4.7 Article

Carbon-supported phosphatized CuNi nanoparticle catalysts for hydrazine electrooxidation

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 44, Issue 21, Pages 10637-10645

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2019.03.005

Keywords

Phosphatized alloy nanoparticles; Electrocatalyst; Synergistic effect; Hydrazine oxidation reaction

Funding

  1. National Natural Science Foundations of China [21561019, 51863019]
  2. program of Changjiang Scholars and Innovative Research Team in University [IRT_15R56]
  3. Foundation of A Hundred Youth Talents Training Program of Lanzhou Jiaotong University
  4. Key research and development plan of Gansu Province [2017GS10906]

Ask authors/readers for more resources

Developing non-noble metal catalysts with high performance to reduce the cost of hydrazine fuel cells is urgent. Herein, in this study, a series of carbon-supported phosphatized CuNi catalysts (P--CuxNiy/C) are designed for hydrazine oxidation reaction (HzOR) via high temperature phosphating process. Among them, the P-Cu2Ni/C is found to be a promising candidate for hydrazine electrooxidation. Electrochemical measurement results indicate that the P-Cu2Ni/C catalyst exhibits higher catalytic activity and stability for HzOR in comparison with P-CuNi/C, P-CuNi2/C, Cu2Ni/C, Cu/C and Ni/C catalysts. Additionally, HzOR kinetics are also investigated, and it proves that hydrazine electrooxidation on P-Cu2Ni/C is a diffusion controlled irreversible process. Meanwhile, physical characterization reveals that the catalysts have doped phosphorus successfully. All results demonstrate that as-prepared P-Cu2Ni/C catalyst is a promising electrocatalyst for direct hydrazine fuel cells. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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