Journal
COMPOSITES SCIENCE AND TECHNOLOGY
Volume 171, Issue -, Pages 111-117Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2018.12.019
Keywords
Cellulose nanofibrils; Nanocomposites; Mechanical properties; Thermal properties; Layered double hydroxide
Categories
Funding
- National Natural Science Foundation of China [51703177, 21704079]
- Fundamental Research Funds for the Central Universities [WUT: 2017IVA107, 2017III025, 2018III009, 2018IVB022, 2018IVB041]
- State Key Laboratory of Pulp and Paper Engineering [201765]
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High-performance and environment-friendly biomass-based composite films have drawn much attention recently. Here, bio-nanocomposites of TEMPO-oxidized cellulose nanofibrils (TOCNs) reinforced with layered double hydroxides (LDHs) were prepared through an environmentally benign pathway by aqueous dispersion. The results showed that LDHs could be uniformly dispersed in the cellulose nanofibril matrix to form an intercalated nanolayered structure due to good compatibility and the formation of ionic and hydrogen bonds between LDHs with positive charges and TOCNs with negative charges. The TOCN-LDH composite films exhibited high light transmittance, which exceeded 80% with an LDHs content of less than 10%. Moreover, the incorporation of LDHs improved not only the mechanical properties of the cellulose nanofibrils, but also their thermal stability, flame retardancy and hydrophobicity. More specifically, the highest Young's modulus and tensile strength reached 39.3 GPa of TOCN-LDH20 and 358 MPa of TOCN-LDH5, which were 364% and 178% of the neat TOCN film, respectively. The water contact angle and limiting oxygen index of the TOCN-LDH composite film increased from 46 degrees to 103 degrees, and from 25 to 31, respectively, with the LDH content increase from 0 to 20 wt%.
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