Coarsening behaviour and interfacial structure of γ′ precipitates in Co-Al-W based superalloys

This work discusses the effects of alloying on the coarsening behaviour of the L1(2) ordered gamma' phase and the structure of the gamma/gamma' interfaces in three Co-Al-W base superalloys aged at similar to 90 degrees C below the respective solvus temperatures: Co-7Al-7W, Co-10Al-5W-2Ta and Co-7Al-7W-20Ni (at.%). The coarsening kinetics are adequately characterised by the classical Lifshitz-Slyozov-Wagner model for Ostwald ripening. Co-7Al-7W exhibited much slower coarsening than its quaternary derivatives. Alloying can be exploited to modify the coarsening kinetics either by increasing the solvus temperature by adding tantalum, or by adding nickel to shift the rate controlling mechanism towards dependence on the diffusion of aluminium rather than tungsten. Lattice resolution STEM imaging was used to measure the widths of the order disorder (structural) and Z-contrast (compositional) gradients across the gamma/gamma' interfaces. Similarly to nickel base superalloys, the compositional gradient was found to be wider than the structural. Co-7Al-7W-20Ni had much wider interface gradients than Co-7Al-7W and Co-10Al-5W-2Ta, which suggests that its gamma' phase stoichiometry is less constrained. A possible correlation between temperature and misfit normalised r vs. t(1/3) coarsening rate coefficients and the structural gradient width has also been identified, whereby alloys with wider interfaces exhibit faster coarsening rates. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.