Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 837, Issue -, Pages 95-102Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2019.02.016
Keywords
MnOx/Ni(OH)(2); SPI/rGO membrane; Glucose detection; Electrochemical biosensor
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Funding
- National Natural Science Foundation of China [21806096]
- Open Project Program of National Demonstration Center for Experimental Light Chemistry Engineering Education [2018QGSJ02-19]
- Shaanxi University of Science Technology
- Guangxi Key Laboratory of Clean Pulping, Papermaking and Pollution Control Opening Fund [KF 201711]
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A novel nonenzymatic glucose sensor was fabricated based on the MnOx/Ni(OH)(2) nanocomposite electrodeposited sulfonated polyimides/graphene nano-sheets membrane (SPI/rGO). Firstly, MnOx nanorod array was prepared on SPI/rGO membrane using pulse reverse potential electrodeposition. Then Ni(OH)(2) nanoparticle was also deposited on the membrane to obtain SPI/rGO-MnOx/Ni(OH)(2). The electrochemical behaviors of the resulted sensor were investigated by cyclic voltammetry and chronoamperometry in alkaline solution. Combining the outstanding electrocatalytic activity of MnOx/Ni(OH)(2) and high conductivity of SPI/rGO, the SPI/rGO-MnOx/Ni(OH)(2) sensor showed remarkable advantages for glucose detection including high sensitivity, long-term stability and reproducibility. The linear range of detection was arranged from 1 M to 1.8 mM, and the limit of detection was 0.333 mu M (S/N = 3). Moreover, the good selectivity for glucose and satisfactory results in real samples detection by the prepared sensor were also demonstrated.
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