Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 33, Pages 9671-9675Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201605337
Keywords
cyclizations; diazo compounds; indoles; spirocycles; synthetic methods
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Funding
- University of York
- Leverhulme Trust [ECF-2015-013]
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Indolyl alpha-diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of catalysts were used, including complexes of Rh-II, Pd-II, and C-uII, as well as SiO2, to promote diazo decomposition and subsequent cyclization/rearrangement through a range of mechanistic pathways.
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