Correction
Environmental Sciences
Majid Kermani, Tahereh Rahmatinia, Vahide Oskoei, Samira Norzaee, Abbas Shahsavani, Mahdi Farzadkia, Mohammad Hossein Kazemi
Summary: A correction to this paper has been published.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Engineering, Biomedical
Shi Zhou, Yi Xing, Xing Yuan, Guanlan Wu, Xiaolin Zhu, Dongmei Wu
Summary: The effects of six polycyclic aromatic hydrocarbons (PAHs) on V79 cells were studied using a miniature electrochemical system, revealing different cytotoxicity sequences depending on the biomarkers used. The variations in cytotoxicity sequences measured by different biomarkers may be related to different structures affecting cellular receptors, intercellular communication, and protein expression.
BIOMEDICAL MICRODEVICES
(2021)
Article
Engineering, Chemical
Chunqing Xia, Qinglong Liu, Ling Zhao, Lan Wang, Jingchun Tang
Summary: This study investigated the degradation of petroleum hydrocarbons in soil using FeS@BC and FeS activated persulfate (PS). The results showed that the FeS@BC/PS system had a higher removal rate for total petroleum hydrocarbons, polycyclic aromatic hydrocarbons, and n-alkanes compared to the FeS/PS system. Radical quenching experiment and Electron Paramagnetic Resonance revealed that the dominant active substance is sulfate free radical produced by PS during activation. The FeS@BC/PS system has great potential for the remediation of petroleum-contaminated soil.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Environmental
Chang-Mao Hung, Chin-Pao Huang, Chiu-Wen Chen, Shuchen Hsieh, Cheng-Di Dong
Summary: In this study, a pilot-scale hybrid treatment system consisting of HC, HS, and PS was used to remove PAHs from dredged harbor sediments. The study found that under certain conditions, the combined HC-PS-HS system can effectively remove PAHs, especially lower-ring PAHs. Additionally, the decline in organic matter content during the combined treatment process was found to lead to the gradual degradation and transformation of aromatic protein-based components into soluble microbial metabolites.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Toxicology
Caroline Scaramboni, Maria Lucia Arruda Moura Campos, Daniel Junqueira Dorta, Danielle Palma de Oliveira, Silvia Regina Batistuzzo de Medeiros, Marcos Felipe de Oliveira Galva, Kristian Dreij
Summary: This study investigated the cytotoxicity and genotoxicity of Retene in human HepG2 liver cells. Results showed that Retene induced DNA strand breaks, micronuclei formation, and reactive oxygen species (ROS) formation in a dose-and time-dependent manner. The study suggested that oxidative stress may be a key mechanism of the genotoxic effects of Retene.
TOXICOLOGY IN VITRO
(2023)
Article
Engineering, Environmental
Dongdong Wen, Huaqiu Liu, Yajun Zhang, Rongbing Fu
Summary: In this study, a novel strategy was proposed and proven to enhance the delivery of persulfate (PS) to soil by electrokinetics (EK). The application of pulsed direct current (DC) electric field thermally activated the PS in situ, promoted PS plume mixing and contaminants-free radicals reaction, and replenished PS to achieve efficient degradation of contaminants in low permeability zones. The results showed that EK transport rate of PS in soil was 12.3 times higher than diffusion. Irregular pulsed DC field maintained the targeted temperature during activation phase, resulting in the generation of oxidative radicals (SO·4/·OH). Electromigration and electroosmosis also promoted PS transport and reactive mixing, enhancing the degradation of polycyclic aromatic hydrocarbons (PAHs) contaminated soil. PS concentrations in pore fluid increased with continuous fluctuations. Long-term low-temperature activation led to a significant decrease (nearly 60%) in average concentration of PAHs in the whole soil cell over 10 days. These findings demonstrate the great potentiality of the novel strategy in remediating low permeability contaminated soil.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Review
Environmental Sciences
Francesco Bianco, Marco Race, Stefano Papirio, Patryk Oleszczuk, Giovanni Esposito
Summary: Biochar is proposed as an innovative and sustainable technology for remediation of PAH-contaminated sediments, mainly through sorption mechanisms. The use of biochar can significantly improve the efficiency of PAH removal from sediments, especially when used in combination with multi-PAH systems and high dosages. Additionally, biochar has shown to decrease PAH degradation during bioaugmentation and phytoremediation of sediments, but can increase degradation when used with nitrate as an electron acceptor in low-temperature conditions.
Article
Environmental Sciences
Jian Wang, Xiaofang Zhang, Xian Zhou, Michael Gatheru Waigi, Fredrick Owino Gudda, Chaolan Zhang, Wanting Ling
Summary: This study developed a dual peroxide system for the oxidation remediation of soils contaminated with PAHs, achieving a maximum PAHs degradation efficiency of 70.8% under optimized conditions. The results demonstrate the promising efficiency and potential of the dual peroxide system for PAH oxidation in neutral soils contaminated with PAHs.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Multidisciplinary Sciences
Yusuke Nakakuki, Takashi Hirose, Hikaru Sotome, Min Gao, Daiki Shimizu, Ruiji Li, Jun-Ya Hasegawa, Hiroshi Miyasaka, Kenji Matsuda
Summary: Helically twisted conductive nanocarbon materials are suitable for optoelectronic and electromagnetic molecular devices on the nanometer scale, showing a large effective conjugation length and ultrafast decay dynamics. The extended π-helicenes achieved a large effective conjugation length through helical fusion, leading to an absorption edge in the near-infrared region.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Xiushang Xu, Amy L. Vonder Haar, Rengo Yoshioka, Qizheng Zhang, Serhii Vasylevskyi, Andrew J. Musser, Akimitsu Narita
Summary: A benzo[rst]pentaphene derivative, BPP-MeOPA, was synthesized and characterized by NMR and single-crystal X-ray analysis. Investigation of its photophysical properties, including transient absorption spectroscopy, revealed improved absorption and emission features from an S-1 state with excitonic and charge-transfer character by introducing MeOPA groups.
CHEMICAL COMMUNICATIONS
(2023)
Article
Pharmacology & Pharmacy
Mandeep Dahiya, Rajendra Awasthi, Kamal Dua, Harish Dureja
Summary: In this study, magnetic nanoparticles were prepared using an emulsion solvent evaporation method and optimized using Box Behnken design. The optimized nanoparticles showed a mean particle size range of 71.81 +/- 4.4 to 384.1 +/- 10.5 nm, a polydispersity index range of 0.203 +/- 0.008 to 0.777 +/- 0.010, and a zeta potential range of -34.4 +/- 3.1 to -10.2 +/- 0.6 mV. The entrapment efficiency was 84.64 +/- 0.78%. TEM image confirmed the formation of spherical nanoparticles. The optimized formulation released 25.18%-56.63% and 54.38%-90.56% of loaded drug in phosphate buffer and 0.1 N HCl, respectively. The IC50 value of the optimized formulation in HepG2 cell lines was 38.12 μg/mL. The XRD analysis confirmed the amorphous form of the loaded drug. The average surface roughness for the magnetite and optimized formulation was 5.27025 nm and 8.29138 nm, respectively. The magnetization saturation for magnetite and optimized formulation was 28.58 emu/g and 25.46 emu/g, respectively. The electron paramagnetic resonance spectroscopy revealed a g-Lande factor of 4.30 for pure magnetite and 4.24 for the optimized formulation, indicating the superparamagnetic nature of the particles.
JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Environmental
Longgang Chu, Long Cang, Zhaoyue Sun, Xinghao Wang, Hong Chen, Guodong Fang, Juan Gao
Summary: This study systematically investigated the formation mechanism of nitro byproducts of anthracene (ANT) during the electrokinetic (EK) chemical oxidation process. The formation of nitro-byproducts, including 14 different kinds, were observed and their nitration pathways were proposed and described. These nitro-byproducts, which have enhanced acute toxicity, mutagenic effects, and potential threat to the ecosystem, should be further studied during the EK process.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Review
Environmental Sciences
Meng Qiao, Weixiao Qi, Huijuan Liu, Jiuhui Qu
Summary: Oxygenated polycyclic aromatic hydrocarbons (OPAHs) have higher concentrations and toxicity in water environments, posing significant ecological risks to surface water ecosystems.
ENVIRONMENT INTERNATIONAL
(2022)
Article
Chemistry, Organic
Yushi Ohno, Shogo Ando, Daisuke Furusho, Ryoyu Hifumi, Yuuya Nagata, Ikuyoshi Tomita, Shinsuke Inagi
Summary: Here, a facile and selective synthesis of cationic azatriphenylene derivatives was achieved through electrochemical intramolecular cyclization, where the key step involves atom-economical C-H pyridination without a transition-metal catalyst or an oxidant. This proposed strategy provides a practical approach for introducing cationic nitrogen (N (+)) into pi-electron systems, thus expanding the molecular design of N (+)-doped polycyclic aromatic hydrocarbons.
Article
Chemistry, Inorganic & Nuclear
Huimin Zhong, Cong Jiang, Jiahui Zou, Guancheng Zhu, Yanyan Huang
Summary: In this study, CeO2-based porous carbonaceous frameworks (CeO2 PCFs) were used as antioxidant nanozymes to scavenge reactive oxygen species and absorb benzo[a]pyrene. CeO2 PCFs exhibited excellent superoxide dismutase-like and catalase-like activity, effectively eliminating superoxide radical, hydroxyl radical, and hydrogen peroxide. The 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) free radical scavenging assay confirmed the free radical scavenging ability of CeO2 PCFs. Furthermore, CeO2 PCFs with large surface area and porous structure efficiently adsorbed benzo[a]pyrene. The designed CeO2 PCFs can serve as new antioxidant nanozymes for scavenging reactive oxygen species and adsorbing polycyclic aromatic hydrocarbons (PAHs).
INORGANIC CHEMISTRY
(2023)
Article
Agricultural Engineering
Chang-Mao Hung, Chiu-Wen Chen, Chin-Pao Huang, Der-Shyan Sheu, Cheng-Di Dong
Summary: This study aimed to assess the combined use of biopolymer, poly-3-hydroxybutyrate, and peroxymonosulfate to degrade phthalate esters (PAEs) and decontaminate waste-activated sludge (WAS). The combined treatment removed 86% of PAEs from WAS in 12 hours and enriched the PAE-biodegrading microbes. The use of poly-3-hydroxybutyrate and peroxymonosulfate showed promising potential for WAS pretreatment, contributing to circular bioeconomy and pollution mitigation.
BIORESOURCE TECHNOLOGY
(2023)
Article
Environmental Sciences
Chang-Mao Hung, Chin-Pao Huang, Shu-Ling Hsieh, Ya-Ting Chen, Chiu-Wen Chen, Cheng-Di Dong
Summary: This study presents an efficient method for remediating DEHP-contaminated marine sediments using water hyacinth biochar (WHBC) as a carbocatalyst activated by calcium peroxide (CP). The catalytic capacity of WHBC was significantly influenced by the pyrolysis temperature. The WHBC/CP system achieved a 94% removal of DEHP, with singlet oxygen (1O2) and electron-rich carbonyl functional groups playing crucial roles in the non-radical activation of CP. Moreover, WHBC showed lower cytotoxicity in HepG2 cells and induced cell cycle arrest at the G2/M phase.
ENVIRONMENTAL RESEARCH
(2023)
Review
Chemistry, Physical
Parushi Nargotra, Vishal Sharma, Yi-Chen Lee, Yung-Hsiang Tsai, Yung-Chuan Liu, Chwen-Jen Shieh, Mei-Ling Tsai, Cheng-Di Dong, Chia-Hung Kuo
Summary: The urgent demand for alternative energy sources is due to the burden on fossil fuels and resulting energy crisis and climate change. Lignocellulosic biomass is a renewable and alternative bioresource for energy generation. Different pretreatment strategies have been established to overcome biomass recalcitrance, and biological pretreatment using microbial enzymes is a promising method. Cellulases, hemicellulases, and ligninolytic enzymes have numerous industrial applications. This review provides a detailed description of these enzymes and their prospective applications in lignocellulosic biomass valorization. Solid state fermentation and enzyme immobilization strategies are discussed, along with future prospects.
Article
Biotechnology & Applied Microbiology
Chang-Mao Hung, Chin-Pao Huang, Shu-Ling Hsieh, Ya-Ting Chen, Chiu-Wen Chen, Cheng-Di Dong
Summary: This study developed an advanced oxidation process using water hyacinth biochar (WHBC) as a green catalyst to activate calcium peroxide (CaO2; CP) for the remediation of PAH-contaminated sediments, and emphasized the biochar-driven cellular oxidative stress. The catalytic capacity of WHBC was determined at pyrolysis temperature between 300 and 900 degrees C. WHBC prepared at 700 degrees C (WHBC700) and CP removed 74% of PAHs from the sediment matrix.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Article
Biotechnology & Applied Microbiology
Anusuiya Singh, Chiu-Wen Chen, Anil Kumar Patel, Cheng-Di Dong, Reeta Rani Singhania
Summary: The depletion of fossil fuels has led to an energy crisis, which has resulted in a shift towards alternative energy resources. Lignocellulosic biomass or agricultural residue can be used to produce bioethanol to address the energy crisis and reduce environmental pollution. Sorghum distillery residue (SDR) generated during Kaoliang liquor production can be utilized to produce bioethanol and solve environmental problems.
BIOENGINEERING-BASEL
(2023)
Article
Agricultural Engineering
Chang-Mao Hung, Chiu-Wen Chen, Chin-Pao Huang, Cheng-Di Dong
Summary: This study synthesized a novel material, dual heteroatom nitrogen and boron-co-doped lignin-based biochar (NB-LGBC), which was used for the activation of calcium peroxide (CP) to enhance the removal of organic micropollutants (OMPs), such as 4-nonylphenol (4-NP), from waste activated sludge (WAS). The introduction of NB-LGBC/CP significantly improved the degradation of 4-NP through a synergistic interaction and electron transfer. Furthermore, the NB-LGBC/CP treatment enriched specific bacteria, Desulfonatronum within the Proteobacteria phylum, in the WAS, enhancing the biological treatment capacity of 4-NP. Therefore, NB-LGBC shows great potential as a novel approach for decontamination of WAS.
BIORESOURCE TECHNOLOGY
(2023)
Article
Environmental Sciences
Vaibhav Sunil Tambat, Anil Kumar Patel, Chiu-Wen Chen, Tirath Raj, Jo-Shu Chang, Reeta Rani Singhania, Cheng-Di Dong
Summary: Globally, environmental concerns are increasing due to pollution levels, particularly hazardous heavy metals like vanadium. This study aims to develop a sustainable method for vanadium removal and utilize the biomass for biofuels, addressing the lack of green treatment methods. The use of microalgae for vanadium treatment has shown promising results, with significant improvement in removal efficiency after optimizing key parameters.
ENVIRONMENTAL POLLUTION
(2023)
Review
Green & Sustainable Science & Technology
Henna Mohi ud din Wani, Chiu-Wen Chen, Chun-Yung Huang, Reeta Rani Singhania, Young Joon Sung, Cheng-Di Dong, Anil Kumar Patel
Summary: Bioactive peptides derived from proteinaceous red algae biomass have attracted significant attention for their varied structures and potential applications. However, there is a lack of research on feasible approaches for producing and purifying bioactive peptides. This article explores the latest trends in easily applicable approaches for extracting bioactive peptides for cutaneous applications. It also emphasizes the importance of peptide purity and bioactivity, and suggests future research directions to increase yield and improve separation methods, as well as conducting human clinical trials to validate their health benefits.
Article
Green & Sustainable Science & Technology
Yee Cheng Lim, Chih-Feng Chen, Chiu-Wen Chen, Cheng-Di Dong
Summary: This study evaluated the feasibility of using harbor sediments and oyster shells for lightweight aggregate (LWA) production. It was found that the LWAs prepared with a 5-15% oyster shell content and sintered at 1125℃ were suitable for structural lightweight concrete, meeting the regulations for building materials in Taiwan.
Review
Chemistry, Multidisciplinary
Ashutosh Tiwari, Chiu-Wen Chen, Dibyajyoti Haldar, Anil Kumar Patel, Cheng-Di Dong, Reeta Rani Singhania
Summary: Biorefinery is a promising alternative to petrorefinery for sustainable development, with lignocellulosic biomasses as the most important raw material. Enzymatic conversion of biomasses into bioethanol is considered the most sustainable method, but biomass recalcitrance presents a major challenge. Pretreatment targeting lignin, the main contributor to recalcitrance, is necessary to make cellulose and hemicellulose more accessible to enzymes. Laccase, a lignin-degrading enzyme, is a potential option for biological pretreatment, although its slow reaction rate is a limitation. This article provides insights into biorefinery and emphasizes the significance of laccase.
APPLIED SCIENCES-BASEL
(2023)
Review
Chemistry, Multidisciplinary
Rhessa Grace Guanga Ortizo, Vishal Sharma, Mei-Ling Tsai, Jia-Xiang Wang, Pei-Pei Sun, Parushi Nargotra, Chia-Hung Kuo, Chiu-Wen Chen, Cheng-Di Dong
Summary: Bioactive peptides derived from fish byproduct protein hydrolysate have vast potential as functional food ingredients. Enzymatic hydrolysis is the preferred method for the preparation of these peptides due to its high specificity, mild reaction conditions, and lack of residual organic solvents. However, the use of proteases and the availability of food-grade enzymes pose limitations. Current research focuses on the purification and identification of these peptides, as well as their bioactivities, including antiproliferative, antimicrobial, antihypertensive, antiglycemic, antitumor, and antioxidative functions. The growing interest in proteomics and the utilization of marine and aquatic waste stems from the bioactivity and sustainability of these products.
APPLIED SCIENCES-BASEL
(2023)
Article
Agricultural Engineering
Chang-Mao Hung, Jia-Wei Cheng, Chiu-Wen Chen, Chin-Pao Huang, Cheng-Di Dong
Summary: The effect of pyrolysis atmosphere (CO2 or N2), pyrolysis temperature (300-900 degrees C), and heteroatom (N, B, O, P, NP, or NS) doping on the content of polycyclic aromatic hydrocarbons in pineapple leaf biochar was investigated. Without doping, the highest polycyclic aromatic hydrocarbon production (1332 +/- 27 ng/g) was observed in CO2 at 300 degrees C, while the lowest (157 +/- 2 ng/g) was observed in N2 at 700 degrees C. The main components, naphthalene and acenaphthylene, accounted for about 91% of the total polycyclic aromatic hydrocarbon in biochar produced under CO2 at 300 degrees C. Doping significantly reduced the total hydrocarbon content, with reductions of 49% (N), 61% (B), 73% (O), 92% (P), 93% (NB), and 96% (NS) under the conditions of maximal polycyclic aromatic hydrocarbon production (CO2, 300 degrees C). The findings highlight the importance of controlling pyrolysis atmosphere, temperature, and heteroatom doping for the management of polycyclic aromatic hydrocarbons in biochar production and contribute to the development of circular bioeconomy.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Chang-Mao Hung, Chiu-Wen Chen, Chin-Pao Huang, Cheng-Di Dong
Summary: The formation of polycyclic aromatic hydrocarbons (PAHs) in sorghum distillery residue-derived biochar (SDRBC) was evaluated under different thermochemical pyrolysis conditions. Boron doping significantly reduced the PAHs content in SDRBC, demonstrating its potential for efficient PAHs reduction. Combination of pyrolysis temperature and atmosphere, along with heteroatom doping, is an effective strategy for suppressing PAHs formation and utilizing pyrolysis products with low carbon footprint.
BIORESOURCE TECHNOLOGY
(2023)
Review
Environmental Sciences
Thanh-Binh Nguyen, Kamakshi Sherpa, Xuan-Thanh Bui, Van-Truc Nguyen, Thi-Dieu-Hien Vo, Hien-Thi-Thanh Ho, Chiu-Wen Chen, Cheng-Di Dong
Summary: Biochar usage in soil remediation has shown promising potential in improving soil quality, increasing crop yields, and mitigating climate change through carbon sequestration. However, the long-term implications of biochar on soil health and the environment still need further investigation. Understanding the key factors, potential risks, and future research directions in biochar remediation is crucial for guiding future studies.
ENVIRONMENTAL POLLUTION
(2023)
Review
Chemistry, Multidisciplinary
Parushi Nargotra, Vishal Sharma, Mei-Ling Tsai, Shu-Ling Hsieh, Cheng-Di Dong, Hui-Min David Wang, Chia-Hung Kuo
Summary: The increasing concerns about climate change and the overexploitation of non-renewable resources have led to the need for alternative renewable and eco-friendly resources for the production of innovative materials, achieving the goals of bioeconomy. Lignocellulosic biomass (LB), derived from plant-based agro-industrial food waste and crop residues, can be utilized for the production of various value-added chemicals and bioproducts. Cellulose, derived from LB, is the most abundant natural and biodegradable organic polymer, with wide-ranging applications in lignocellulosic biorefineries and food industries. However, the extraction of cellulose from LB is challenging due to the recalcitrant nature of biomass. A suitable cellulose extraction method through LB fractionation is necessary to improve cellulose yield. Nanocellulose (NC) has great potential and researchers are interested in developing environmentally friendly cellulose extraction methods. Cellulose nanofibrils and nanocrystals have excellent mechanical properties, non-toxic characteristics, and biodegradability, making them suitable for diverse industrial sectors. This review emphasizes the potential role of cellulose extraction and NC production from agro-food waste, discusses different pretreatment methods for cellulose extraction from LB, and highlights the applications and future directions of cellulose and NC-based commercial products.
APPLIED SCIENCES-BASEL
(2023)