Journal
ORGANIC LETTERS
Volume 21, Issue 4, Pages 1042-1045Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b04073
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Funding
- National Natural Science Foundation of China [21572131, 21620102003, 21831005]
- Shanghai Municipal Education Commission [201701070002E00030]
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The asymmetric hydrogenation of silylimines was first developed by using a palladium complex of a P-stereogenic diphosphine ligand as the catalyst, affording the valuable chiral alpha-aminosilanes with quantitative conversions and excellent enantioselectivities (up to 99% ee).
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