Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 15, Pages 2569-2574Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600229
Keywords
chemoselective process; heterogeneous catalysis; recyclable catalyst; transesterification; zinc
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Funding
- Scientific Research on Innovative Area Middle molecular strategy and Platform for Drug Discovery, Informatics, and Structural Life Science from MEXT [2707]
- Grants-in-Aid for Scientific Research [15H05846, 16H01032, 15K14930, 16K08166] Funding Source: KAKEN
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We report the development of a universal and recyclable heterogeneous zinc/imidazole catalyst. The catalyst is recoverable through simple filtration and can be reused at least five times, retaining its catalytic activity. Leached zinc species were not responsible for the observed catalysis based on the hot filtration test and ICP-MS analysis. The heterogeneous zinc catalyst also promotes chemoselective transesterification over amidation.
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