Journal
CATALYSTS
Volume 8, Issue 12, Pages -Publisher
MDPI
DOI: 10.3390/catal8120644
Keywords
in situ catalysts; dispersed catalysts; hydroconversion; vacuum gas oil
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Funding
- Russian Science Foundation [17-73-30046]
- Russian Science Foundation [17-73-30046] Funding Source: Russian Science Foundation
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The nickel-tungsten sulfide catalysts for the hydroconversion of hydrocarbons were prepared from oil-soluble nickel and tungsten precursor compounds in situ with the use of silica, alumina, titania, zeolite Y, and amorphous aluminosilicate as additives in a vacuum gas oil medium. It was found that the catalytic activity in hydrocracking depends on the concentration of acid sites in the resulting catalyst. With the use of oxide additives, the dispersion and the promoter ratio of the in situ formed sulfide particles increased in the order SiO2-Al2O3-TiO2. It was noted that the promoter ratio of sulfide particles obtained with the use of aluminosilicate additives depended on their porous structure peculiarities. The use of titanium dioxide as a catalytic system component made it possible to reach high activity in hydrocracking, hydrodearomatization, and hydrodesulfurization, which was comparable to that of a system based on zeolite Y, a highly acidic component.
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