Article
Polymer Science
Muhammad Akram, Jiayan Shi, Hamad Khalid, Fei Zeng, Yanqing Tian
Summary: In this study, a new fluorinated oxygen probe monomer based on porphyrin was synthesized and copolymerized with other monomers to fabricate oxygen sensitive copolymers. Among the fabricated surfaces, nanofiber membrane showed the highest oxygen sensitivity and pressure sensitivity, with fast response to oxygen, making it a potential application in pressure mapping of biological systems and unsteady surfaces.
EUROPEAN POLYMER JOURNAL
(2023)
Article
Chemistry, Analytical
I Dalfen, T. Burger, C. Slugovc, S. M. Borisov, I Klimant
Summary: Optical oxygen sensors based on various immobilized oxygen indicators in microparticles were studied under high hydrostatic pressure, revealing that all porous materials remained stable under elevated pressure. While the actual oxygen concentration did not change with increasing pressure, the sensors showed a significant decrease in calculated oxygen concentration, which was reversible.
SENSORS AND ACTUATORS B-CHEMICAL
(2022)
Article
Nanoscience & Nanotechnology
Xu-dong Ying, Jian-xiang Chen, Dan-yu Tu, Yi-cao Zhuang, Di Wu, Liang Shen
Summary: The new Zn-MOF 1 exhibits excellent luminescence-quenching efficiency and sensing characteristics, showing fast response, high sensitivity, and specific selectivity in detection of 5-HT and 5-HIAA.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Taotao Li, Xinyi Li, Yu Zheng, Pan Zhu, Cheng Zhang, Kui Zhang, Jing-Juan Xu
Summary: In this study, long-lived luminescent materials were used to design a chemical sensing platform, which eliminates real-time excitation and background fluorescence. Phosphorescent carbon dots (CDs) were immobilized in a silica matrix (CDs@SiO2) to achieve afterglow emission in an aqueous dispersion. Through nonradiative energy transfer systems, multicolor afterglow emissions were successfully obtained in aqueous media. A ratiometric phosphorescent probe was designed using CDs@SiO2 as a donor and a Hg2+-responsive rhodamine derivative as an acceptor, enabling the sensitive detection of Hg2+ ions.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Jing Shi, Xiaozhan Yang, Hui Pan, Wenlin Feng
Summary: A new Tb-MOF based on terephthalic acid and thiophene-2,5-dicarboxylic acid was successfully synthesized, with bright green luminescence in aqueous solution. This Tb-MOF can be used as a sensor for trace Bi3+ detection in water.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Jashobanta Sahoo, Santlal Jaiswar, Pabitra B. Chatterjee, Palani S. Subramanian, Himanshu Sekhar Jena
Summary: The study focused on the selective interactions between three mononuclear lanthanide-based complexes and various anions in aqueous media, highlighting their excellent luminescence changes specifically with HPO42-. The complexes demonstrated high sensitivity and selectivity towards HPO42-, with complex 3 showing the most steady quenching of luminescence throughout the titration.
Article
Engineering, Environmental
Haotian Ma, Li Guan, Mingjun Chen, You Zhang, Yue Wu, Zhenyang Liu, Dawei Wang, Fenghe Wang, Xu Li
Summary: The utilization of biomass is an important approach to provide sustainable carbon sources for green chemistry. In this study, carbon quantum dots (MP-CQDs) were successfully synthesized using local fruit Mopan persimmons via the hydrothermal method. The MP-CQDs showed good structural and optical properties, with excitation-dependent behavior. They exhibited high selectivity towards Fe3+ ions and were successfully used in anti-counterfeiting applications.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Ceramics
Lixia Yang, Yating Fu, Weilun Cheng, Zhaofeng Chen, Di Peng, Xiaofeng Zhao, Zongde Kou
Summary: The incorporation of Bi3+ sensitizer had significant effects on the phosphorescence properties and oxygen partial pressure sensitivity of Eu3+ doped YSZ phosphors, enhancing phosphorescence intensity and oxygen sensitivity through mechanisms such as energy transfer and cross-relaxation. However, the impact of increasing Bi3+ concentration on oxygen sensitivity was found to be complex, with varying effects observed on different phosphorescence series.
CERAMICS INTERNATIONAL
(2022)
Article
Biochemistry & Molecular Biology
Yujia Jiang, Binbin Su, Honghui Chen, Tongtong Zhang, Haiping Liu, Yang Yu
Summary: By inserting the lanthanide binding tag (LBT) into the copper binding loop of Azurin protein, a new protein called Az-LBT with two metal bonding centers was created, showing strong luminescence upon coordination with Tb3+ and luminescence quenching upon Cu2+ binding, with high metal specificity and a detection limit of 0.65 μM for Cu2+.
BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS
(2021)
Article
Chemistry, Analytical
Linchun Zhang, Fanyuan Lin, Min Ye, Dongjie Tian, Jingwen Jin, Yipeng Huang, Yaqi Jiang, Yiru Wang, Xi Chen
Summary: The tetranuclear copper iodide hybrid material Cu4I4(PPh3)4 shows good oxygen sensing performance, with a wide linear range for both gaseous oxygen and dissolved oxygen. It exhibits excellent reversibility, rapid response, and water resistance, indicating promising prospects in oxygen sensing and potentially paving the way for new applications in the field.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Environmental Sciences
Ross N. Gillanders, James M. E. Glackin, Zdenka Babic, Mario Mustra, Mitar Simic, Nikola Kezic, Graham A. Turnbull, Janja Filipi
Summary: Utilizing honeybees to collect trace residues of explosives in mined areas, coupled with fluorescent polymer sensors for analysis, can achieve safe demining efficiently. Investigating potential false positive sources and estimating the mass of explosives returned to the colony using a model could help estimate the number of mines in a given area.
Article
Chemistry, Applied
Jianhua Guo, Wenjing Lu, Yating Meng, Huiping Wang, Chuan Dong, Shaomin Shuang
Summary: A convenient and cost-effective hydrothermal route was developed for the synthesis of red-emissive carbon dots (R-CDs) from neutral red and catechol. The R-CDs exhibited high photostability, outstanding biocompatibility, and desirable biological penetration, and could be used for monitoring quercetin and pH. The method enabled accurate testing of quercetin using a smartphone based laboratory device and color processing software, and could successfully quantify trace amounts of quercetin in various samples. The R-CDs also demonstrated a pH response and were capable of monitoring quercetin and pH in living cells.
Article
Chemistry, Inorganic & Nuclear
Juncheng Zhou, Yuhao Chen, Shuang Xian, Yicun Liang, Guojia Huang, Lian Wang, Xiaozhan Yang
Summary: Europium metal-organic frameworks (Eu-MOFs) synthesized by the solvothermal method exhibit a unique luminescence quenching effect towards nitrobenzene and copper ions, with high sensitivity and low detection limits, serving as potential sensing luminescence quenching probes for NB and Cu2+ ions.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Analytical
Yue Hu, Yu-Cong Fan, Xiao-Hui Jiang, Li-Mei Zhou, Zheng-Jun Cheng
Summary: A novel ratiometric fluorescent probe was established for sensitively and selectively monitoring proanthocyanidins by simultaneously regulating the photoluminescence of alloy Au/Ag nanoclusters and thiamine through MnO2 nanosheets. The RF-probe showed a linear range for detecting PAs concentrations with satisfactory results in real samples.
Article
Crystallography
Jing Ru, Yixuan Shi, Qiang Guo, Boxuan Hu, Leilei Li, Yanlan Wang, Chunlin Ma
Summary: Two new luminescent metal-organic frameworks (MOFs) have been synthesized via solvothermal conditions. The frameworks exhibit different structures and show fluorescence quenching response towards picric acid and 4-Nitrophenol, while they exhibit fluorescence turn-on response towards acetylacetone.
Article
Chemistry, Physical
A. Aathif Basha, Attar Kubaib, Mohammad Azam
Summary: The properties of a set of compounds were comprehensively assessed using various analytical techniques, revealing their stability and favorable drug-like characteristics. Potential antiviral and antioxidant properties were predicted, indicating promise for biological efficacy.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)
Article
Chemistry, Physical
Meiqi Liu, Baoming Hou, Yuheng Li, Yuyu Pan, Bing Yang
Summary: This paper investigates the application potential of thermally activated delayed fluorescent (TADF) molecules with donor-acceptor-donor-acceptor pi-conjugated macrocycle structures in organic light-emitting diodes. The study finds that the macrocyclic structure has a smaller energy gap between the first singlet excited state and the first triplet excited state compared to the linear structure. The TADF efficiency is also analyzed and explained based on spin-orbit coupling and intersystem crossing rates.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)
Article
Chemistry, Physical
Run Liu, Jiahui Liu, Jiarui Fang, Xiruo Bai, Dan Wang, Yixuan Qie, Shuqi Zu, Guancheng Wang, Xinyi Sui, Runyao Chang, Yizhu Wang, Ziheng Li
Summary: This paper investigates the remodeling effect of H2O molecules and their adsorption behavior on Co2+-doped SnO2 (221) crystal plane materials. The results show that H2O molecules remodel the crystal plane by creating oxygen defects, leading to hydroxylation. The hydroxylated crystal surface adsorbs O2 and then H2O molecules, affecting the electrical conductivity of the crystal plane.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)
Article
Chemistry, Physical
Marisol Ibarra-Rodriguez, Paul Horley, Mario Sanchez
Summary: In this study, the functionalized borophene was investigated as a potential sensor or transporter of glucose for biomedical applications. The adsorption of glucose molecules on different boron-based complexes was studied, and the results showed that these complexes have high binding energies and can efficiently adsorb glucose molecules. The findings suggest that borophene-based systems with different oxidation states hold promise for intelligent drug delivery and biosensor design.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)
Article
Chemistry, Physical
Syed Hassan Sarwar, Saad Jawaid Khan, Syed Faraz Jawed
Summary: The medical community is currently focusing on targeted and controlled drug delivery, and many researchers are utilizing computational resources to understand drugnanocarrier combinations and develop targeted drug delivery systems. This study used molecular dynamics to investigate the encapsulation capacity of Carbazochrome, a hemostatic drug, in Single-Walled Carbon Nanotubes of different morphological variations. The results showed that the nanotube radius and length had the most significant impact on the encapsulation capacity, followed by nanotube chirality. Temperature also affected the drug encapsulation when the nanotube radius was not very large and the chiral angle was near 30 degrees.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)
Article
Chemistry, Physical
Yinquan Sui, Mengying Sun, Yongxin Wang, Zhitong Xu, Jinglu Yan, Huanpeng Liu
Summary: In this study, the structural and hydrogen storage properties of loaded Pt atoms were investigated using density functional theory (DFT) with and without substitution of B atoms on the edges of conical graphene layers (CGL). It was found that the position of the substituted B atom at the edge of the CGL has an important effect on the position of the loaded Pt atom and its hydrogen adsorption and storage properties.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2024)