Journal
PURE AND APPLIED CHEMISTRY
Volume 91, Issue 5, Pages 839-849Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2018-0926
Keywords
colloid stabilization; copper(I) complexes; cyclic aminomethylphosphines; gold(I) complexes; ICPC-22; sensors for biothiols; stimuli responsive luminescence; thermochromism; vapochromism
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A variety of gold(I) and copper(I) complexes based on heterocyclic phosphine platform has been obtained. Due to the presence of exocyclic chromophoric pyridyl groups in the ligands complexes demonstrate noticeable phosphorescence. Cyclic nature of the phosphine ligands is responsible for supramolecular host-behavior of the complexes. Unique structure of complexes on a scaffold of the cyclic PNNP ligands favors the stimuli-induced structural reorganizations followed by stimuli-responsive luminescence. This, in turn, makes the complexes versatile building blocks for bottom-up design of smart nanomaterials for analytical and biomedical applications.
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