Journal
ORGANIC ELECTRONICS
Volume 65, Issue -, Pages 135-140Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2018.11.015
Keywords
Perovskite solar cells; Dopant-free; Hole transport material; Phenanthrenone
Funding
- National Key R&D Program of China [2016YFB0400703]
- National Natural Science Foundation of China [21472135]
- Natural Science Foundation of Jiangsu Province of China [BK20151216]
- Collaborative Innovation Center of Suzhou Nano Science and Technology (CIC-Nano), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Key Research and Development Plan of Shaanxi Province [2017ZDCXL-GY-06-03]
- Special Scientific Research Plan of Shaanxi Provincial Education Department [17JK0095]
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Spiro-OMeTAD is the most popular hole transport material (HTM) for perovskite solar cells. The insertion of one carbonyl group into the spirobifluorene framework in spiro-OMeTAD gave a novel phenanthrenone-based hole transport material (spiro-PT-OMeTAD). It is found that the introduction of one carbonyl group into spiro-PTOMeTAD led to a big difference in the absorption behaviors, frontier molecular orbital energy levels and hole mobilities. The steady-state photoluminescence characterization and the space-charge-limited-current measurement indicate that this phenanthrenone-based material plays an important role in hole collection and transportation in perovskite solar cells. As a result, the dopant-free perovskite solar cells based on spiro-PTOMeTAD showed highly improved performance by exhibiting a short-circuit current density of 22.36 mA/cm(2), an open-circuit voltage of 0.99 V, and a fill factor of 0.62% under 1 sun illumination, which gave an overall power conversion efficiency (PCE) of 13.83%, compared to 10.5% for the spiro-OMeTAD based devices.
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