Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 7, Pages 958-962Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900021
Keywords
carbon dioxide; epoxides; host-guest systems; metalloporphyrins; zeolites
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Funding
- Science AMP
- Technology Development Fund of Tianjin Education Commission for Higher Education [2017KJ127]
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It is a great challenge to rationally integrate multiple reactive sites into a composite material with confined nanospace, which can be applied as a nanoreactor to facilitate targeting catalytic reaction. In this work, an ionic metalloporphyrin has been encapsulated in situ into ZIF-8 for a solvent-free synthesis of cyclic carbonates from CO2 and epoxides without any co-catalyst under 1 atm CO2.
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