Article
Chemistry, Physical
A. E. B. Lima, R. Y. N. Reis, L. S. Ribeiro, L. K. Ribeiro, M. Assis, R. S. Santos, C. H. M. Fernandes, L. S. Cavalcante, E. Longo, J. A. O. Osajima, G. E. Luz Jr
Summary: CuWO4-Pal nanocomposite was successfully synthesized and applied in the photodegradation of antibiotic CIP under visible-light irradiation. The study showed that the nanocomposite exhibited excellent photocatalytic performance for the degradation of CIP.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Environmental Sciences
M. C. Shibu, M. D. Benoy, S. Shanavas, J. Duraimurugan, G. Suresh Kumar, Mohammad Abu Haija, P. Maadeswaran, T. Ahamad, Quyet Van Le, S. M. Alshehri
Summary: SnO2 and SnO2/rGO nanostructures were successfully synthesized and their properties were studied using various techniques. The results showed an enhancement in the photocatalytic properties of the SnO2/rGO nanostructures.
Article
Environmental Sciences
Yasin Orooji, Khatereh Pakzad, Mahmoud Nasrollahzadeh
Summary: This study presents a green and novel catalyst, a magnetic copper complex conjugated to modified calcium lignosulfonate (LS), prepared through a diamine (Fe3O4@LS@naphthalene-1,5-diamine@copper complex; FLN-Cu). The synthesized catalyst showed excellent photocatalytic performance in the degradation of dyes under UV irradiation. The catalyst exhibited high stability and could be easily separated and reused multiple times without significant loss of catalytic ability.
Article
Engineering, Environmental
Min Zou, Chao Tan, Yan Zhang, Junjie Hu, Zhou Ma, Zhengqiu Yuan, Lei Zhang, Ming Wu, Hu Zhou
Summary: To solve the recovery problem of nanosized powder form of photocatalysts, a macroscale membrane-shaped photocatalyst with high efficiency and stability was developed. Zinc oxide (ZnO) and cadmium sulfide (CdS) nanoparticles were loaded onto a polyurethane (PU) matrix through blending and in-situ growth. The introduction of ZnO improved the hydrophilicity of the membrane without compromising its structural integrity. After constructing CdS/ZnO heterojunction, the photocatalytic activity was further enhanced. The CdS/ZnO/PU composite membrane displayed the highest photocatalytic performance, with a degradation efficiency of potassium ethyl xanthate (PEX) up to 97.06%, significantly higher than the ZnO/PU and CdS/PU membranes. Moreover, the composite membrane also exhibited satisfactory performance for removing various refractory organic pollutants.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Physical
Lufang Ning, Xue Chen, Zhouping Wang, Jing Xu
Summary: A magnetically separable Co-imbedded N-doped carbonaceous framework (Co-N-C)/supramolecular perylene diimide (SA-PDI) photocatalyst was prepared via in-situ self-assembly, forming a 3D/1D heterostructure. The Co-N-C acted as a multifunctional co-catalyst to enhance the performance of SA-PDI in pollutant degradation, H2O2 production, and disinfection activities. The Co-N-C/SA-PDI photocatalyst exhibited significantly improved degradation rates, H2O2 generation, and bacterial inactivation compared to SA-PDI. This study provides a novel strategy for designing high-efficiency photocatalysts for energy conversion and environmental remediation based on SA-PDI.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Multidisciplinary
Narasimharao Kitchamsetti, Chidurala Shilpa Chakra, Ana Lucia Ferreira De Barros, Daewon Kim
Summary: The preparation of metal organic frameworks (MOFs) has gained attention due to their exceptional properties. In this study, Ag-MOF nanosheets were synthesized using a solvothermal assisted route and applied as a photocatalyst for the removal of different organic pollutants. Various characterization techniques were used to analyze the composition, optical properties, morphology, and microstructure of the AMOF nanosheets. The results showed that the AMOF nanosheets exhibited significant photocatalytic activity for the degradation of dye pollutants.
Article
Chemistry, Multidisciplinary
Manjiri A. Mahadadalkar, Ganesh Dhakal, Sumanta Sahoo, Deivasigamani Ranjith Kumar, Marjorie Lara Baynosa, Van Quang Nguyen, Mostafa Saad Sayed, Abdelrahman M. Rabie, Woo Kyoung Kim, Jae-Jin Shim
Summary: In this study, a TiO2/In2S3 heterojunction composite photocatalyst was successfully prepared through a simple low-temperature hydrothermal method. The composite showed excellent photocatalytic degradation performance for Rhodamine B under solar light irradiation, with a degradation rate of 99.9% in just 20 minutes. The environmentally friendly synthesis process and high stability make the TiO2/In2S3 composite a promising candidate for cost-effective wastewater treatment.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Applied
Andre Torres-Pinto, Claudia G. Silva, Joaquim L. Faria, Adrian M. T. Silva
Summary: There is a strong demand to identify sustainable methods for producing nanostructured materials, particularly carbon nitride photocatalysts. This study evaluated the impact of different precursors on the microwave synthesis of these materials and their photocatalytic performances. The photocatalyst prepared with the urea precursor after a two-step microwave treatment showed the best performance for phenol degradation and total organic carbon removal.
Article
Chemistry, Inorganic & Nuclear
Zahra Jalalat, Aziz Habibi-Yangjeh, Paria Hemmati-Eslamlu, Yuksel Akinay
Summary: In this study, an s-scheme g-C3N4(M)/Bi5O7Br nanocomposite was synthesized via a simple precipitation method. The nanocomposite showed superior photocatalytic performance under visible light, exhibiting efficient degradation of various pollutants and conversion of Cr(VI) into Cr(III). Spectrophotometric, photoluminescence, and electrochemical studies confirmed the enhanced charge separation and movement within the photocatalyst. The nanocomposite also demonstrated biocompatibility, as evidenced by successful seed growth. In conclusion, the s-scheme g-C3N4(M)/Bi5O7Br system is a promising candidate for environmental detoxification.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Review
Green & Sustainable Science & Technology
Nur Aqilah Mohd Razali, Wan Norharyati Wan Salleh, Farhana Aziz, Lau Woei Jye, Norhaniza Yusof, Ahmad Fauzi Ismail
Summary: This article discusses the current research status and issues of tungsten trioxide (WO3) as a promising photocatalyst for wastewater treatment, exploring the importance of improving efficiency and summarizing different precursors, synthesis methods, modification types, and operational parameters in a photocatalytic system. The review emphasizes the impact of photocarrier recombination on the widespread application of WO3.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Materials Science, Multidisciplinary
Huihui Deng, Cunqi Qin, Kemei Pei, Guoyong Wu, Mei Wang, Huagang Ni, Peng Ye
Summary: In the catalytic process of semiconductors, the rapid recombination of electron-holes greatly reduces the catalytic activity. A low-defect reduced hydroxylated graphene (RGOH) was used as a carrier material to prepare TiO2/reduced hydroxylated graphene (T/RGOH) nanocomposite photocatalyst, which showed a higher degradation efficiency for methylene blue compared to pure TiO2 and TiO2/reduced graphene oxide (T/RGO) nanocomposite photocatalysts. The enhanced performance was attributed to the higher electrical conductivity of RGOH and the existence of Ti-O-C bonds in the T/RGOH, which improved electron-hole separation and prevented rapid recombination.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Review
Agricultural Engineering
Priyanka Bhardwaj, Naviljyot Kaur, Manickam Selvaraj, Hamed A. Ghramh, Badria M. Al-Shehri, Gursharan Singh, Shailendra Kumar Arya, Kalpana Bhatt, Suresh Ghotekar, Ravi Mani, Soon Woong Chang, Balasubramani Ravindran, Mukesh Kumar Awasthi
Summary: This review provides experimental data on a range of emerging recalcitrant compounds and discusses the laccase-mediated degradation mechanism in detail. Laccase immobilization can improve degradation efficiency and reusability. Further studies are needed to uncover the proper degradation mechanisms for each compound.
BIORESOURCE TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Hongzhi Yang, Tianpei He, Yaohui Wu, Jinhua Luo, Aihua Zhang, Xiaoyong Chen, Yelin Zeng, Yonghong Wang, Yunlin Zhao, Guangjun Wang
Summary: A novel PbMoO4@MBC (MBL-2) magnetic heterojunction photocatalyst was prepared, which had a large specific surface area, excellent magnetic response, and high light absorption capacity. It exhibited high photocatalytic activity and stability.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Environmental Sciences
Amal Soufi, Hind Hajjaoui, Mohamed Abdennouri, Samir Qourzal, Noureddine Barka
Summary: A novel ternary Mg0.8Cu0.2Fe2O4/SiO2/CeO2 nanocomposite was fabricated using an ultrasonic-assisted technique and demonstrated excellent Fenton-like activity for the removal of tartrazine dye. The nanocomposite was synthesized by coating SiO2 around Mg0.8Cu0.2Fe2O4 core and then incorporating CeO2 using a simple ultrasonic-assisted route. The removal efficiency of tartrazine dye reached 100% within 120 min using 0.2 g/L of Mg0.8Cu0.2Fe2O4/SiO2/CeO2.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Jiachi Liang, Xinqi Li, Jianliang Zuo, Jing Lin, Zili Liu
Summary: The binary composite catalyst of g-C3N4 and BiOI shows great potential in visible light catalytic degradation of organic pollutants. By adjusting the scale and morphology of the heterojunction composite catalyst, a Z-scheme heterojunction composite catalyst (0D/2D g-C3N4/BiOI) was developed, which demonstrates superior performance in degrading organic pollutants and provides a universal approach to enhance photocatalytic efficiency.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2021)
Retraction
Nanoscience & Nanotechnology
Bibekananda De, Brigitte Voit, Niranjan Karak
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Paper & Wood
Geeti Kaberi Dutta, Niranjan Karak
Summary: This study presents an environmentally friendly fabrication method of a bio-based waterborne polyester nanocomposite for corrosion protection of metal surfaces. The nanocomposite, reinforced with a cellulose nanofiber-reduced graphene oxide-zinc oxide nanohybrid, showed excellent anticorrosion activity and maintained transparency, mechanical toughness, thermal stability, and chemical resistance. The prepared thermosetting nanocomposites have enormous potential as sustainable anticorrosive coating materials.
Article
Polymer Science
Nobomi Borah, Niranjan Karak
Summary: This scientific paper discusses the synthesis of a bio-based tannic acid epoxy resin TAE100 with excellent mechanical properties and adhesive strength, showing potential applications in eco-coatings and adhesives. The thermosets are also biodegradable, as confirmed by microbial testing, making them suitable for environmentally friendly purposes.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Environmental
Sukanya Kundu, Niranjan Karak
Summary: This article reviews the recent progress in the application of polymeric photocatalytic membranes (PPM) for environmental remediation. It focuses on the removal efficiency and mechanisms for degrading various pollutants, and highlights the challenges and performances of fabricating PPMs in the presence of sunlight.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Green & Sustainable Science & Technology
Dimpee Sarmah, Niranjan Karak
Summary: This study demonstrates a new synthetic strategy to improve the mechanical properties of starch grafted poly(acrylic acid) hydrogel by introducing a double cross-linked network. The cross-linked hydrogel exhibits excellent mechanical strength and notable adsorption capacity for heavy metal ions, making it promising for wastewater purification and reusability.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Polymer Science
Ashok Bora, Niranjan Karak
Summary: This study synthesized a biobased superabsorbent with high water absorption capacity and fast water absorption rate using starch and itaconic acid, which shows great potential to be used as an environmentally friendly superabsorbent in agricultural applications.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Polymer Science
Annesha Kar, Niranjan Karak
Summary: This article reports the synthesis of a bio-based water-soluble poly(ester amide) through a solvent-free environmentally friendly method, and its further modification using poly(vinyl alcohol). The prepared polymeric resin exhibited excellent mechanical properties, good thermal stability, transparency, and biodegradability, making it a potential environmentally friendly coating material.
JOURNAL OF POLYMER RESEARCH
(2022)
Review
Chemistry, Multidisciplinary
Poonam Singh, Anuj Rana, Niranjan Karak, Indresh Kumar, Sravendra Rana, Pankaj Kumar
Summary: Sustainable development is a critical concern in today's fast-paced technological world, and the use of renewable resources is essential in achieving sustainable development goals. Researchers have been focusing on the development of bio-based polymers derived from renewable resources like lignin, chitosan, vegetable oils, cellulose, etc. These polymers, particularly those derived from vegetable oils, offer unique properties that can be used to create value-added systems, such as coatings with improved protective properties against corrosion. This review explores the use of vegetable oil-based self-healing polymers in anti-corrosion coatings.
Article
Materials Science, Composites
Raghav Poudel, Niranjan Karak
Summary: In this study, a green composite of yam and alkali-treated corn stalk fiber was prepared, which exhibited good mechanical and thermal properties and excellent biodegradability under normal environmental conditions. The potential applications of this composite material include packaging, biomedical, automobile, and construction sectors.
COMPOSITES SCIENCE AND TECHNOLOGY
(2023)
Article
Polymer Science
Kalyan Dutta, Niranjan Karak
Summary: BPA-based epoxy thermoset has toxic effects on human health, so there is a need for environmentally friendly bio-based alternatives. In this study, a gallic acid amide was synthesized from renewable gallic acid and diethanol amine, and the epoxy resin was obtained through a condensation reaction. The synthesized epoxy thermosets showed excellent properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Samiran Morang, Ashutosh Bandyopadhyay, Jay Hind Rajput, Biman B. Mandal, Atharva Poundarik, Niranjan Karak
Summary: Waterborne polyurethanes with smart attributes like self-healing, shape-memory, reprocessability, and excellent mechanical properties are achieved through the triple synergistic effect of dynamic hard domains, asymmetric IPDI-IPDA architecture, and shape memory effect. This strategy leads to the synthesis of robust self-healable WPUs with high healing efficiency, shape recovery, and outstanding mechanical strength. The SHWPU elastomer exhibits all characteristics of advanced materials with smart attributes and eco-friendly nature.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Samiran Morang, Ashutosh Bandyopadhyay, Biman B. Mandal, Niranjan Karak
Summary: A transparent, self-healable, and highly tough waterborne polyurethane elastomer with amazing mechanical properties has been developed by molecular engineering. The elastomer shows excellent shape recovery, high fracture energy, and good hemocompatibility. Additionally, it retains its mechanical strength during melt re-processability and can be biodegraded with the help of microbes. This material holds great potential as a smart biomaterial and coating for biomedical devices.
ACS APPLIED BIO MATERIALS
(2023)
Article
Materials Science, Biomaterials
Dimpee Sarmah, Munmi Borah, Manabendra Mandal, Niranjan Karak
Summary: In recent years, polysaccharide-based hydrogels have gained attention due to their biodegradability, biocompatibility, and non-toxicity. This study presents a simple method for synthesizing a mechanically tough, biocompatible, and biodegradable hydrogel using polysaccharides like starch and agar. The hydrogel showed high mechanical strength and cell viability, and also exhibited good encapsulation efficiency for antibacterial drugs. The hydrogel with loaded drug demonstrated the potential to be used as a promising candidate in wound dressing applications.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Materials Science, Multidisciplinary
Samiran Morang, Jay Hind Rajput, Anwesha Mukherjee, Atharva Poundarik, Bodhisatwa Das, Niranjan Karak
Summary: This study introduces a new strategy to enhance the self-healing ability and mechanical properties of polyurethane (PU) films. By utilizing the triple synergistic effect of a dynamic hard domain, multiple hierarchical hydrogen bonding, and semi-interpenetrating network formation, a series of self-healable waterborne PU/polyacrylic films were prepared. These films exhibit excellent mechanical robustness and biodegradability. The study also demonstrates the potential of these films in biomedical applications.
MATERIALS ADVANCES
(2023)
Article
Chemistry, Multidisciplinary
Nobomi Borah, Muzamil Ahmad Rather, Bibrita Bhar, Biman B. Mandal, Manabendra Mandal, Niranjan Karak
Summary: This study successfully synthesized a nanohybrid of cellulose nanofibers loaded with iron oxide nanoparticles, which showed improved thermomechanical performance and tunable applicability in a bio-based epoxy matrix. Additionally, the nanocomposite exhibited pH-responsive release behavior when used as a carrier platform for an antibacterial drug.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)