Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 10, Pages 1964-1980Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801799
Keywords
Enantioselectivity; Pinacol rearrangement; Sigmatropic rearrangement; Transition metal catalysis; Organocatalysis; Carbon migration; Hydride shift
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Funding
- EPFL (Switzerland)
- Swiss National Science Foundation [SNSF 20020-155973]
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Among the fundamental chemical transformations in organic synthesis, rearrangement has been recognized as powerful and reliable reactions for the construction of carbon-carbon or carbon-heteroatom bonds. Benefiting from the advance of the novel catalytic system, catalyst design and activation mode, the chemistry of enantioselective rearrangements has experienced ever-growing development recently and has been successfully used in the synthesis of chiral non-racemic building blocks, natural products, and other valuable compounds. We present herein a survey of the recent development on the catalytic enantioselective rearrangement (from 2013 onward) organized according to the rearrangement type.
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