Article
Energy & Fuels
Shuai Zhao, Wan-Fen Pu, Lei Su, Ce Shang, Yang Song, Wei Li, Hui-Zhuo He, Yi-Gang Liu, Zhe-Zhi Liu
Summary: This study investigated the combustion of oxidized and pyrolyzed cokes, finding that the former can combust at lower temperatures due to differences in molecular polarity and microstructure. By determining the kinetic triplets of coke combustion, along with the most appropriate reaction models for each type of coke, the research contributed to building numerical models for simulating the in-situ combustion process.
Article
Energy & Fuels
Yanhong Wang, Yongzhao Zhou, Shuanshi Fan, Xuemei Lang, Gang Li
Summary: The coking characteristics of heavy oil play a crucial role in the in situ combustion process. After low temperature oxidation, the pyrolysis coking characteristics of heavy oil change significantly, resulting in a higher coke yield but lower oxidation activity and heat value.
Article
Energy & Fuels
Yi-Bo Li, Shi-Xing Zhang, Chen Luo, Shuai Zhao, Bing Wei, Wan-Fen Pu
Summary: The success of the in situ combustion process depends on the stability and movement of the combustion front. The study found that coke deposition in porous media significantly affects porosity and subsequent air injection. Oxidized coke causes more damage to porosity due to drastic low-temperature oxidation, while pyrolyzed coke has a limited impact on porosity. Montmorillonite has the strongest catalytic effect on coke deposition, while other minerals also influence coke deposition.
Article
Energy & Fuels
Ya-fei Chen, Hong Yin, Dong-lin He, Hai-feng Gong, Zhe-zhi Liu, Yun-qi Liu, Xian-ming Zhang, Wan-fen Pu
Summary: This study investigates the evolution of low temperature oxidized coke generated from the pyrolysis of ultra-heavy oil during in-situ combustion. The results show that low temperature oxidation leads to the formation of oxidation groups and promotes the evolution of aromatic structures and functional groups. Additionally, low temperature oxidation reactions have a significant impact on the morphology, oxidizability, and exothermicity of the coke.
Article
Energy & Fuels
Xianghui Zhang, Junjie Wang, Ling Wang, Zhongquan Li, Wei Hu, Yanqiu Dai, Yuanyu Kou, Shengjun Lei, Qian Li, Wen Zhang, Hongkui Li, Ruyan Wang, Qian Feng
Summary: Clay minerals like montmorillonite play a significant role in storing and recovering petroleum. Montmorillonite, a natural solid acid catalyst, has the ability to catalyze heavy oil oxidation during in-situ combustion. The catalytic activity of montmorillonite depends on the heating process of heavy oil, particularly in the high-temperature oxidation stage. Dehydration of interlayer water in montmorillonite has the strongest catalytic effect on heavy oil oxidation.
Article
Energy & Fuels
Shuai Ma, Yun-Yun Li, Ri-Gu Su, Xu-Sheng Wang, Jing-Jun Pan, Quan Shi, Guang-Zhi Liao, Chun-Ming Xu
Summary: In this study, the low-temperature oxidation (LTO) process of heavy oil was investigated by subjecting it to LTO reactions at different temperatures. The reaction products were characterized and analyzed to reveal the changes in molecular compositions and oxidation pathways. The experimental results showed that the oxidation reaction of heavy oil shifted from kinetic-controlled to diffusion-controlled as the oxidation depth increased. The oxidation reaction reached a maximum and stable value in oxygen content. The compositions of ketone compounds and acid polyoxides in the oil phase did not change significantly with further increase in reaction temperature, while the compositions of deep oxidation products in the coke phase changed significantly. The findings are important for combustion propulsion and crude oil extraction.
Article
Energy & Fuels
Seyedsaeed Mehrabi-Kalajahi, Mikhail A. Varfolomeev, Chengdong Yuan, Almaz L. Zinnatullin, Nikolay O. Rodionov, Farit G. Vagizov, Yuri N. Osin, Luidmila S. Yakimova
Summary: Bimetallic oxide CoFe2O4 nanoparticles were synthesized and coated with oleic acid to form oil-dispersed catalyst for accelerated heavy oil oxidation. The catalytic activity of CoFe2O4@oleic acid nanoparticles was higher than CoFe2O4, promoting the heavy oil oxidation process.
Article
Engineering, Chemical
Ilgiz F. Minkhanov, Alexander V. Bolotov, Aidar R. Tazeev, Vladislav V. Chalin, Anini Franck D. Kacou, Ranel I. Galeev, Rustam N. Sagirov, Ameen A. Al-Muntaser, Dmitrii A. Emelianov, Mohammed Amine Khelkhal, Mikhail A. Varfolomeev
Summary: Thermally enhanced oil recovery methods, such as in situ combustion and steam injection, are important for improving oil reserve exploitation and meeting oil demand and economic growth. Challenges in these methods include early breakthrough of the combustion front and heat loss in deeper reservoirs. More data and research are needed on the effects of reservoir properties on the combustion front and heat transfer efficiency. This study investigates the role of interlayers' minerals in stabilizing the combustion front and suggests that clay dispersion can improve oil recovery.
Article
Chemistry, Physical
Xianghui Zhang, Junjie Wang, Ling Wang, Zhongquan Li, Ruyan Wang, Hongkui Li, Ming Luo, Huiyu Liu, Wei Hu, Qian Feng
Summary: Kaolinite has a catalytic effect on the oxidation of heavy oil, which is dependent on its thermal transformation. It significantly affects the HTO and FD stages of heavy oil oxidation, but has little influence on the LTO stage.
APPLIED CLAY SCIENCE
(2022)
Article
Energy & Fuels
Yunyun Li, Guangzhi Liao, Zhengmao Wang, Rigu Su, Shuai Ma, Hui Zhang, Liangang Wang, Xusheng Wang, Jingjun Pan, Quan Shi
Summary: This study investigated the molecular changes associated with coke formation during in-situ combustion (ISC) by conducting a thermal oxidation experiment on heavy crude oil. The results showed that oxidation and thermal cracking are both important reactions in the simulated ISC process, and the molecular composition provides valuable insights into the behavior of coke formation from crude oil.
Article
Energy & Fuels
Chengdong Yuan, Dmitrii A. Emelianov, Mikhail A. Varfolomeev, Nikolay O. Rodionov, Muneer A. Suwaid, Iskander R. Vakhitov
Summary: In this study, copper (II) stearate was introduced as an oil-soluble catalyst for heavy oil oxidation in in-situ combustion process, leading to a significant reduction in activation energy and improved formation rate and quality of coke-like residues, thereby enhancing the efficiency of heavy oil recovery in in-situ combustion process.
Article
Energy & Fuels
Liangliang Wang, Tengfei Wang, Yao Zhang, Xiaoqiang Peng, Wei Song, Jinshun Yang, Chengdong Yuan
Summary: The thermo-oxidative characteristics and kinetics of HQ heavy oil were studied using TG-DSC-FTIR-MS technique. The oxidation reactions of HQ heavy oil were divided into low temperature oxidation, fuel deposition, and high temperature combustion stages. The reaction mechanisms were analyzed using FTIR and MS analysis. The obtained data provide important references for understanding crude oil oxidation mechanism and simulating ISC processes accurately.
Article
Energy & Fuels
Evgeny Popov, Aysylu Askarova, Aliya Mukhametdinova, Kirill Maksakov, Gennadiy Usachev, Viktor Darishchev, Sudarshan A. Mehta (Raj), Alexey Cheremisin
Summary: This study evaluated the applicability of ISC technology in a heavy oil carbonate field through experiments, considering factors such as initial oil saturation and combustion parameters. The results showed that ISC technology is feasible within a specific range of oil saturation levels.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2021)
Article
Energy & Fuels
Junjie Wang, Xianghui Zhang, Wei Hu, Ling Wang, Zhongquan Li, Yanqiu Dai, Yuanyu Kou, Shengjun Lei, HongKui Li, Qian Feng
Summary: In situ combustion (ISC) is an effective method for enhancing heavy oil (HO) recovery. However, the reliability of thermal analysis (TA) data has been affected by the adhesion of high viscosity HO to the substrate and crucible. This study aimed to identify factors impacting TA data reliability and improve the accuracy and reproducibility of TA data for future ISC.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
(2023)
Article
Energy & Fuels
Huaqian Xu, Jun Li, Dian Zhong, Kuo Zeng, Hongyang Zuo, Xiong Zhang, Vasilevich Sergey Vladimirovich, Haiping Yang, Hanping Chen
Summary: Bio-oil has potential as an alternative fuel, but the formation of coke and soot during combustion affects its usability. This study investigates the formation mechanisms of primary coke, secondary coke, and soot during the initial stage of bio-oil combustion, and analyzes the relationship between their physicochemical properties and combustion characteristics.
JOURNAL OF THE ENERGY INSTITUTE
(2023)
Article
Energy & Fuels
Yulia F. Chirkova, Ulukbek Zh. Mirzakimov, Matvei E. Semenov, Roman S. Pavelyev, Mikhail A. Varfolomeev
Summary: The use of natural gas as an energy source is increasing due to its low greenhouse gas emissions, but conventional storage and transportation methods are limited. Gas hydrate technology provides an economical, environmentally friendly, and safe medium to store energy. However, the low rate of hydrate formation hinders its industrial application. Chemical promoters are being developed to accelerate hydrate formation. Sodium sulfosuccinate compounds synthesized from glycerol and pentaerythritol showed promising promotional properties in methane hydrate formation experiments. The conversion rate of water-to-hydrate increased to 86 +/- 4% with the best promoter at a concentration of 500 ppm.
Article
Chemistry, Physical
Ilgiz F. Minkhanov, Vladislav V. Chalin, Aidar R. Tazeev, Alexander V. Bolotov, Irek I. Mukhamatdinov, Sergey A. Sitnov, Alexey V. Vakhin, Mikhail A. Varfolomeev, Sergey I. Kudryashov, Igor S. Afanasiev, Alexey V. Solovyev, Georgiy V. Sansiev, Dmitry A. Antonenko, Kirill A. Dubrovin, Iaroslav O. Simakov
Summary: In order to evaluate the efficiency of the catalytic aquathermolysis process, physical modeling was carried out on bituminous sediments of Paleocene-Miocene carbonate rocks, characterized by the presence of open and closed fractures. Three filtration experiments were performed on an unextracted reservoir model with extra-viscous oil (EVO). The results showed that the efficiency of oil displacement could be significantly increased by using a solvent and the combined use of a solvent and a catalyst, which is associated with the processes of oil refining.
Article
Engineering, Chemical
Muneer A. A. Suwaid, Ilgiz F. F. Minkhanov, Mikhail A. A. Varfolomeev, Ameen A. A. Al-Muntaser, Alexander V. V. Bolotov, Richard Djimasbe, Shadi A. A. Saeed, Dmitrii A. A. Emelianov, Ruslan K. K. Khairtdinov, Aidar I. I. Sattarov, Mohammed Amine Khelkhal
Summary: This study focuses on selecting the optimal solvent for enhanced oil recovery in the Akan oilfield. The viscosity of the oil was analyzed, and the effects of various solvents on viscosity dynamics were studied. Results showed that toluene and o-xylene were the most effective solvents for increasing oil recovery and reducing viscosity in the Akan oilfield.
Article
Energy & Fuels
Mohammed Hail Hakimi, Alok Kumar, Alok K. Singh, Aref Lashin, Afikah Rahim, Mikhail A. Varfolomeev, Nura Abdulmumini Yelwa, Khairul Azlan Mustapha
Summary: This study evaluates the geochemical and petrographic characteristics of bituminite shales from the Kapurdi mine in Rajasthan, NW India to determine their organic matter inputs and oil-prone potentials. The high total organic carbon (TOC) content and low total sulfur content suggest a fresh lacustrine environment for the deposition of these bituminite shales. The presence of Botryococcus algae confirms the dominance of a lacustrine setting. The organic matter inputs and environmental conditions indicate the potential for both oil and gas generation.
JOURNAL OF PETROLEUM EXPLORATION AND PRODUCTION TECHNOLOGY
(2023)
Article
Engineering, Chemical
Alexis Tirado, Guillermo Felix, Mikhail A. Varfolomeev, Chengdong Yuan, Jorge Ancheyta
Summary: An analysis was conducted on the reaction pathways in the hydrocracking of vacuum gas oil (VGO) using parallel and in-series reaction schemes. Kinetic parameters were estimated based on experimental data and diverse crucial factors using a Ni-Mo-F3.6/ASA-Al2O3 catalyst in a temperature range of 380-410 degrees C and 10 mPa. The results showed that the kinetic model based on parallel reaction pathways had a better fit compared to the literature. Sensitivity analysis, parity plot, and residual analysis were performed to ensure the suitability of the kinetic parameters. Each kinetic model presented a good fit with the experimental data, with average absolute error below 5%.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Energy & Fuels
Alexis Tirado, Guillermo Felix, Ameen A. Al-Muntaser, Mohamed Said Chemam, Chengdong Yuan, Mikhail A. Varfolomeev, Jorge Ancheyta
Summary: Despite significant efforts to understand the reaction mechanism of asphaltenes during aquathermolysis reaction, knowledge about their molecular structures and reaction pathways remains limited. This work extensively reviews and discusses experimental results from different samples of asphaltenes during aquathermolysis reaction to obtain information on their elemental composition, functional groups, and average structural parameters. The findings provide theoretical support for future research on the aquathermolysis of heavy crude oils with various catalysts and highlight the impact of operating conditions, catalyst type, and asphaltene structure on the changes in asphaltenes.
Article
Energy & Fuels
Meisam Babapour Golafshani, Seyedsaeed Mehrabi-Kalajahi, Mikhail A. Varfolomeev, Kamil G. Sadikov, Dmitrii A. Emelianov, Nikolay O. Rodionov, Almaz L. Zinnatullin, Farit G. Vagizov
Summary: Copper tallate (Cu-Tall oil) was used as a soluble catalyst in in situ combustion for the oxidation of crude oil. The synthesized catalyst showed high catalytic efficiency in both liquid phase and porous medium. The presence of Cu-Tall oil catalyst resulted in a decrease in viscosity and reduction of high-molecular-weight compounds during the heavy oil oxidation process.
Article
Energy & Fuels
Shamil E. Gainullin, Abdolreza Farhadian, Polina Y. Kazakova, Matvei E. Semenov, Yulia F. Chirkova, Atousa Heydari, Roman S. Pavelyev, Mikhail A. Varfolomeev
Summary: Novel amino acid derivatives (ACDs) were developed as efficient promoters for methane hydrate formation and recovery, exhibiting superior kinetics compared to anionic surfactants without foaming. ACD5 achieved the highest promotion effect in distilled water, increasing the water-to-hydrate conversion from 39.6% to 94.3%, exceeding sodium dodecyl sulfate (SDS). ACDs also showed higher promotion activity than SDS in salt water, making seawater a cost-effective alternative for methane hydrate production.
Article
Energy & Fuels
Yulia F. Chirkova, Andrey S. Stoporev, Roman S. Pavelyev, Mikhail A. Varfolomeev
Summary: In recent years, interest in gas hydrates has grown due to their potential as an energy source and environmentally friendly alternative to storing and transporting natural gas. This study compared the effectiveness of sulfonated castor oil (SCO) and sodium dodecyl sulfate (SDS) as promoting reagents in the formation and decomposition of methane and methane-propane hydrates in a porous medium. The results showed that SCO significantly improved the water conversion rate in methane hydrates due to enhanced mass transfer in the presence of surfactants, while the effect on methane-propane hydrates was limited. Both SCO and SDS accelerated hydrate formation, but SCO required less supercooling. These findings suggest that SCO is comparable to SDS in promoting activity in porous media with varying water saturation.
Review
Energy & Fuels
Abdolreza Farhadian, Azam Shadloo, Xin Zhao, Roman S. Pavelyev, Kiana Peyvandi, Zhengsong Qiu, Mikhail A. Varfolomeev
Summary: Gas hydrate formation is a serious challenge for the oil and gas industry, causing safety, environmental, and economic problems. Current kinetic hydrate inhibitors (KHIs) are not biodegradable, cheap, and eco-friendly. This report reviews efforts to develop KHIs with higher biodegradability and emphasizes the need for cheaper and greener options.
Article
Engineering, Chemical
Alexis Tirado, Guillermo Felix, Muneer A. Suwaid, Ameen A. Al-Muntaser, Dmitry A. Antonenko, Igor S. Afanasiev, Mikhail A. Varfolomeev, Chengdong Yuan, Jorge Ancheyta
Summary: Oil-soluble catalysts have been found to improve the flow properties of heavy crude oil during steam injection processes. In order to better understand the effects and reaction mechanisms of these catalysts, further studies using complex kinetic models are needed. This study investigated the catalytic effect of copper oleate on aquathermolysis of heavy crude oil, and developed a kinetic model to predict the yield of different fractions and gases. The results showed that copper oleate reduces polyaddition reactions of heavy fractions and favors the production of lighter compounds.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Energy & Fuels
Shuai Zhao, Wanfen Pu, Hao Gao, Ruofan Wang, Mikhail A. Varfolomeev, Qi Jiang, Chengdong Yuan
Summary: A thermogravimetric study was conducted to investigate the isothermal low-temperature oxidation (LTO) characteristics of heavy crude oil and its oxidized oils. The study determined the appropriate reaction orders and activation energies for the different oil samples, and found that the oils oxidized at higher temperatures had higher residual mass after thermal degradation. The developed isothermal kinetics was shown to be a useful tool for predicting the LTO behavior of heavy oils.
Article
Engineering, Chemical
Alexis Tirado, Guillermo Felix, Ameen A. Al-Muntaser, Chengdong Yuan, Mikhail A. Varfolomeev, Jorge Ancheyta
Summary: Steam-based technologies, particularly catalytic aquathermolysis, show great promise for increasing the recovery factor of heavy crude oil. This process requires proper experimentation to evaluate operational conditions, catalyst performance, and reaction kinetics. This study provides a comprehensive review of experimental results on diverse upgraded oil samples, discussing the effects of various reaction parameters and highlighting behaviors in gas production and viscosity reduction for future research and development. The reactivity of chemical compounds involved plays a significant role in crude oil upgrading, necessitating detailed analysis for experimental development and scale-up.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Thermodynamics
Sergey P. Verevkin, Arina V. Elbakari, Sergey V. Vostrikov, Ruslan N. Nagrimanov, Mikhail A. Varfolomeev
Summary: Alkyl benzoates, which are esters of benzoic acid, serve as important preservatives in the food and beverage industry. New synthesis pathways from renewable sources offer opportunities for their large-scale production and expand their applications to platform chemicals and hydrogen storage. The challenge lies in controlling selectivity and yield due to the multi-step production and conversion of alkyl benzoates. Thermochemical and thermophysical data play a crucial role in fine-tuning the distribution between thermodynamic and kinetic products. This study focuses on investigating the thermochemical properties of a homological series of alkyl benzoates and calculating the energetics of relevant chemical reactions for hydrogen storage.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2023)
Article
Chemistry, Physical
Sergey P. P. Verevkin, Svetlana V. V. Portnova, Vladimir N. N. Emel'yanenko, Ruslan N. N. Nagrimanov, Mikhail A. A. Varfolomeev
Summary: Hydrogen bonding is a fascinating phenomenon that exhibits unusual properties in organic and biomolecules. This study focuses on quantifying the strength of intra-molecular hydrogen bonds in alkyl 2-hydroxybenzoates. Through experimental measurements and validation by quantum chemical methods, it is determined that the intra-HB strength in methyl 2-hydroxybenzoate is -43 kJ mol(-1), and it is found to be independent of the chain length of the alkyl 2-hydroxybenzoates.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)