Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 36, Pages 10904-10908Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604348
Keywords
DFT calculations; halogen-halogen bonding; ionic liquids; polychlorides; solid-state structures
Categories
Funding
- DFG-GRK [1582]
Ask authors/readers for more resources
The polychloride salt [CCl(NMe2)(2)](+)(2)[Cl-8](2-) was synthesized and crystallized in the ionic liquid [BMP]OTf. The compound was fully characterized by Raman spectroscopy as well as X-ray single-crystal structure determination, and represents the first example of a polychloride dianion to be described. Detailed gas-phase and solid-state calculations concerning the nature of the bonding situation were also performed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
