Review
Polymer Science
Anja Marinow, Zviadi Katcharava, Wolfgang H. H. Binder
Summary: The integration of self-healing polymer materials into advanced lithium batteries shows promise in improving battery performance and reliability. These materials can repair damage to the electrolyte, prevent electrode cracking and pulverization, and stabilize the solid electrolyte interface (SEI), leading to longer battery lifetimes and addressing financial and safety concerns.
Article
Materials Science, Multidisciplinary
Yue Qi, Xinqian Zeng, Liangping Xiao, Xingyun Li, Honggang Liao, Qingchi Xu, Jun Xu
Summary: In this study, ultrathin two-dimensional amorphous TiO2 porous nanosheet aerogel was successfully synthesized, and improved electrochemical performance was achieved through an optimized assembly method.
SCIENCE CHINA-MATERIALS
(2022)
Article
Chemistry, Physical
Ryan S. Longchamps, Xiao-Guang Yang, Shanhai Ge, Teng Liu, Chao-Yang Wang
Summary: By utilizing a self-heating structure, the huge potential of current battery materials can be unleashed to provide high energy and power performance in extreme low-temperature conditions. The heating process efficiently increases the battery temperature with minimal energy consumption. The chemistry-agnostic nature of self-heating can enhance the rate capability of lithium-ion and lithium metal batteries, expanding the performance envelopes of battery materials for electrified transportation.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Yong Wang, Hui Xu, Xi Chen, Hong Jin, Jiping Wang
Summary: The elastic self-healing CA-PAA binder designed for silicon anodes can accommodate large volume changes and maintain high performance during cycling.
ENERGY STORAGE MATERIALS
(2021)
Article
Energy & Fuels
Janghyuk Moon
Summary: Understanding the role of oxygen content in silicon suboxides (SiOx) is crucial for improving their performance as negative electrode materials for Li-ion batteries. Adjusting the oxidation of silicon suboxides for use as anodes has not been extensively studied. Our research demonstrates the importance of tailoring the oxygen content for desired lithiation properties in SiOx, leading to differences in volume change and voltage profiles with lithiation.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Physical
Hongmei Liu, Qingping Wu, Xiang Guan, Mian Liu, Fei Wang, Ruijiang Li, Jun Xu
Summary: Researchers have designed and synthesized a self-healing polymer binder (PAA-TUEG) that improves the electrochemical performance and cycle life of silicon anode materials. This binder combines high Li-ion conductivity and self-healing ability, offering a new approach for next-generation batteries using high-capacity materials.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Electrochemistry
K. K. Rajeev, Jaebin Nam, Wonseok Jang, Yeonho Kim, Tae-Hyun Kim
Summary: The study explores the use of crosslinked glycol chitosan as a polymer binder for silicon anodes in lithium-ion batteries, showing excellent electrochemical performance, rate performance, and cycling stability. The binder forms a strong and dynamic covalent bonding to effectively buffer the volume changes in the silicon anodes during battery cycling, demonstrating great potential for practical applications in LIBs.
ELECTROCHIMICA ACTA
(2021)
Article
Engineering, Chemical
Takafumi Hanada, Kosuke Seo, Wataru Yoshida, Adroit T. N. Fajar, Masahiro Goto
Summary: By utilizing density functional theory calculations, this study investigated novel extractants derived from amino acids to improve the separation of Ni and Co in lithium-ion battery recycling processes. The research demonstrated the effectiveness of the glycine-derived amic-acid extractant for the recovery of Ni and Co, providing insights into the design of extractants for mutual separation of Ni, Co, and Mn in recycling processes. This study highlights the potential of amic-acid extractants for enhancing the efficiency and environmental friendliness of LiB recycling.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Analytical
Jing Geng, Zhengguang Zou, Tianxing Wang, Shuchao Zhang, Shenglin Zhong, Wenqin Ling, Xiaoxiao Peng, Xixi Hu
Summary: Mn and K co-doped lithium iron phosphate (LFP) cathode materials were successfully synthesized by solvothermal method. The contributions of the two dopants to the LFP were investigated using density functional theory (DFT) calculations and various characterizations. The presence of Mn improved the energy band and diffusion kinetics, while K contributed to the stabilized structure and widened diffusion channel. The co-doped LFP cathode exhibited a high capacity of 145 mAhmiddotg-1 at 5 C and maintained a 96% retention rate after 400 cycles. The interaction between the two doping elements was discussed by comparing with a control group, and the KLMFP samples showed superior electrochemical performance in cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge-discharge cycling tests.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Junkai Zhao, Daina Wei, Jianjun Wang, Kaimeng Yang, Zhaolong Wang, Zhengjian Chen, Shiguo Zhang, Ce Zhang, Xiaojing Yang
Summary: In this study, a three-dimensional self-healing binder (PVA + LB) composed of polyvinyl alcohol and lithium metaborate solution is proposed to improve the cycle stability of Si-based lithium-ion batteries. The use of PVA + LB as a binder results in maintained reversible capacity and excellent electrochemical performance of silicon electrodes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Hao Chen, Zhenzhen Wu, Zhong Su, Su Chen, Cheng Yan, Mohammad Al-Mamun, Yongbing Tang, Shanqing Zhang
Summary: Silicon is considered the most promising anode material for next-generation lithium ion batteries, but silicon particles undergo volume changes and pulverization during charge/discharge processes, damaging the longevity of silicon anodes. This study synthesized a novel self-healing binder to repair the damage to silicon anodes, achieving excellent electrochemical performance.
Article
Chemistry, Physical
Rakesh Parida, Jin Yong Lee
Summary: This article explores the potential of boron based molecules as electrolyte additives in lithium ion batteries to increase conductivity and solid electrolyte interface formation. The efficacy of a new class of B-based podand molecule as an anion receptor additive is studied using DFT and MD simulation. Results show that the designed additive is more efficient in binding PF6- ion, promoting the diffusion of Li+ and lowering viscosity under various conditions. This research holds promise for the development of more efficient and effective energy storage solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Zhen Zhang, Natasha Ghezawi, Bingrui Li, Sirui Ge, Sheng Zhao, Tomonori Saito, Diana Hun, Peng-Fei Cao
Summary: This study presents a series of autonomous self-healable and highly adhesive elastomers with outstanding mechanical properties and ultrahigh adhesion force. The elastomers can self-heal autonomously with full recovery of functionalities and demonstrate resilience to water during the healing process. They also exhibit negligible sensitivity to dust on surfaces, distinguishing them from regular adhesive polymers. These high-toughness, autonomous self-healable, and ultra-adhesive elastomers open up new possibilities for applications in various fields.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
S. Davino, D. Callegari, D. Pasini, M. Thomas, I. Nicotera, S. Bonizzoni, P. Mustarelli, E. Quartarone
Summary: Next-generation Li-ion batteries need to have improved durability, quality, reliability, and safety to meet the stringent technical requirements of crucial sectors like e-mobility. One approach to overcome degradation is the use of advanced materials with self-healing properties, such as the gel electrolyte proposed in this study.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Fei Wang, Xiang Ma, Yiren Li, Hongmei Liu, Qingping Wu, Xiang Guan, Hui Liu, Xiao Xia Wang, Jun Xu
Summary: This study reports the synthesis of room-temperature rapid self-healing polymer binders (Al/Alg-TUEG) via dynamic coordination bonds (Al-O) and hydrogen bonds. The prepared polymer binders exhibit excellent properties with a peeling force of 4.2 N, a swelling ratio of 9.5%, and a recovery of 90% in 2 hours at room temperature. The Si@Al/Alg-TUEG anodes show stable cycling for 300 cycles at 0.5 C with a capacity retention rate of 77.4%, indicating their potential as binder candidates for high-energy-density lithium-ion batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Guoqiang Zhang, Yangsen Xu, Guoshuai Liu, Yongliang Li, Chuanxin He, Xiangzhong Ren, Peixin Zhang, Hongwei Mi
Summary: The strong Coulomb interactions in crystalline carbon nitride hinder the dissociation of Frenkel excitons, leading to inefficient charge separation and photocatalytic efficiency. To address this issue, a strategy is proposed to induce a built-in electric field (BIEF) through molecular regulation. By changing the charge density distribution, the BIEF overcomes the high exciton binding energy (EBE) and significantly improves the exciton dissociation efficiency (EDE) from 21.5% to 51.9%. This study establishes a method to enhance exciton dissociation in polymer photocatalysts by molecular regulation-induced BIEF.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Wang Suhang, Zuo Jinxinl, Li Yongliang, Zhong Yiming, Ren Xiangzhong, Zhang Peixin, Sun Lingna
Summary: In this study, a Fe2O3-MWNTs composite with a reinforced concrete structure was fabricated using a sol-gel process and high-temperature in situ sintering. With the designed reinforced concrete construction, the composite showed excellent electrochemical performance, making it a promising anode material for high-performance lithium-ion batteries.
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
(2023)
Article
Chemistry, Multidisciplinary
Huimin Wang, Changhong Wang, Matthew Zheng, Jianneng Liang, Ming Yang, Xingyu Feng, Xiangzhong Ren, Denis Y. W. Yu, Yongliang Li, Xueliang Sun
Summary: A solid-state sandwich electrolyte is designed for Cu-Li batteries to overcome the limited solubility and shuttle effect of Cu ions. The solid-state Cu-Li battery demonstrates a high energy density and long-term cyclability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Shenghua Ye, Shuhua Xie, Yaqi Lei, Xiuyuan Yang, Jing Hu, Lirong Zheng, Zhida Chen, Yonghuan Fu, Xiangzhong Ren, Yongliang Li, Xiaoping Ouyang, Qianling Zhang, Jianhong Liu, Xueliang Sun
Summary: In this study, dual-metal atomic pairs of Mn-Fe binuclear sites anchored onto a graphite-like structure were constructed. The strong short-range electronic interaction between Mn and Fe sites in the binuclear structure transforms Fe sites to a high spin state, improving the oxygen reduction reaction performance of the Mn-Fe structure.
Correction
Chemistry, Multidisciplinary
Zhisen Zeng, Yuehong Zeng, Lingna Sun, Hongwei Mi, Libo Deng, Peixin Zhang, Xiangzhong Ren, Yongliang Li
Summary: This study achieved long cyclic stability of acidic aqueous zinc-ion batteries by atomic layer deposition and investigated the effect of the induced orientation growth of the Zn anode on their performance.
Correction
Chemistry, Physical
Muhammad Rauf, Ling Yang, Jingwen Wang, Hongwei Mi, Qianling Zhang, Peixin Zhang, Xiangzhong Ren, Yongliang Li
Summary: This article investigates the manipulation of oxygen evolution reaction kinetics of a free-standing CoSe2-NiSe2 heterostructured electrode by interfacial engineering. The results demonstrate that by adjusting the composition and structure of the electrode, catalytic activity and stability can be significantly improved.
SUSTAINABLE ENERGY & FUELS
(2023)
Review
Chemistry, Multidisciplinary
Wenda Chen, Xiuyuan Yang, Zhida Chen, Zhijun Ou, Jiangtao Hu, Yuan Xu, Yongliang Li, Xiangzhong Ren, Shenghua Ye, Jieshan Qiu, Jianhong Liu, Qianling Zhang
Summary: Electrochemical NO3-RR can store renewable electric energy and green hydrogen into NH3, providing a potential solution for green hydrogen storage and transportation.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Electrochemistry
Yuehong Zeng, Huiming Wang, Muhammad Rauf, Hongwei Mi, Lingna Sun, Qixing Wu, Qianling Zhang, Xiangzhong Ren, Yongliang Li
Summary: In this study, a synergistic effect between carbon nanotube (CNT) network and atomic layer deposition (ALD) of TiO2 is reported. The CNTs and TiO2 work together to capture zinc ions and suppress dendrite growth, resulting in uniform deposition during repeated cycles. The modified anode (TiO2-CNT@Zn anode) exhibits high plating/stripping reversibility and ultralong lifespan. Furthermore, the Zn-MnO2 battery with the TiO2-CNT@Zn anode shows enhanced cycling stability.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Xianliang Li, Tingyi Zhou, Zhaoyan Luo, Lei Zhang, Zhiheng Ren, Qianling Zhang, Chuanxin He, Xiantao Jiang, Yongliang Li, Xiangzhong Ren
Summary: A novel high-performance bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries is constructed based on bimetal Mn@Co-N-C encapsulated in in situ grown N,S-doped graphitic carbon framework with a porous three-dimensional (3D) structure. The catalyst exhibits a high half-wave potential for oxygen reduction reaction and a low operating overpotential for oxygen evolution reaction. Both liquid electrolyte-based and all-solid-state batteries assembled with this catalyst show excellent charging-discharging performance, long lifetime, and high flexibility.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Nanoscience & Nanotechnology
Qingying Zhu, Guoyong Yang, Limin Tang, Hongwei Mi, Lingna Sun, Qianling Zhang, Libo Deng, Peixin Zhang, Xiangzhong Ren, Yongliang Li
Summary: In order to improve the efficiency of oxygen evolution reaction, researchers synthesized a heterostructured electrocatalyst by depositing iron oxides on carbon cloth via plasma-enhanced atomic layer deposition, and then growing cobalt oxide nanosheet arrays. This electrocatalyst exhibited excellent electrocatalytic performance for OER in alkaline solution. This design and optimization strategy provides a promising way for the synthesis of ideally designed catalytic architectures for energy storage and conversion applications.
Article
Nanoscience & Nanotechnology
Sundaram Chandrasekaran, Rong Hu, Lei Yao, Lijun Sui, Yongping Liu, Amor Abdelkader, Yongliang Li, Xiangzhong Ren, Libo Deng
Summary: We successfully fabricated bifunctional M-N-C catalysts for rechargeable zinc-air batteries using a new class of metal-organic framework. These catalysts exhibited excellent alkaline oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities, with lower overpotentials and half-wave potentials compared to commercial Pt/C catalysts. The strong electronic correlation between metallic Co nanoparticles and atomic Co-N-4 sites in the catalysts enhanced the adsorption/desorption of intermediates in ORR/OER, resulting in improved bifunctional electrocatalytic performance. The Co@C-CoNC-based rechargeable zinc-air battery showed high power density and stability during discharge.
NANO-MICRO LETTERS
(2023)
Review
Chemistry, Physical
Zhongxin Song, Junjie Li, Qianling Zhang, Yongliang Li, Xiangzhong Ren, Lei Zhang, Xueliang Sun
Summary: A fuel cell is an energy conversion device that continuously releases electrical energy through electrochemical reactions. Single-atom catalysts (SACs) with 100% atom utilization efficiency have shown remarkable performance in fuel cells, saving costs. This review introduces the synthesis and application of SACs, providing experiences for the development of potential industrialized fuel cell catalysts in the future.
Article
Chemistry, Multidisciplinary
Yishu Li, Xiaodan Yang, Yan He, Fan Li, Kefeng Ouyang, Dingtao Ma, Juan Feng, Jiali Huang, Jinlai Zhao, Ming Yang, Yanyi Wang, Yangsu Xie, Hongwei Mi, Peixin Zhang
Summary: A novel ultrathin polymer electrolyte with significantly enhanced multiple kinetics is developed using a densified polyacrylonitrile/silicon dioxide nanofiber membrane as a mediator. It exhibits excellent mechanical properties and high-temperature structural stability, enabling reversible zinc metal anodes at elevated temperatures.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Engineering, Environmental
Xue Ye, Jianneng Liang, Jiangtao Hu, Dazhuan Wu, Yongliang Li, Xiaoping Ouyang, Qianling Zhang, Xiangzhong Ren, Jianhong Liu
Summary: To achieve safe and high energy density solid-state batteries (SSBs), minimizing the weight of solid-state electrolyte (SSE) and using a high voltage and high specific capacity cathode are crucial. An ultra-thin blending polymer electrolyte (BPE) is designed by blending PEO, PMMA, and PVDF-HFP, and complexing with SN, FEC, and LiTFSI plasticizers. The BPE shows superior performance in terms of capacity retention, stability, and Coulombic efficiency, indicating its promising application in high energy density quasi-solid-state batteries (QSSBs).
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Shenghua Ye, Shuhua Xie, Yaqi Lei, Xiuyuan Yang, Jing Hu, Lirong Zheng, Zhida Chen, Yonghuan Fu, Xiangzhong Ren, Yongliang Li, Xiaoping Ouyang, Qianling Zhang, Jianhong Liu, Xueliang Sun
Summary: In this study, dual-metal atomic pairs of Mn-Fe binuclear sites were constructed, which exhibited strong short-range electronic interaction and improved oxygen reduction reaction performance.
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)