4.7 Article

Activation of peroxymonosulfate by magnetic catalysts derived from drinking water treatment residuals for the degradation of atrazine

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 366, Issue -, Pages 402-412

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.12.016

Keywords

Peroxymonosulfate; Magnetic catalysts; Drinking water treatment residuals; Activation mechanism; Degradation pathway

Funding

  1. National Key Research and Development Program of China [2018YFD0800903, 2016YFD0800207]
  2. National Natural Science Foundation of China [41671487]
  3. Beijing Natural Science Foundation [16L00073]

Ask authors/readers for more resources

Magnetic catalysts (MCs) derived from iron-rich drinking water treatment residuals (WTRs) were prepared through pyrolysis treatment and introduced as activators of peroxymonosulfate (PMS) for refractory atrazine (ATZ) degradation. Comprehensive characterization analysis indicated that pyrolytic temperature could manipulate the crystalline structure evolution of the MCs and influence their physicochemical and catalytic properties. The catalytic performances of the as-prepared samples pyrolyzed at 600 degrees C (MC-600) and 1000 degrees C (MC-1000) were evaluated, and MC-1000 exhibited far more excellent catalytic reactivity than MC-600 in PMS oxidation system. Such difference was mainly attributed to that Fe3O4 and Fe are the dominant active ingredients of MC-600 and MC-1000, respectively. The electron spin resonance (ESR) tests and radical quenching experiments revealed that hydroxyl radical ((OH)-O-center dot) and sulfate radical (SO4 center dot-) predominated in the MC-600/PMS and MC-1000/PMS systems, respectively. The mechanisms of the MCs-mediated PMS activation process were elucidated, among which the role of iron mineral phase was emphatically explored. Furtherly, possible degradation by-products were identified by LC-MS, and potential degradation pathways were proposed. Ultimately, the effects of pivotal parameters (i.e. MC-1000 dosage, PMS concentration, initial pH, and water matrix species) on ATZ degradation were investigated to assess the applicability of the MC-1000/PMS system.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Environmental Sciences

Influence of Fe(II) on Sb(III) oxidation and adsorption by MnO2 under acidic conditions

Chengjun Zhang, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

Article Geochemistry & Geophysics

Comparison of the reaction kinetics and mechanisms of Sb(III) oxidation by reactive oxygen species from pristine and surface-oxidized pyrite

Wenting Wang, Chengjun Zhang, Jun Shan, Mengchang He

CHEMICAL GEOLOGY (2020)

Article Engineering, Environmental

Seasonal relevance of agricultural diffuse pollutant with microplastic in the bay

Wei Ouyang, Yu Zhang, Li Wang, Damia Barcelo, Yidi Wang, Chunye Lin

JOURNAL OF HAZARDOUS MATERIALS (2020)

Article Engineering, Environmental

Higher Fine Particle Fraction in Sediment Increased Phosphorus Flux to Estuary in Restored Yellow River Basin

Yidi Wang, Wei Ouyang, Chunye Lin, Weihong Zhu, Andrea Critto, Mats Tysklind, Xuelei Wang, Mengchang He, Baodong Wang, Haotian Wu

Summary: The study reveals deep uncertainty in estimating sediment pollutant flux in river delta-front estuaries, with fine particles in rivers controlling pollution status in estuaries. The Yellow River's high-silt sediment load, significant in global fluvial sediment transport, shows a negative correlation with estuarine phosphorus flux.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2021)

Article Environmental Sciences

Toxicity and bioavailability of antimony to the earthworm (Eisenia fetida) in different agricultural soils

Qianyun Zhong, Lianzhen Li, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu

Summary: Laboratory experiments were conducted to investigate the toxicity of antimony (Sb) to earthworms in four different agricultural soils. The earthworms clearly avoided the Sb spiked soils, and the avoidance response was correlated to the exposure dose. Different toxic effects of Sb were observed in the four types of soils, with antimony being more toxic in sandy alkaline soil. The study provided comprehensive data on the toxicological effects of Sb in agricultural soil, which can contribute to ecological risk assessments.

ENVIRONMENTAL POLLUTION (2021)

Article Environmental Sciences

Deep insight into the Sb(III) and Sb(V) removal mechanism by Fe-Cu-chitosan material

Tianning Wang, Yonghong Jiao, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu, Haijiao Xie

Summary: This study prepared a porous Fe-Cu-chitosan composite through one-step coprecipitation and found the optimal Fe/Cu proportion for antimony adsorption. Spectral characterization, batch experiments, and density functional theory simulations were conducted to determine the adsorption mechanism involving Fe-Cu coupling and surface hydroxyls.

ENVIRONMENTAL POLLUTION (2022)

Article Engineering, Environmental

Reductive removal of As(V) and As(III) from aqueous solution by the UV/ sulfite process: Recovery of elemental arsenic

Jianbing Wang, Jiyong Liu, Xianjia Peng, Mengchang He, Xingyun Hu, Jinmin Zhao, Feng Zhu, Xin Yang, Linghao Kong

Summary: This study proposes a UV/sulfite advanced reduction method for removing arsenic (As(V) and As(III)) from water. The results show that this method can effectively remove over 99.9% of arsenic and avoid the generation of hazardous waste. The reduction of arsenic is favorable under alkaline conditions, while the presence of dissolved oxygen and some other substances inhibits the reduction process.

WATER RESEARCH (2022)

Article Engineering, Environmental

Efficient removal of antimony by a facile liquid-controlled strategy reinforced hematite-spinel (Fe2O3-MnFe2O4) composite: construction, simulation and practical evaluation

Tianning Wang, Yonghong Jiao, Mengchang He, Xianjia Peng, Peng Liu, Wei Ouyang, Chunye Lin, Xitao Liu, Haijiao Xie

Summary: In this study, a novel adsorbent was prepared by a one-step hydrothermal method for efficient removal of aqueous antimony. The composite material showed excellent adsorption capacity for Sb(III) and Sb(V), and XAS and DFT analysis revealed that the Fe-Mn-CS interface structure had the highest adsorption energy for antimony.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Environmental Sciences

Occurrence, distribution, and migration of antimony in the Zijiang River around a superlarge antimony deposit zone

Huiji Liu, Wei Zeng, Mengchang He, Chunye Lin, Wei Ouyang, Xitao Liu

Summary: This study analyzed the occurrence, distribution, migration, and influencing factors of antimony (Sb) in the Zijiang River. The study found that mining and smelting were the main sources of Sb in the river. The concentration of Sb showed a decreasing trend from the tributaries to the mainstream, and the retention and accumulation of sediments led to the secondary release of Sb.

ENVIRONMENTAL POLLUTION (2023)

Article Environmental Sciences

Monte Carlo simulation and delayed geochemical hazard revealed the contamination and risk of arsenic in natural water sources

Huiji Liu, Chanjuan Kang, Jun Xie, Mengchang He, Wei Zeng, Chunye Lin, Wei Ouyang, Xitao Liu

Summary: This study conducted a comprehensive investigation on the contamination and ecological and health risks of arsenic in the Zijiang River, finding relatively high concentrations of arsenic in the midstream area. The release of arsenic should be given more consideration for secondary risk. Although the overall risk of arsenic in surface waters was low, children had higher health risks compared to adults.

ENVIRONMENT INTERNATIONAL (2023)

Article Engineering, Environmental

Effective reduction and recovery of As(III) and As(V) from alkaline wastewater by thiourea dioxide: Efficiency and mechanism

Feng Zhu, Linghao Kong, Mengchang He, Duxian Fang, Xingyun Hu, Xianjia Peng

Summary: In alkaline wastewater with high arsenic concentration, traditional lime precipitation generates large amounts of hazardous waste. In this study, a heat-activated reduction method using thiourea dioxide (TDO) was proposed to efficiently remove and recover arsenic from alkaline wastewater. More than 99.9% of As(III)/As(V) were reduced to As(0) with a purity of more than 99.5 wt% by TDO within 30 min. The highly reductive eaq -and SO2• radicals generated during TDO decomposition significantly contributed to the arsenic reduction. Increasing pH and temperature improved the arsenic reduction by accelerating the formation of eaq -and SO2• radicals. Dissolved oxygen had a negative effect on arsenic removal, while CO32- slightly suppressed the removal effect. SiO32-, PO43-, Cl-, SO42-, and NH4+ had negligible effects. This method has potential for efficient arsenic removal and reduction in alkaline wastewater.

WATER RESEARCH (2023)

Article Engineering, Environmental

Mechanistic insights into Sb(III) and Fe(II) co-oxidation by oxygen and hydrogen peroxide: Dominant reactive oxygen species and roles of organic ligands

Yiqing Wang, Linghao Kong, Mengchang He, Chunye Lin, Wei Ouyang, Xitao Liu, Xianjia Peng

Summary: Sole O2 or H2O2 oxidants are insufficient for oxidizing Sb(III) over a time scale of hours to days, but Sb(III) oxidation can occur during Fe(II) oxidation by O2 and H2O2 due to the generation of reactive oxygen species (ROS). However, the mechanisms and effects of organic ligands on the co-oxidation of Sb(III) and Fe(II) require further investigation. This study provides detailed insights into the co-oxidation of Sb(III) and Fe(II) by O2 and H2O2, highlighting the influence of pH, anions, and organic ligands on the oxidation processes. The results contribute to a better understanding of the geochemical cycling and fate of Sb in subsurface environments and have implications for the in-situ remediation of Sb(III)-contaminated sites using Fenton reactions.

WATER RESEARCH (2023)

Article Environmental Sciences

Sediment Flux, Coastal Development, and Industrial Pressure Drive the Historical Vanadium Concentrations in the East China Sea and Two Bays of Shandong

Roberto Xavier Supe Tulcan, Wei Ouyang, Zewei Guo, Hao Xin, Chunye Lin, Jiamei Wang, Mengchang He

Summary: The concentrations and variations of vanadium in coastal areas are highly influenced by sediment flux and anthropogenic projects. Urban and industrial development has led to pollution of coastal sediments. Vanadium is of significant interest due to its distribution, concentrations, accumulation, and risks, especially in bays with industrial development and high population.

ACS ES&T WATER (2023)

Article Environmental Sciences

Response of soil microbial activities and ammonia oxidation potential to environmental factors in a typical antimony mining area

Aihua Wang, Shujun Liu, Jun Xie, Wei Ouyang, Mengchang He, Chunye Lin, Xitao Liu

Summary: Mining, smelting, and tailing deposition activities can cause metalloid contamination in soils, posing a threat to ecosystems and human health. Microbial indicators play a crucial role in assessing soil ecological risks due to their sensitivity to environmental factors. This study focused on Xikuangshan, the largest active antimony mine in the world, and investigated soil properties, metalloid contents, and microbial characteristics. The results showed that the soils were mainly polluted by antimony, followed by cadmium and arsenic. Microbial characteristics varied among different sampling points in the mining area. The findings provide a theoretical basis for ecological risk assessment of contaminated soils.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

Article Chemistry, Analytical

Mechanism of birnessite-promoted oxidative dissolution of antimony trioxide

Jun Shan, Xintong Ding, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu

ENVIRONMENTAL CHEMISTRY (2020)

Article Engineering, Environmental

Temperature-modulated sensing characteristics of ultrafine Au nanoparticle-loaded porous ZnO nanobelts for identification and determination of BTEX

Shun-Shun Chen, Xu-Xiu Chen, Tian-Yu Yang, Li Chen, Zheng Guo, Xing-Jiu Huang

Summary: A temperature-modulated sensing strategy was proposed to identify and determine BTEX compounds. Highly effective identification of BTEX was achieved using linear discrimination and convolutional neural network analyses. Additionally, quantitative analysis of concentration was accomplished by establishing the relationship between concentration and response.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Particulate matter-induced metabolic recoding of epigenetics in macrophages drives pathogenesis of chronic obstructive pulmonary disease

Myungkyung Noh, Jeong Yeon Sim, Jisung Kim, Jee Hwan Ahn, Hye-Young Min, Jong-Uk Lee, Jong-Sook Park, Ji Yun Jeong, Jae Young Lee, Shin Yup Lee, Hyo-Jong Lee, Choon-Sik Park, Ho-Young Lee

Summary: This study reveals that chronic exposure to PM induces chronic inflammation and development of COPD by dysregulating NAD+ metabolism and subsequent SIRT1 deficiency in pulmonary macrophages. Activation of SIRT1 by resveratrol effectively mitigates PM-induced inflammation and COPD development. Targeting metabolic and epigenetic reprogramming in macrophages induced by PM is a promising strategy for COPD treatment.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Electrocatalytic degradation of nitrogenous heterocycles on confined particle electrodes derived from ZIF-67

Yu Liu, Linlin Qin, Yiming Qin, Tong Yang, Haoran Lu, Yulong Liu, Qiqi Zhang, Wenyan Liang

Summary: Co/NC/PAC electrode was prepared by compounding ZIF-67 with powder-activated carbon for the electrocatalytic treatment of nitrogen-containing heterocyclic compounds. The degradation efficiency of the four compounds reached 90.2-93.7% under optimal conditions, and the degradation order was pyridazine < pyrimidine < pyrazine < pyridine.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Yttrium speciation variability in bauxite residues of various origins, ages and storage conditions

Julien Couturier, Pierre Tamba Oulare, Blanche Collin, Claire Lallemand, Isabelle Kieffer, Julien Longerey, Perrine Chaurand, Jerome Rose, Daniel Borschneck, Bernard Angeletti, Steven Criquet, Renaud Podor, Hamed Pourkhorsandi, Guilhem Arrachart, Clement Levard

Summary: This study analyzes the properties of bauxite residue samples and explores the influence of bauxite ore origin, storage conditions, and storage time. The results show that the speciation of yttrium is related to the origin of bauxite ore, while no significant variation was observed with storage conditions or aging of the residues.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Trophic transfer and their impact of microplastics on estuarine food chain model

Sakthinarenderan Saikumar, Ravi Mani, Mirunalini Ganesan, Inbakandan Dhinakarasamy, Thavamani Palanisami, Dharani Gopal

Summary: Microplastic contamination in marine ecosystems poses a growing concern due to its trophic transfer and negative effects on marine organisms. This study investigates the transfer and impacts of polystyrene microplastics in an estuarine food chain. The results show that microplastics can be transferred through the food chain, although the transfer rates are low. The exposed organisms exhibit stress responses, suggesting the potential risk of microplastics reaching humans through the food chain.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Review Engineering, Environmental

Antibiotic resistance genes and heavy metals in landfill: A review

Yan-Jiao Li, Ying Yuan, Wen-Bing Tan, Bei-Dou Xi, Hui Wang, Kun-Long Hui, Jia-Bao Chen, Yi-Fan Zhang, Lian-Feng Wang, Ren-Fei Li

Summary: This review investigated and analyzed the distribution, composition, and abundance of heavy metals and antibiotic resistance genes (ARGs) in landfill. The results showed that heavy metals have lasting effects on ARGs, and complexes of heavy metals and organic matter are common in landfill. This study provides a new basis to better understand the horizontal gene transfer (HGT) of ARGs in landfill.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

The effect of synthesis conditions on the in situ grown MIL-100(Fe)-chitosan beads: Interplay between structural properties and arsenic adsorption

Jessy Joseph, Ari Vaisanen, Ajay B. Patil, Manu Lahtinen

Summary: Efficient and environmentally friendly porous hybrid adsorbent beads have been developed for the removal of arsenic from drinking water. The structural tuning of the adsorbents has been shown to have a significant impact on their adsorption performance, with high crystallinity leading to increased adsorption capacity and selectivity towards As5+.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Phthalate metabolites in breast milk from mothers in Southern China: Occurrence, temporal trends, daily intake, and risk assessment

Yangyang Liu, Minhua Xiao, Kaiqin Huang, Juntao Cui, Hongli Liu, Yingxin Yu, Shengtao Ma, Xihong Liu, Meiqing Lin

Summary: This study measured the levels of phthalate metabolites in breast milk collected from mothers in southern China. The results showed that phthalates are still prevalent in the region, and breastfeeding contributes to phthalate intake in infants. However, the levels detected do not pose significant health risks to infants based on dietary exposure. The increasing exposure to certain phthalates calls for further research into their sources and potential risks.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Depth significantly affects plastisphere microbial evenness, assembly and co-occurrence pattern but not richness and composition

Zhiqiang Wu, Jianxing Sun, Liting Xu, Hongbo Zhou, Haina Cheng, Zhu Chen, Yuguang Wang, Jichao Yang

Summary: Ocean depth affects microbial diversity, composition, and co-occurrence patterns of microplastic microbial communities. Deterministic processes dominate the assembly of mesopelagic plastisphere microbial communities, while stochastic processes shape the assembly of bathypelagic microbial communities. The relationships between microorganisms in the mesopelagic layer are more complex and stable, with Proteobacteria and Actinobacteriota playing important roles.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Abatement of antibiotics and resistance genes during catalytic ozonation enhanced sludge dewatering process: Synchronized in volume and hazardousness reduction

Tingting Xiao, Renjie Chen, Chen Cai, Shijie Yuan, Xiaohu Dai, Bin Dong, Zuxin Xu

Summary: Based on the efficiency of catalytic ozonation techniques in enhancing sludge dewaterability, this study investigated its effectiveness in simultaneous reduction of antibiotics and antibiotic resistance genes. The results showed that catalytic ozonation conditioning changed the distribution of antibiotics and achieved high degradation rates. It also significantly reduced the abundance of ARGs, inhibited horizontal gene transfer, and decreased the signal transduction of typical ARGs host bacteria.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Unlocking the potential of ferrate(VI) in water treatment: Toward one-step multifunctional solutions

Yang Deng, Xiaohong Guan

Summary: This article discusses two different development approaches for ferrate(VI) technology in water treatment, arguing that process integration is a promising method that can drive technological innovation and revolution in water treatment, achieving higher treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Floating Catalytic Foam with prominent heat-induced convection for the effective photocatalytic removal of antibiotics

Zhe Zhang, Lu Zhang, Zhihao Huang, Yuxin Xu, Qingqing Zhao, Hongju Wang, Meiqing Shi, Xiangnan Li, Kai Jiang, Dapeng Wu

Summary: In this study, a floating catalytic foam was designed and prepared to enhance the mass transfer in immobilized photocatalysts for wastewater treatment. The floating catalytic foam could float on the water surface and establish a temperature gradient, effectively promoting the diffusion and adsorption of target molecules during the photocatalytic process.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Mechanism and synergistic effect of sulfadiazine (SDZ) and cadmium toxicity in spinach (Spinacia oleracea L.) and its alleviation through zinc fortification

Muhammad Nafees, Adiba Khan Sehrish, Sarah Owdah Alomrani, Linlin Qiu, Aasim Saeed, Shoaib Ahmad, Shafaqat Ali, Hongyan Guo

Summary: The accumulation of cadmium and antibiotics in edible plants and fertile soil is a worldwide problem. This study investigated the potential of zinc oxide nanoparticles to alleviate the toxicity of both cadmium and antibiotics and promote spinach growth.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Aminoalkyl organosilicon with dual chemical sites for SO2 absorption and analysis of site-specific absorption entropy and enthalpy

Lurui Wan, Kai Wang, Yuan Chen, Zhiyong Xu, Wenbo Zhao

Summary: In this study, a low viscosity and high thermal stability SO2 absorbent with dual interacting sites was successfully synthesized. The absorbent showed the highest absorption enthalpy change and entropy change values among reported SO2 absorbents, and exhibited lower viscosity and comparable thermal stability to ILs.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Improvement of Fe(III)/percarbonate system by molybdenum powder and tripolyphosphate: Co-catalytic performance, low oxidant consumption, pH-dependent mechanism

Zhengwei Zhou, Guojie Ye, Yang Zong, Zhenyu Zhao, Deli Wu

Summary: This study utilized Mo powder and STPP to enhance the performance of the sodium percarbonate system in pollutant degradation. The presence of Mo and STPP resulted in a higher degradation rate of the model pollutant SMX, with low oxidant consumption. The system generated multiple active species through a series of chain reactions at different pH values, exhibiting excellent performance towards electron-rich pollutants. Furthermore, Mo demonstrated excellent stability and reusability.

JOURNAL OF HAZARDOUS MATERIALS (2024)