Variations and sources of nitrous acid (HONO) during a severe pollution episode in Beijing in winter 2016

HONO is an important precursor of OH radical and plays a key role in atmospheric chemistry, but its source and formation mechanism remain uncertain, especially during complex atmospheric pollution processes. In this study, HONO mixing ratios were measured by a custom-macle instrument during a severe pollution event from 16 to 23 December 2016, at an urban area of Beijing. The measurement was divided into three periods: I (haze), II (severe haze) and III (clean), according to the levels of PM25. This pollution episode was characterized by high levels of NO (75 +/- 39 and 94 +/- 40 ppbV during periods I and II, respectively) and HONO (up to 10.7 ppbV). During the nighttime, the average heterogeneous conversion frequency during the two haze periods were estimated to be 0.0058 and 0.0146 h(-1), and it was not the important way to form HONO. Vehicle emissions contributed 52% (+16)% and 40% (+/- 18)% to ambient HONO at nighttime during periods I and II. The contribution of homogeneous reaction of NO with OH should be reconsidered under high-NOx conditions and could be noticeable to HONO sources during this pollution event Furthermore, HONO was positively correlated with PM25 during periods I and II, suggesting a potential chemical link between HONO and haze particles. (C) 2018 Elsevier B.V. All rights reserved.