4.8 Article

Facilitated Ion Transport in Smectic Ordered Ionic Liquid Crystals

Journal

ADVANCED MATERIALS
Volume 28, Issue 42, Pages 9301-9307

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201602702

Keywords

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Funding

  1. Fundamental RAMP
  2. D Program for Core Technology of Materials
  3. Industrial Strategic Technology Development Program - Ministry of Knowledge Economy, Republic of Korea
  4. Materials Architecturing Research Center of Korea Institute of Science and Technology (KIST)
  5. Disaster and Safety Management Institute - Ministry of Public Safety and Security of Korea government
  6. DOE BER

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A novel ionic mixture of an imidazolium-based room-temperature ionic liquid containing ethylene-oxide-functionalized phosphite anions is fabricated, which, when doped with lithium salt, self-assembles into a smectic-ordered ionic liquid crystal through Coulombic interactions between the ion species. Interestingly, the smectic order in the ionic-liquid-crystal ionogel facilitates ionic transport.

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