4.2 Article

Preparation of calcium manganese phosphate by mechanochemical synthesis of manganese and hydroxyapatite

Journal

JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY
Volume 55, Issue 3, Pages 807-815

Publisher

SPRINGER
DOI: 10.1007/s41779-018-00293-4

Keywords

Manganese-hydroxyapatite; Calcium manganese phosphate; High-energy ball milling

Ask authors/readers for more resources

Biocompatible hydroxyapatite (HA), with chemical formula Ca-5(PO4)(3)(OH), is widely used in dentistry and orthopedics. Inorganic additions of metal ions into HA structure can significantly influence physicochemical properties of HA-based ceramics. Calcium manganese phosphate (Ca19Mn2(PO4)(14)) was successfully synthesized by mechanochemical method where the manganese was added to HA with 5, 10, 15, and 20 wt%. The mechanochemical process was investigated by using Fourier-transform infrared spectrometer (FT-IR), X-ray diffraction (XRD), and differential thermal analysis (DTA). The compacted circular disc samples heat-treated at 1200 degrees C were also investigated using field emission scanning electron microscopy (FE-SEM) where fine agglomerates with small grain size were found. Sample densification improved with increasing sintering temperature. Calcium manganese phosphate (Ca19Mn2(PO4)(14)), beta-tricalcium phosphate (beta-Ca-3(PO4)(2)), and manganese oxide (Mn2O3) phases were formed and increases with increasing sintering temperature. The electrochemical behaviors and corrosion rate were investigated by potentiodynamic polarization, which confirms low corrosion rate that calculated by weight loss test of HA/Mn sample in Hank's solution. With increasing Mn content, Vicker's hardness and contact angle of the 1200-degrees C sintered materials decrease.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.2
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Synthesis of lead-borate glasses using high energy ball milling (attritor)

Ahmed E. Hannora

JOURNAL OF NON-CRYSTALLINE SOLIDS (2015)

Article Chemistry, Physical

Structure and compression strength of hydroxyapatite/titania nanocomposites formed by high energy ball milling

Ahmed E. Hannora, Sabbah Ataya

JOURNAL OF ALLOYS AND COMPOUNDS (2016)

Article Engineering, Electrical & Electronic

Correlation between grain size and transport properties of lead titanate based-glass-ceramic nano-composites

Amany E. Harby, Ahmed E. Hannora, M. S. Al-Assiri, M. M. El-Desoky

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2016)

Article Chemistry, Inorganic & Nuclear

Relaxor Ferroelectric-Like Behavior in Barium Titanate-Doped Glass via Formation of Polar Clusters

M. M. El-Desoky, A. E. Harby, Ahmed E. Hannora, M. S. Al-Assiri

JOURNAL OF CLUSTER SCIENCE (2017)

Article Chemistry, Physical

Observation of relaxor-like behavior in BT and PT doped glasses for energy storage applications

Amany E. Harby, Ahmed E. Hannora, M. M. El-Desoky

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

Article Engineering, Electrical & Electronic

Preparation of nanostructured manganites SmMnO3 and Sm0.5Sr0.5MnO3 by mechanochemical synthesis method

Ahmed E. Hannora, F. F. Hanna

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2019)

Article Engineering, Electrical & Electronic

Effects of heat treatment on the structural and electrical conductivity of Fe2O3-P2O5-PbO glasses

Ahmed E. Hannora, M. M. El-Desoky

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2019)

Article Materials Science, Multidisciplinary

Surface mechanical attrition treatment of commercially cold rolled copper plate

Ahmed E. Hannora

MATERIALS RESEARCH EXPRESS (2019)

Article Crystallography

Correlation between Nanostructural and Enhanced Electrical Conductivity of Annealed 30V2O5-20Bi2O3-50P2O5Glass

Ahmed Hannora, Mohamed El-Desoky

CRYSTAL RESEARCH AND TECHNOLOGY (2020)

Article Engineering, Electrical & Electronic

Annealing effects on the structural, thermal, and electrical properties of 10PbTiO3-10Fe2O3-30V2O5-50B2O3 glass

Ahmed E. Hannora, Marwa A. Abbas, M. M. El-Desoky

Summary: This study investigated the crystallization behavior and kinetic parameters of lead titanate glass, finding enhanced thermal stability and electrical conductivity after annealing. The increase in electrical conductivity was attributed to the small polaron hopping (SPH) mechanism.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Engineering, Electrical & Electronic

Relaxor ferroelectric-like behavior in 10PbTiO3-10Fe2O3-30V2O5-50B2O3 glass for energy storage applications

M. M. El-Desoky, N. K. Wally, A. M. Ali, Amany E. Harby, Ahmed E. Hannora

Summary: Demand for dielectric materials in energy storage devices at high voltage applications has increased recently. Appearance of polar clusters in glass matrix could promote its use in energy storage applications. The developed glass sample shows typical relaxor ferroelectrics like behavior, with a high energy storage density at room temperature.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Engineering, Electrical & Electronic

Structural, electrical and magnetic properties of perovskite La0.4Sr0.6MnO3 prepared by mechanochemical synthesis technique

Peter N. G. Ibrahim, Farid F. Hanna, Ahmed E. Hannora

Summary: Lanthanum strontium manganite with perovskite structure was successfully produced through mechanochemical synthesis. Annealing at higher temperatures leads to reduced lattice parameters and increased crystallite size. Room temperature superparamagnetic behavior was observed in annealed samples, along with a slight decrease in electrical resistance at room temperature.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2022)

Article Materials Science, Ceramics

Preparation and Characterization of Hydroxyapatite/Alumina Nanocomposites by High-Energy Vibratory Ball Milling

A. E. Hannora

JOURNAL OF CERAMIC SCIENCE AND TECHNOLOGY (2014)

Article Nanoscience & Nanotechnology

STRUCTURE AND MAGNETIC PROPERTIES OF MECHANICAL ALLOYED Mn-15at.% Al

Ahmed E. Hannora, Faried F. Hanna, Lotfy K. Marei

INTERNATIONAL JOURNAL OF NANOSCIENCE (2013)

No Data Available