4.6 Article

Amorphous germanium oxide nanobubbles for lithium-ion battery anode

Journal

MATERIALS RESEARCH BULLETIN
Volume 110, Issue -, Pages 24-31

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2018.10.007

Keywords

Amorphous GeOx; Citric acid; Hydrothermal; Anode; Lithium-ion batteries

Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIP)

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Germanium (Ge) is a promising anode material for lithium-ion batteries (LIBs) due to its large theoretical specific capacity (1600 mA h g(-1)), high Li diffusivity and large intrinsic electrical conductivity. Despite these merits, its large volumetric change during lithiation/delithiation process and relatively high production cost make it difficult to use in commercial batteries. In this paper, we report a facile, easy to scale up, and environmentally friendly method to prepare an amorphous phase GeOx (x < 1) hollow composite at a hydrothermal condition using an aqueous precursor solution containing GeO2 particles, and citric acid. The citric acid induces gas bubble templates and frameworks to improve the structural strain for Li+ ion conduction during cycling. The resulting GeOx-C hallow composite anode shows enhanced cyclability with a reversible capacity of 930 mA h g(-1) after 100 cycles at a current density of 0.3 C.

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