4.5 Article

UV and Visible Light Induced Photocatalytic Degradation on p-n Cu2O/ZnO Nanowires Decorated with Au-Pd Alloy Nanoparticles

Journal

ADVANCED MATERIALS INTERFACES
Volume 6, Issue 6, Pages -

Publisher

WILEY
DOI: 10.1002/admi.201801744

Keywords

Au-Pd alloy nanoparticles; blue-light-emitting diode; Cu2O; ZnO nanowires; photocatalytic degradation; UV-light-emitting diode

Funding

  1. Ministry of Science and Technology, Taiwan
  2. MOST [107-2221-E-024-009-MY2]

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Chemical solutions are applied to synthesize Au-Pd alloy nanoparticles (NPs) and ZnO/Cu2O core-shell nanowires (NWs) on ITO/glass substrates by the photochemical, electrochemistry, and hydrothermal methods. The Cu2O cubic structures and ZnO hexagonal wurtzite structures are verified as being polycrystalline and single crystalline, respectively, by X-ray diffraction and high-resolution transmission electron microscopy (HR-TEM). The p-Cu2O/n-ZnO NWs samples exhibit rectification properties that confirm the p-n heterojunction interface. The diameter range of the Au-Pd alloy NPs is around 2-15 nm and the Au/Pd ratio is 27:28, according to HR-TEM and X-ray photoelectron spectroscopy. The p-Cu2O/n-ZnO core-shell NWs feature higher UV photocatalytic degradation of methylene blue than do the ZnO NWs. Deposited Au, Pd, Au-Pd alloy NPs on the p-Cu2O/n-ZnO core-shell NWs improve the photocatalytic degradation efficiency under UV and blue light. The Au-Pd alloy NPs/p-Cu2O/n-ZnO core-shell NWs offer the best photocatalytic properties under UV- and blue-light-emitting diode (LED) illumination.

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