4.1 Article

Study of Organic Self-Assembled Nanosystems by Means of High-Frequency ESR/ENDOR: The Case of Oil Asphaltenes

Journal

RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 88, Issue 11, Pages 2374-2380

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363218110208

Keywords

complex self-assembled nanosystem; oil disperse system; asphaltene; vanadium porphyrin complexes; electron nuclear double resonance

Funding

  1. project 5-100 of the Program for Competitive Growth of Kazan Federal University

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An approach to investigate self-assembly of oil disperse systems based on high-field electron nuclear double resonance has been suggested. As exemplified by asphaltenes, the oil components most prone to self-assembly, the formation of planar rather than multilayer structures has been directly evidenced experimentally. The suggested method can be applied to elucidate the self-assembly mechanism in wide range of organic objects.

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