Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 63, Issue 12, Pages 1534-1540Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023618120173
Keywords
complex inorganic oxides; coprecipitation method; Pechini method; cathode material; electrochemical properties
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Funding
- Russian Science Foundation [17-03-01424]
- Russian Science Foundation [17-13-01424] Funding Source: Russian Science Foundation
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Layered Li-rich transition metal oxides are considered among the most promising cathode materials for high energy density lithium-ion batteries. It was studied how the method and conditions of synthesis of Li-rich oxides Li1.2Mn0.54Ni0.13Co0.13O2 affect their electrochemical properties. Coprecipitation methods and modified Pechini process were used. It was shown that it is necessary to carefully choose the synthesis conditions when using the modified Pechini method because of their significant effect on the morphology of Li-rich oxides. Samples were obtained with high electrochemical characteristics: capacity discharge of 260-270 mAh/g (16 mA/g) and 60-70 mAh/g (988 mA/g) within the voltage range of 2.5-4.8 V.
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