Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 57, Issue 7, Pages 799-805Publisher
WILEY
DOI: 10.1002/pola.29328
Keywords
polyaddition; poly(urethane); vicinal diol; thermal and mechanical properties
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Funding
- JSR Co., Ltd.
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We describe the utilization of four kinds of diol derivatives, representing structural similarity to the well-known and commercially available vinyl monomers such as acrylate, acrylamide, styrene, and N-substituted maleimide. The vinyl monomers are readily converted by dihydroxylation reaction to afford the vicinal diol. The synthesis of poly(urethane)s was performed by the reaction of the vicinal diol with two model diisocyanates, including methylene diphenyl isocyanate (MDI) and hexamethylene diisocyanate (HDI) in the presence of dibutyltin dilaurate to form a series of poly(urethane)s, and the effect of vicinal diol containing a side chain inherited from vinyl monomers on their thermal and mechanical properties was investigated using thermogravimetric analysis, differential scanning calorimetry, and tensile test. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 799-805
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