Trapping Effect for Heart Rate Detection

Chao Xie, Yi Wang, Zhaosheng Xia, Yu Cheng, Xisheng Cui, Shijie Xu, Xingang Ren, Wenhua Yang, Zhixiang Huang

Summary: In this study, a highly efficient flexible photodetector with remarkable light trapping effect and excellent photoresponse performance was successfully fabricated. It also demonstrated outstanding mechanical flexibility and robust bending endurance, making it suitable for applications such as monitoring heart rate.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Article Materials Science, Multidisciplinary

MAPbBr3-nXn (X = Cl, I) single-crystal narrowband photodetectors for potential application in traffic light recognition

Feng-Xia Liang, Shi-Fu Li, Jie Yu, Liang-Liang Zhou, Jiang Wang, Can Fu, Xiang An, Jian-An Huang, Li Wang, Lin-Bao Luo

Summary: A series of MAPbBr(3-n)X(n) (X=Cl, I) single-crystal films with controllable thickness have been grown through space-limited inverse temperature crystallization, achieving filter-free narrowband photodetectors with peak responses at 505, 590 and 620 nm, corresponding to the green, yellow and red of traffic lights. These narrowband photodetectors demonstrate superior performance, with a maximum responsivity of 182 mA W^-1 and specific detectivity of 9.68 x 10(10) Jones, and a traffic light recognition assembly based on them shows good color recognition capability.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

Article Materials Science, Multidisciplinary

A dual-band graphene/silicon nanowire array heterojunction photodetector induced by leaky mode resonances

Di-Hua Lin, Fang Wan, Shu-Chang Gong, Can Fu, Feng-Xia Liang, Lin-Bao Luo

Summary: Dual-band photodetectors (DBPDs) are widely used in multispectral information monitoring in both civil and military applications. This paper presents a novel DBPD fabricated using a silicon nanowire array, which exhibits dual-band absorption resulting from leaky mode resonances (LMRs) in the nanowires. Experimental results show two peak responsivities at 430 nm and 660 nm, matching well with simulations and confirming the practicality of this silicon-based wavelength-selective spectral detection device.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

No Data Available