Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 4, Pages 622-630Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500941
Keywords
carbon dioxide fixation; catalysis; convergent activation; cyclic carbonates; N-heterocyclic carbene
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Funding
- Federal Ministry of Research and Education (BMBF) [01 RC 1004 A]
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Concepts to facilitate the conversion of epoxides with carbon dioxide to the corresponding cyclic carbonates commonly focus on the activation of the epoxide. Herein we report a catalytic system which allows the simultaneous activation of carbon dioxide and the epoxide. This convergent activation concept is realized by combining a suitable carbene as catalyst for the carbon dioxide activation with a second catalytic system based on potassium iodide for epoxide activation. Initial experiments showed synergistic effects and thus proving the feasibility of this activation concept. Moreover a standard protocol was developed and the substrate scope under these conditions has been studied. Under mild and solvent-free conditions 14 epoxides could be converted. The respective cyclic carbonates were obtained in good to excellent yields with selectivities 99% after simple filtration.
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