Article
Chemistry, Physical
M. T. Colomer, E. Rodriguez, M. Moran-Pedroso, F. Vattier, A. de Andres
Summary: Novel Tb-doped TiO2 hollow spheres (HSs) have been synthesized for the first time in the range of 0.0-2.0 at.%, revealing a significant impact of Tb presence and morphology on the anatase-to-rutile transition temperature. Contrary to expectations, Tb doping reduces the transition temperature and favors rutile phase formation in HSs. XPS measurements confirm the presence of Tb3+ and Tb4+ in both HSs and NPs, with Tb4+ contributing to weakened f-f emission intensity and destabilization of the anatase phase.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Applied
Nhan V. Nguyen, Nam Nguyen, Jason R. Hattrick-Simpers, Oleg A. Kirillov, Martin L. Green
Summary: Transparent conducting oxides have high optical transmittance and are electrically conductive, with differences in optical responses between materials such as TiO2, ZnO, and SnO2. The bandgap and electronic characteristics were determined and discussed in this study.
APPLIED PHYSICS LETTERS
(2021)
Article
Chemistry, Physical
Min Chen, Jianhua Chen, Chuncheng Chen, Changbin Zhang, Hong He
Summary: The research shows that CuOx-rutile is more suitable for the oxidation of ammonia gas under visible light compared to CuOx-anatase, contrary to previous beliefs. Further analysis revealed that the interaction between CuOx and TiO2 differs significantly in different crystal phases, resulting in distinct directions of charge transfer.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Materials Science, Multidisciplinary
Hussein O. Badr, Francisco Lagunas, Daniel E. Autrey, Jacob Cope, Takayuki Kono, Takeshi Torita, Robert F. Klie, Yong-Jie Hu, Michel W. Barsoum
Summary: We synthesized 1D TiO2-based nanofilaments by reacting Ti-containing precursors with quaternary ammonium hydroxides at near-ambient conditions. The structure was previously believed to be anatase-based, but we now conclude that it is actually a 1D titania lepidocrocite-based structure. The NFs grow along [100] and tend to self-assemble/stack in two directions. The band gap is not affected by the nature of the cations surrounding the NFs.
Article
Chemistry, Physical
Davina Messou, Vincent Bernardin, Frederic Meunier, Marta Borges Ordono, Atsushi Urakawa, Bruno F. Machado, Vincent Colliere, Regis Philippe, Philippe Serp, Carole Le Berre
Summary: The catalytic performances of TiO2-supported Ni catalysts for the methanation of CO2 are investigated, showing that the crystalline phases of TiO2 significantly affect the activity of Ni. Mixing rutile and anatase TiO2 can increase the reaction rate significantly without direct contact between the two catalysts. The synergy between the two catalysts is attributed to hydrogen spillover mediated by surface or gas-phase species.
JOURNAL OF CATALYSIS
(2021)
Review
Chemistry, Multidisciplinary
Diana Rakhmawaty Eddy, Muhamad Diki Permana, Lintang Kumoro Sakti, Geometry Amal Nur Sheha, Solihudin, Sahrul Hidayat, Takahiro Takei, Nobuhiro Kumada, Iman Rahayu
Summary: This study aims to clarify the differences between titanium dioxide polymorphs and their properties in different photocatalytic applications. Homophase titanium dioxide has disadvantages such as high recombination rates and low adsorption capacity. On the other hand, heterophase titanium dioxide can effectively stimulate electron transfer and exhibit superior photocatalytic performance. Various biphase and triphase polymorphs of titanium dioxide are discussed, and the focus is on the synthesis and application of heterophase titanium dioxide as a photocatalyst.
Article
Materials Science, Ceramics
Xiaoping Wu, Yong Liu
Summary: The transformation of anatase titanium dioxide to rutile form is influenced by factors such as heating temperature, heating time, and particle states. The roles of temperature and time in the anatase-rutile transformation for pigmentary TiO2 production are not clearly understood.
CERAMICS INTERNATIONAL
(2023)
Article
Geochemistry & Geophysics
Shenghua Wu, Jingwen Mao, Hong Yu, Daorong Tan, Xinxia Geng
Summary: The study of TiO2 polymorphs in the Dongyuan gold veins in South China provides important insights into the temperature range for early mineral precipitation and suggests that ore-forming fluids originated from deeper and hotter crustal levels in the shallow crust.
AMERICAN MINERALOGIST
(2021)
Article
Chemistry, Multidisciplinary
Pritha Biswas, Tamara D. Koledin, Skylar N. Farmer, Melissa K. Santala, Janet Tate
Summary: The transformation from amorphous to crystalline in TiO2 films in air leads to different polymorphs, which can be manipulated by introducing Sn into the system. Sn stabilizes the rutile structure at the Sn/TiO2 interfaces by scavenging oxygen, resulting in rutile formation.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Materials Science, Ceramics
Gloria M. Hernandez Ortiz, Rodrigo Parra, Vanesa Fuchs, Maria A. Fanovich
Summary: An effective method for the synthesis of TiO2-HA composite materials by sol-gel followed by carbon dioxide supercritical drying was presented. The influence of the amount of hydroxyapatite (HA) in the dioxide of titanium (TiO2) matrix on the crystalline structure and microstructure development of the composites was discussed.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Instruments & Instrumentation
Dimple Saikia, Priyanka Jadhav, Arti R. Hole, Chilakapati Murali Krishna, Surya P. Singh
Summary: This study demonstrates the application of Raman spectroscopy in monitoring the growth kinetics of three different pathogenic bacteria. The spectral features revealed temporal changes in the peptide and nucleic acid content of cells during different growth stages, and successful discrimination between growth phases was achieved using principal component analysis.
APPLIED SPECTROSCOPY
(2022)
Article
Thermodynamics
Manoel Y. Manuputty, Casper S. Lindberg, Jochen A. H. Dreyer, Jethro Akroyd, John Edwards, Markus Kraft
Summary: The study explores the relative stability of anatase and rutile in stagnation flame synthesis with stoichiometric mixtures. It shows high sensitivity of anatase-rutile composition to flame dilution and discusses two formation mechanisms/pathways. By applying a particle model and a phase transformation model, it is found that anatase formation is favored in more dilute flames while rutile is favored in less dilute flames.
COMBUSTION AND FLAME
(2021)
Article
Materials Science, Multidisciplinary
Fatemehsadat Moosavi, Alex Lemarchand, Cyrille Bazin, Maria Konstantakopoulou, Mathieu Fregnaux, Christophe Colbeau-Justin, Touraj Tavakoli Gheinani, Andrei Kanaev, Mehrdad Nikravech
Summary: Nanocomposite TiO2 coatings with mixed anatase-rutile crystalline polymorphs and strong adherence to glass substrates were prepared using a spray-plasma deposition method. The coating exhibited enhanced photocatalytic activity for cefixime antibiotic decomposition under UVA light illumination, and the activity significantly increased after the formation of the rutile phase, suggesting a synergistic effect of the two-component solids.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2022)
Article
Chemistry, Multidisciplinary
Ying Feng, YongChao Zhu, Tian Chen, Pengcheng Li, Bingjie Liu, Jianfeng Cai, Wenjie Liang, Hai Xu
Summary: Weakly crystalline TiO2 with high catalytic activity was prepared using a simple green chemical oxidation reaction at low temperatures, achieving significant degradation of methylene blue and isopropyl alcohol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Olufemi Olatidoye, Daria Thomas, Bishnu Prasad Bastakoti
Summary: A facile method of synthesizing mesoporous TiO2 thin films using polymeric micelles as a template is reported. The mesoporous TiO2 films showed enhanced photocatalytic activity due to increased surface area and rough surface around the pores. Photocatalytic testing demonstrated the effectiveness of the prepared mesoporous thin films in degrading dyes.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Physical
Monica Scarisoreanu, Alina G. Ilie, Evghenii Goncearenco, Ana Maria Banici, Iulia P. Morjan, Elena Dutu, Eugenia Tanasa, Ioana Fort, Miruna Stan, Cristian N. Mihailescu, Claudiu Fleaca
APPLIED SURFACE SCIENCE
(2020)
Article
Materials Science, Multidisciplinary
Victor Aurel Andrei, Cristiana Radulescu, Viorel Malinovschi, Alexandru Marin, Elisabeta Coaca, Maria Mihalache, Cristian Nicolae Mihailescu, Ioana Daniela Dulama, Sofia Teodorescu, Ioan Alin Bucurica
Article
Chemistry, Physical
Alexandra Sandulescu, Crina Anastasescu, Florica Papa, Monica Raciulete, Anca Vasile, Tanta Spataru, Monica Scarisoreanu, Claudiu Fleaca, Cristian N. Mihailescu, Valentin S. Teodorescu, Nicolae Spataru, Maria Zaharescu, Ioan Balint
Summary: In the light-triggered oxidation of phenol over TiO2 with noble metal loading, supported noble metals act as visible light absorbers, assist in charge separation, and catalyze the production of O-2(-), resulting in mild oxidation products and the mineralization of phenol to CO2 by center dot OH radicals. The presence of supported noble metals enhances the oxidative conversion of phenol through the interplay between center dot OH and O-2(-) production.
Article
Materials Science, Multidisciplinary
Maria Badiceanu, Sinziana Anghel, Natalia Mihailescu, Anita Ioana Visan, Cristian N. Mihailescu, Ion N. Mihailescu
Summary: The development of new biological devices requires continuous efforts in improving the functionalization based on materials and fabrication techniques. Laser techniques provide effective deposition methods to enhance coating adherence and biological characteristics without compromising mechanical properties. This review discusses various laser techniques compared to other deposition methods.
Article
Materials Science, Multidisciplinary
Dorel F. Albu, Jeanina Lungu, Gianina Popescu-Pelin, Cristian N. Mihailescu, Gabriel Socol, Adrian Georgescu, Marcela Socol, Alexandra Banica, Victor Ciupina, Ion N. Mihailescu
Summary: Active TiO2 semiconductor layers were synthesized using pulsed laser deposition under different gas atmospheres, and the morphological and structural characteristics of the TiO2 nanostructures were investigated. It was found that the gas nature played a key role in the deposited film's architecture and overall performance. The photovoltaic structures based on TiO2 coatings grown in He exhibited the best electro-optical performance.
Article
Chemistry, Inorganic & Nuclear
E. Goncearenco, I. P. Morjan, E. Dutu, M. Scarisoreanu, C. Fleaca, L. Gavrila-Florescu, F. Dumitrache, A. M. Banici, V. S. Teodorescu, C. Anastasescu, A. Sandulescu, I Balint
Summary: This study prepared W and V co-doped TiO2 nanoparticles using laser pyrolysis technique and chemical impregnation method. The addition of noble metals Pt or Pd improved the photocatalytic properties of the nanoparticles, with W:V:TiO2@Pt material showing better performance in the conversion of CH3OH compared to the reference Degussa P25 sample.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Engineering, Electrical & Electronic
Iuliana P. Morjan, Elena Dutu, Claudiu T. Fleaca, Florian Dumitrache, Ion Morjan, Natalia Mihailescu, Mihai Demian, Valentin S. Teodorescu, Monica Scarisoreanu
Summary: The effect of annealing on the structural, optical, and electrical properties of F&Zn double doped SnO2 nanoparticles was investigated. Annealing resulted in an increase in crystallite size, disappearance of divalent tin phases, and complete removal of fluorine at 1000 degrees C. It also reduced the oxygen vacancies and caused changes in the optical band gap energies.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2022)
Article
Chemistry, Physical
Cristian N. Mihailescu, Muhammad Arif Mahmood, Natalia Mihailescu, Mihai Oane
Summary: Recently, the study of ultrafast laser-material interaction has gained worldwide attention. Computational models are needed to reduce the cost of real-time experimentation. A non-Fourier heat equation was used to solve the problem, and a close correlation between simulations and experimental results was found. Interesting phenomena were observed, such as the coupling of electron-phonon becoming zero and the propagation of thermal waves due to non-Fourier heat implementation.
Article
Crystallography
Cristian N. Mihailescu, Mihai Oane, Bogdan A. Sava, Andrei C. Popescu, Mihail Elisa, Muhammad Arif Mahmood, Natalia Mihailescu, Ana V. Filip, Sinziana Andreea Anghel, Ion N. Mihailescu, Carmen Ristoscu
Summary: A semi-analytical-numerical solution is proposed for the laser additive manufacturing process, which describes the interaction between laser and ceramics. The thermal distribution within the ceramic sample is inferred using the Fourier heat equation. The study shows an inverse correlation between the laser scanning speed and thermal distribution intensity. This model is useful for describing and monitoring low-intensity laser beam-ceramic processing.
Article
Nanoscience & Nanotechnology
Ana-Maria Panaitescu, Iulia Antohe, Ana-Maria Raduta, Sorina Iftimie, Stefan Antohe, Cristian Nicolae Mihailescu, Vlad-Andrei Antohe
Summary: In this study, zinc telluride thin films were deposited on optical glass using radio-frequency magnetron sputtering. The films were characterized optically and electrically, showing excellent properties for high-performance small-wavelength photodetectors.
Article
Chemistry, Multidisciplinary
Luiza Izabela Toderascu, Livia Elena Sima, Stefana Orobeti, Paula Ecaterina Florian, Madalina Icriverzi, Valentin-Adrian Maraloiu, Cezar Comanescu, Nicusor Iacob, Victor Kuncser, Iulia Antohe, Gianina Popescu-Pelin, George Stanciu, Petre Ionita, Cristian N. N. Mihailescu, Gabriel Socol
Summary: In this study, L-Cysteine-coated magnetic iron oxide nanoparticles loaded with doxorubicin were synthesized and extensively characterized. The binding of doxorubicin to L-Cysteine was confirmed, and the internalization of the nanoparticles delivering doxorubicin was observed in melanoma cells. The nanoparticles also modulated cell signaling pathway activity, induced cell cycle arrest and apoptosis, and exhibited pH-dependent drug release. These results demonstrate the potential of the nanoparticles as efficient drug delivery vehicles in melanoma therapy.
Article
Multidisciplinary Sciences
Mihai Oane, Bogdan A. Sava, Muhammad Arif Mahmood, Natalia Mihailescu, Sinziana Anghel, Ana V. Filip, Ion N. Mihailescu, Cristian N. Mihailescu, Carmen Ristoscu
Summary: A novel analytical formalism based on the Quantum heat transport equation is proposed to describe the interaction between femtosecond/picosecond laser pulses and DNA. The formalism generates solutions based on inputs such as voltage, laser beam intensity, and laser-DNA interaction time. Thermal waves induced inside irradiated DNA are accounted for. Analytical simulations show that the optimal regime of laser-DNA interaction occurs when a potential carrier generated at the interface is equal to 3.5 x 10-3 eV. It should be noted that the formalism breaks down if the potential carrier generated at the interface is less than 10-2 eV. Additionally, for pulse durations less than 1 ps, the spatial-temporal distribution of the laser beam plays a crucial role in defining the shape and magnitude of the thermal distribution within the irradiated DNA strands.
Article
Chemistry, Inorganic & Nuclear
Ayushi Rai, Nicusor Iacob, Aurel Leca, Claudiu Locovei, Victor Kuncser, Cristian N. Mihailescu, Andreas Delimitis
Summary: The structural properties of VO2 thin films grown on LSAT or Si substrates by PLD were investigated using TEM methods. The successful growth of VO2 in variable thicknesses was confirmed by optimizing the O-2 partial pressure and growth temperature. The films exhibited a columnar polycrystalline morphology with narrow columns, and four VO2 polymorphs were detected. Strain measurements revealed that the residual strain was minimized due to the columnar morphology and intrinsic oxide layers. The complementary electrical and magnetic measurements confirmed a transition from the M1 to the R phase in thick VO2 films, influenced by the initial phase percentage.
Article
Nanoscience & Nanotechnology
Evghenii Goncearenco, Iuliana P. Morjan, Claudiu Teodor Fleaca, Florian Dumitrache, Elena Dutu, Monica Scarisoreanu, Valentin Serban Teodorescu, Alexandra Sandulescu, Crina Anastasescu, Ioan Balint
Summary: TiO2 nanoparticles were synthesized by laser pyrolysis with varying working pressures using ethylene as sensitizer. The obtained powders were analyzed and compared, showing differences in crystallite size and phase content. The photocatalytic properties of the nanoparticles were tested for ethanol photodegradation, with H2 gas production observed in one series and CO2 evolution in the other.
BEILSTEIN JOURNAL OF NANOTECHNOLOGY
(2023)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)