Journal
ORGANIC LETTERS
Volume 21, Issue 7, Pages 2126-2129Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00426
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Funding
- Ministry of Science and Technology of the People's Republic of China [2016YFA0602900]
- NSFC [21871096, 21672071]
- Guangdong Science and Technology Department [2018B030308007, 2018A030310359, 2016A030310433]
- Science and Technology Program of Guangzhou [201707010316]
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A catalyst-free domino reaction to synthesize highly functionalized indanone-fused tetrahydroisoxazole from easily accessed nitrosoarene and 1,6-ynenone with good chemo- and regioselectivity was disclosed. This unprecedented domino reaction represents a new strategy for multifunctionalization of an internal alkyne with nitrosoarene by formation of two rings and four bonds in a single operation.
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