Review
Materials Science, Ceramics
Zeinab Savaedi, Reza Motallebi, Hamed Mirzadeh, Mehdi Malekan
Summary: Thermoforming in the supercooled liquid region can achieve high strain-rate-sensitivity and superplastic ductility. Incipient deformation-induced crystallization and stress-assisted free volume change lead to a transition from Newtonian to non-Newtonian flow. Factors such as heating rate, processing time, and the extent of the supercooled liquid region significantly affect the structural stability. Increasing the deformation temperature enhances superplastic behavior, but high temperatures may promote crystallization and loss of superplastic ductility. Future research directions include optimizing the structure and preparation methods of metal glass-based composites and improving thermoplastic formability.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Engineering, Mechanical
Wei-Hui Lin, Chong-Min She, Chun-Yu Zhang, Paulo S. Branicio, Zhen - Dong Sha
Summary: The mechanical properties of cellular metallic glasses are influenced by the shape of their cellular structures. Random structures with uniform porosity show higher yield strength and Young's modulus compared to microlattice structures. The chiral structure displays the highest Young's modulus, while stochastic cellular structures exhibit higher energy absorption capacity.
INTERNATIONAL JOURNAL OF PLASTICITY
(2022)
Review
Chemistry, Physical
Yu Chen, Zheng-Wei Dai, Jian-Zhong Jiang
Summary: Metallic glasses and high entropy alloys have shown remarkable features but also have issues. Recent efforts have been made to address these problems by introducing new concepts and mechanisms. High entropy metallic glasses, combining the advantages of both, have become a research focus.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Weiping Zeng, Yanhua Chen, Qiang Li, He Li, Baoxia Mu, Jiankang Ye, Chuntao Chang
Summary: The effects of Co content on the properties of Ni-based bulk metallic glasses were systematically investigated. It was found that increasing Co content improves glass forming ability, plastic strain, and corrosion resistance. These Ni-based bulk metallic glasses have excellent comprehensive performance and great potential for industrial applications.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Chemistry, Physical
A. H. Cai, G. Zhou, P. W. Li, D. W. Ding, Q. An, G. J. Zhou, Q. Yang, Y. P. Lin, H. Mao
Summary: The relationship between microstructure and mechanical property of three Zr-based bulk metallic glasses (BMGs) was investigated. The results show that the content of CuZr2-type phase increases but that of Zr6Al2Ni-type phase decreases with increasing Zr content. The plastic flow stress and strain decrease while the plasticity increases with increasing fraction of CuZr2-type cluster, which is named as geometrically unfavorable motifs (GUMs). The fitting parameters from cumulative probability statistics provide valuable clues for investigating the plastic flow and plasticity of the BMGs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
A. Lindsay Greer, Miguel B. Costa, Owain S. Houghton
Summary: There have been remarkable advances in the field of metallic glasses over the last 50 years, including an expanded range of compositions, improved production and shaping techniques, and the discovery of property combinations offering unparalleled performance. Ongoing research continues to provide fundamental insights into the structure and properties of glasses and liquids. This article focuses on the latest advances in understanding and the rapidly expanding prospects for applications.
Article
Materials Science, Multidisciplinary
Chang Liu, Suyue Yuan, Jinwoo Im, Felipe P. J. de Barros, Sami F. Masri, Paulo S. Branicio
Summary: Molecular dynamics simulations are used to investigate the mechanical properties of nanoporous CuxZr1-x metallic glasses. The study reveals a strong correlation between Young's modulus, Ultimate Tensile Strength (UTS), and porosity/composition. Increasing porosity leads to a change in nanoporous topology and a transition from brittle to ductile deformation and failure mechanisms. Genetic Programming (GP) is employed to establish scaling laws for E and UTS as a function of porosity and composition, accurately predicting their values in the entire range considered.
Article
Nanoscience & Nanotechnology
Jiazi Bi, Xinquan Wei, Xiaobin Liu, Ran Li, Ruijuan Xiao, Tao Zhang
Summary: A family of novel Os-Co-Ta-B high-temperature bulk metallic glasses (HTBMGs) with high glass transition temperature, Vickers microhardness, and compressive strength was fabricated by introducing high-modulus refractory metal Os and strong-covalent metalloid B. The impressive strength is attributed to the strong bond characteristics especially for Ta-Os and B-B bonds. The castable OsCo-based HTBMGs with superior mechanical properties and high thermal stabilities are significant for high-temperature applications as advanced structural materials.
SCRIPTA MATERIALIA
(2023)
Article
Chemistry, Multidisciplinary
Yu-Chia Yang, Zhenhai Xia, Sundeep Mukherjee
Summary: This paper explores the relationship between atomic structure and mechanical properties of metallic glasses by using molecular dynamics simulation. The study found that changes in mechanical properties can be linked to short- and medium-range ordering in the atomic structure. Structural statistics, such as Voronoi analysis, were used to determine the mechanical properties of the metallic glass.
Article
Chemistry, Physical
C. Y. Liu, Y. X. Zhang, G. Yuan, C. Y. Zhang, R. D. K. Misra, J. Kang
Summary: The study proposes a novel composition and design strategy for Fe78.9B11.8Si7.6C1Cu0.7 alloy, which successfully achieves excellent magnetic properties and plasticity in Fe-based metallic glasses. This innovation is expected to contribute to the development of next-generation magnetic materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
V Jambur, C. Tangpatjaroen, J. Xi, J. Tarnsangpradit, M. Gao, H. Sheng, J. H. Perepezko, I Szlufarska
Summary: This study shows that minor alloying can enhance the strength of metallic glasses by increasing the chemical bond strength, which is distinct from changes in topological ordering. The addition of transition metals to Al-Sm based metallic glasses increased their hardness, mainly due to the strong bonding between transition metals and aluminum atoms. The effects of topology and chemistry on the mechanical properties of metallic glasses are independent of each other, providing insights for the design of metallic glasses with improved mechanical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Civil
Yu Chen, Jia-Cheng Zhang, Paulo S. Branicio, Zhen-Dong Sha
Summary: This study uses molecular dynamics simulations to investigate the mechanical properties and failure mechanisms of brick-and-mortar metallic glasses. The results show that a desirable balance between strength and plasticity can be achieved in BMMGs with appropriate brick aspect ratios and interlayer thicknesses.
THIN-WALLED STRUCTURES
(2023)
Article
Chemistry, Physical
Guoxiang Shen, Weizhi Li, Zhichao Ma, Shengteng Zhao, Dongni Liu, Hongwei Zhao, Luquan Ren
Summary: This study investigates the depth-dependent mechanical properties of Zr-based bulk metallic glasses using the depth-sensitive nanoindentation technique. The results show that the surface hardness and elastic modulus increase, while fracture toughness decreases with decreasing indentation depth. This mechanical size effect is closely related to the evolution of shear bands at different depths.
Article
Engineering, Mechanical
Jinqian Song, Wenqing Zhu, Xiaoding Wei
Summary: By utilizing Fourier analysis, this study establishes an analysis protocol to quantitatively measure the spatial heterogeneity of metallic glasses, revealing a hierarchy of spatial heterogeneity inherited from thermal processes. The trends of spatial heterogeneity under mechanical loadings provide valuable information about shear instability onset, and a positive correlation between initial nanoscale heterogeneity and material ductility is found. This analysis protocol offers a new way to explore the structure-property relationship for disordered materials.
INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES
(2021)
Article
Materials Science, Ceramics
Zhengyang Huang, Pingjun Tao, Ziyun Long, Zusheng Xiong, Xuguang Zhu, Xi Xu, Zhenghua Huang, Huanhuan Deng, Haisheng Lin, Weiqiu Li, Jiayu Zhang, Haichao Zheng
Summary: The effect of Ti substitution for Cu on the glass forming ability (GFA) and mechanical properties of Zr60Cu(20x)Al10Ni10Tix (x = 0, 1, 3 and 5at.%) bulk metallic glasses (BMGs) was investigated. The addition of Ti improved the GFA of Zr-based BMGs, as indicated by the increase in supercooled liquid region range from 47 K to 79 K. The plasticity and fracture strength of Zr-based BMGs significantly increased with Ti addition, reaching a peak value of 25.3% and 2315 MPa, respectively. The hardness and elastic modulus of Zr-based BMGs were also significantly improved with Ti addition.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2023)
Article
Chemistry, Physical
Y. C. Liao, T. H. Li, P. H. Tsai, J. S. C. Jang, K. C. Hsieh, C. Y. Chen, J. C. Huang, H. J. Wu, Y. C. Lo, C. W. Huang, I. Y. Tsao
Article
Materials Science, Multidisciplinary
Y. C. Liao, S. M. Song, T. H. Li, P. H. Tsai, C. Y. Chen, J. S. C. Jang, J. P. Chu, C. M. Tseng
MATERIALS CHEMISTRY AND PHYSICS
(2020)
Article
Nanoscience & Nanotechnology
X. K. Zhang, J. C. Huang, P. H. Lin, W. S. Chuang, T. Y. Liu, Y. C. Wu, Y. C. Liao, Jason S. C. Jang
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2020)
Article
Materials Science, Multidisciplinary
Y. C. Liao, S. M. Song, T. H. Li, J. B. Li, P. H. Tsai, J. S. C. Jang, C. H. Huang, J. C. Huang, Y. S. Huang, C. H. Lin, Y. S. Lin, C. H. Chen
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2020)
Article
Chemistry, Physical
X. K. Zhang, J. C. Huang, P. H. Lin, T. Y. Liu, Y. C. Wu, W. P. Li, Y. N. Wang, Y. C. Liao, Jason S. C. Jang
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Materials Science, Multidisciplinary
Pei-Hua Tsai, Chung- Lee, Sin-Mao Song, Yu-Chin Liao, Tsung-Hsiung Li, Jason Shian-Ching Jang, Jinn P. Chu
Article
Chemistry, Analytical
Cheng-Tang Pan, Che-Hsin Lin, Ya-Kang Huang, Jason S. C. Jang, Hsuan-Kai Lin, Che-Nan Kuo, De-Yao Lin, Jacob C. Huang
Summary: Intervertebral fusion surgery is a major operation for spinal trauma, degeneration, and deformity correction. Most fusion cages have high stiffness, leading to stress concentration and shielding effects. Using a porous structure in fusion cages can reduce stiffness and improve strength for surrounding tissues. The study designed a porous gradient structure intervertebral cage and evaluated it through simulations and mechanical property testing.
Article
Chemistry, Physical
Y. C. Liao, W. T. Ye, P. S. Chen, P. H. Tsai, J. S. C. Jang, K. C. Hsieh, C. Y. Chen, J. C. Huang, H. J. Wu, Y. C. Lo, C. W. Huang, I. Y. Tsao
Summary: By utilizing the CALPHAD method, a series of Ti60(Al)x(VCrNb)40-x medium-entropy alloys were designed and produced, showing a decrease in density with increasing Al concentration and the formation of nanosized B2 phase at higher Al concentrations. The alloys with BCC structure exhibited excellent compressive ductility, but the tensile properties were influenced by different Al concentrations, resulting in a decrease in plastic strain with increasing Al concentration.
Article
Chemistry, Physical
Po-Sung Chen, Yu-Chin Liao, Yen-Ting Lin, Pei-Hua Tsai, Jason S. C. Jang, Ker-Chang Hsieh, Chih-Yen Chen, Jacob C. Huang, Hsin-Jay Wu, I-Yu Tsao
Summary: Most high-entropy alloys and medium-entropy alloys exhibit excellent mechanical properties. In this study, lightweight nonequiatomic Al-50-Ti-Cr-Mn-V MEAs with a dual phase structure were prepared, showing outstanding compressive strength and ductility. Through alloy composition optimization and heat treatment, a significant improvement in compressive properties was achieved, making these MEAs promising for future energy or transportation applications.
Article
Chemistry, Physical
Chi-Hua Yu, Guan-Hua Huang, Wei-Tang Huang, Chang-Wei Huang, Yu-Chieh Lo, Zih-Jie Hung, Yu-Chin Liao, Jason Shian-Ching Jang, Hsuan-Teh Hu
Summary: In this study, a crystal plasticity finite element model (CPFEM) was employed to investigate the strengthening mechanisms of a new medium-entropy alloy, Ti-65(AlCrNb)(35). The results showed that grain size, strain rate, and cyclic loading have significant effects on the strength of Ti-65(AlCrNb)(35).
Article
Chemistry, Physical
Y. C. Liao, P. S. Chen, P. H. Tsai, J. S. C. Jang, K. C. Hsieh, H. W. Chang, C. Y. Chen, J. C. Huang, H. J. Wu, Y. C. Lo, C. W. Huang, I. Y. Tsao
Summary: In this study, the Ti-65 alloy was processed through a series of thermomechanical treatments, which resulted in significant grain refinement and enhancement of tensile strength, demonstrating good strength-ductility synergy.
Article
Chemistry, Physical
Po-Sung Chen, Sheng-Jia Shiu, Pei-Hua Tsai, Yu-Chin Liao, Jason Shian-Ching Jang, Hsin-Jay Wu, Shou-Yi Chang, Chih-Yen Chen, I-Yu Tsao
Summary: This study explores the use of lightweight nonequiatomic MEAs with Zr additions to achieve high strength and high ductility properties. The Ti-65(AlCrNbV)(28)Zr-7 MEAs demonstrated an optimum combination of mechanical properties after undergoing hot rolling, cold rolling, and rapid annealing. With their high specific yield strength and ductility, these MEAs have considerable potential for energy and transportation applications.
Article
Chemistry, Physical
Po-Sung Chen, Pei-Hua Tsai, Tsung-Hsiung Li, Jason Shian-Ching Jang, Jacob Chih-Ching Huang, Che-Hsin Lin, Cheng-Tang Pan, Hsuan-Kai Lin
Summary: Ti-based metallic glasses have high potential for implant applications. A new biocompatible Ti-based bulk metallic glass composite was successfully fabricated through selective laser melting. The study demonstrates that the TiZrSiCoSnTa system shows promise for preparing biocompatible metallic glass composites into complicated graded foam shapes using additive manufacturing.
Article
Nanoscience & Nanotechnology
P. H. Lin, J. C. Huang, X. K. Zhang, H. S. Chou, W. S. Chuang, T. Y. Liu, Y. C. Liao, J. S. C. Jang
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2020)