Journal
ORGANIC LETTERS
Volume 21, Issue 5, Pages 1342-1346Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00030
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Funding
- JSPS KAKENHI [JP 17H03016, JP 18H04656]
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The meta-selective introduction of functional groups into aromatic substrates was successfully achieved by hydrogen-bond-controlled meta-selective C-H borylation and successive conversion of the boryl group to other functional groups. By this method a wide range of functional groups could be introduced without isolation of the borylated intermediates. The desired meta-functionalized aromatic products were obtained in a one-pot manner even on a gram scale. Regioselective synthesis of multisubstituted aromatic compounds was also achieved.
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