Article
Chemistry, Analytical
Qiu Zhuang, Cheng Zhang, Haiyan Zhuang, Hanyu Deng, Xiangpeng Lin, Yan Li, Hao Chen, Aming Xie, Wei Dong
Summary: A novel TPE-CMP fluorescence sensor has been developed for the high sensitivity detection of tetracycline. The sensor exhibits good linear correlation and excellent selectivity, and has practical feasibility in various samples such as milk, urine, and wastewater.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Physical
Tanushree Mishra, Subhajit Guria, Juheli Sadhukhan, Debojyoti Das, Manas Kumar Das, Susanta Sekhar Adhikari, Swapan Maity, Pralay Maiti
Summary: In this work, we have designed and synthesized a novel fluorescent chemosensor, NR-HG, based on a naphthalimide-based rhodamine platform for the detection of Hg2+ ions. The probe shows high selectivity and sensitivity towards Hg2+ ions, operating through PET, CHEF, and FRET mechanisms. DFT analysis confirms the experimental observations. Cell imaging experiments demonstrate the compatibility of the probe with living cells and its effectiveness in real-life imaging.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Chemistry, Analytical
Junyan Tang, Shuyi Yin, Xiaoya Liu, Zigui Kan, Xicheng Zhang, Mengnan Jiang, Feifei Tao, Fei Wang, Caolong Li
Summary: The study introduces an all-organic graphene/PTEB composite for rapid and direct photoelectrochemical analysis of multi-sulfhydryl compounds through a specific thiol-yne click reaction, showing high sensitivity and low detection limit. The non-covalent interaction between graphene and PTEB improves the optoelectronic properties of PTEB, enabling sensitive detection of thiols. A homemade sensing instrument has successfully achieved real-time monitoring of thiols, indicating its potential as an online sensor or a reaction monitor integrated into industrial production lines.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Spectroscopy
Ahmet Battal, Solomon Bezabeh Kassa, Nuray Altinolcek Gultekin, Mustafa Tavasli, Yavuz Onganer
Summary: In this study, probe L was tested as a colorimetric and ratiometric fluorescent probe for the detection of anions, cations, and neutral molecules. Probe L showed selectivity and sensitivity towards CN- ions and formed a new adduct through nucleophilic conjugate addition. This method demonstrated a low limit of detection and successful application in the detection of CN- in real-world water samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Chemistry, Multidisciplinary
Garion E. J. Hicks, Sheng Li, Nimrat K. Obhi, Charles N. Jarrett-Wilkins, Dwight S. Seferos
Summary: π-Conjugated polymers have unique properties that depend on their ordering, with programming techniques such as covalent and solution programming playing a key role in controlling their assembly. Progress in programming at different stages of material development highlights order-dependent features and unique assembly techniques for pi-conjugated polymers.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Analytical
Pramod Kumar Mehta, Hyojin Park, Eun-Taex Oh, Heon Joo Park, Keun-Hyeung Lee
Summary: In this study, a reversible fluorescent sensor was synthesized for the turn-on monitoring of Hg2+ in water, and a fluorescent sensing method was developed for the selective detection of CH3Hg+ over Hg2+. The sensor showed rapid response (<30 s), high sensitivity and/or selectivity, low detection limits (107 nM), and significant enhancement of fluorescence for CH3Hg+.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Materials Science, Multidisciplinary
Huadong Liu, Hewei Li, Kezhen Du, Haoxuan Xu
Summary: In this paper, yellow fluorescent carbon dots (Y-CDs) were successfully synthesized and used as sensing probes for the detection of Hg2+ ions. The Y-CDs exhibited excellent performance with high selectivity and low detection limit. Additionally, a portable fluorescence test paper was prepared based on Y-CDs, and the mechanism of fluorescence quenching was investigated by synthesizing Y-CDs@ZIF-8 composites.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Fan Xiao, Xiaofeng Fang, Hongyan Li, Hanbing Xue, Zixiang Wei, Wenkang Zhang, Yulin Zhu, Li Lin, Yan Zhao, Changfeng Wu, Leilei Tian
Summary: In this study, a new type of spherical nucleic acids (SNAs) was developed by using fluorescent pi-conjugated polymers (FCPs) as light-harvesting antennas to enhance signal transduction in nucleic acid detection. The hydrophobicity of the graft copolymer was adjusted to control the size and light-harvesting capability of the FCP-SNAs. The optimized FCP-SNA showed a 37-fold signal amplification effect and a limit of detection as low as 1.7 pM in microRNA detection. This method was successfully applied for amplified in situ nucleic acid detection and imaging at the single-cell level.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Spectroscopy
Qinghua Hu, Wenfeng Zhang, Qiang Yin, Yuyuan Wang, Hongqing Wang
Summary: A conjugated fluorescent polymer sensor P2 based on amidoxime groups and polyfluorene was designed and prepared for trace uranyl ion detection in an aqueous medium. The sensor showed good selectivity and sensitivity, with significant application potential for environmental uranyl ion detection.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Physical
Kodai Yamanaka, Masahiko Saito, Tomoyuki Koganezawa, Hayato Saito, Hyung Do Kim, Hideo Ohkita, Itaru Osaka
Summary: The crystallinity of pi-conjugated polymer donors and acceptors is crucial for improving the performance of organic photovoltaic cells. In state-of-the-art OPVs based on nonfullerene acceptors, pi-conjugated polymers with low crystallinity are typically used, yet they provide high efficiencies. This study investigates the blending of pi-conjugated polymers PTzBT and PTzBTE with different acceptor materials, revealing that the crystalline order of the blend films is closely correlated with the OPV performance.
ADVANCED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Maha Mohamed Samy, Mohamed Gamal Mohamed, Ahmed F. M. EL-Mahdy, Tharwat Hassan Mansoure, Kevin C-W Wu, Shiao-Wei Kuo
Summary: A series of conjugated microporous polymers were synthesized, with TBN-TPE-CMP showing high surface area and thermal stability. Blending with highly conductive single-walled carbon nanotubes improved the conductivity of the materials, with TBN-Py-CMP/SWCNT nanocomposite exhibiting high capacitance and excellent capacitance retention.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Energy & Fuels
Li Yang, Xiaoli Zhang, Jinbao Zhang
Summary: This paper discusses the importance of pi-conjugated polymer-functionalized semiconductor surfaces and the use of surface-confined monolayers of these polymers. The nanostructure of the monolayers is influenced by factors such as the type and position of anchor groups, polymer structure, and film-forming techniques. The applications of these monolayers in dye sensitized solar cells and polymer solar cells are summarized. Future research directions for improving the efficiency and assembly states of these monolayers are also discussed.
Article
Biochemistry & Molecular Biology
Die Wang, Luminita Marin, Xinjian Cheng
Summary: In this study, fluorescent small molecule BODIPY and chitosan-based polymer sensors were synthesized, which can effectively detect and quench Hg2+, Hg+, Fe3+, and Fe2+. These sensors also have the ability to remove heavy metal ions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Biochemistry & Molecular Biology
Lauriane Giraud, Stephane Grelier, Etienne Grau, Laurent Garel, Georges Hadziioannou, Brice Kauffmann, Eric Cloutet, Henri Cramail, Cyril Brochon
Summary: The synthesis of environmentally friendly pi-conjugated polymers is challenging. In this study, divanillin-based polyazomethines were synthesized using a potentially bio-based monomer. The polymerization process was achieved in 5 minutes with microwave irradiation and without any metallic catalyst, resulting in water as the only by-product. The structure and properties of the polyazomethines were characterized, and model compounds were used to confirm the E configuration and cross-conjugated nature of the divanillin-based polymers.
Article
Polymer Science
Wei Liu, Haibo Chen, Shifeng Zhang, Peng Li, Weibing Wu
Summary: This work synthesizes two novel fluorescent conjugated polymers with different conjugated structures and investigates their fluorescence sensing performance for 2,4,6-trinitrotoluene (TNT) in both liquid and gas phases. The films of these polymers demonstrate selective detection of gas-phase TNT within a short time, indicating their potential for rapid on-site detection of trace explosives.
MACROMOLECULAR CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Amit Sil, Sabyasachi Roy Chowdhury, Sabyashachi Mishra, Sanjib K. Patra
DALTON TRANSACTIONS
(2018)
Article
Chemistry, Inorganic & Nuclear
Sourav Saha Roy, Amit Sil, Dipanjan Giri, Sabyasachi Roy Chowdhury, Sabyashachi Mishra, Sanjib K. Patra
DALTON TRANSACTIONS
(2018)
Article
Chemistry, Inorganic & Nuclear
Apurba Maity, Amit Sil, Sanjib K. Patra
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2018)
Article
Polymer Science
Dipanjan Giri, Sk Najmul Islam, Sanjib K. Patra
Article
Chemistry, Inorganic & Nuclear
Amit Sil, Utsav Ghosh, Vipin Kumar Mishra, Sabyashachi Mishra, Sanjib K. Patra
INORGANIC CHEMISTRY
(2019)
Article
Chemistry, Inorganic & Nuclear
Sourav Saha Roy, Sanjib K. Patra
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Sourav Saha Roy, Sabyasachi Roy Chowdhury, Sabyashachi Mishra, Sanjib K. Patra
CHEMISTRY-AN ASIAN JOURNAL
(2020)
Article
Polymer Science
Dipanjan Giri, Sagar Kumar Raut, Chinmoy K. Behera, Sanjib K. Patra
Summary: This study presents a fluorescent pi-conjugated copolymer probe that selectively detects Fe3+ ions and shows high sensitivity and selectivity towards ATP. The charge interaction between the polymer and ATP is the main reason for the selective fluorescence enhancement, as revealed by photophysical and sensing studies.
Article
Chemistry, Multidisciplinary
Amit Sil, Sourav Saha Roy, Vipin Kumar Mishra, S. K. Najmul Islam, Sabyashachi Mishra, Sanjib K. Patra
Summary: This study designs and characterizes a series of wire-like binuclear Ru(II) complexes and investigates their electrochemical and spectroscopic properties. The results show that the electronic properties and absorption characteristics of the complexes can be controlled by varying the bridging moieties.
Article
Chemistry, Physical
Sanjukta Parida, Sanjib K. Patra, Sabyashachi Mishra
Summary: The pi-conjugated supramolecular polymers have gained popularity in materials chemistry and biomedicine due to their self-assembling behavior. This study provides a detailed account of the electronic structure and bonding through quantum theory and non-covalent interactions in oligomers of perylene, perylene diimide, and thionated-PDI. The analysis reveals the presence of electrostatic interactions playing a crucial role in the self-assembly process.
Article
Chemistry, Organic
Suman Bhatta, Bidyut Kumar Senapati, Sanjib Kumar Patra, Samik Nanda
Summary: An efficient sequential double-annulation strategy has been developed to synthesize a series of unsymmetrical acridines. This simple protocol enables the assembly of two aromatic rings from simple starting materials and shows a good substrate scope and functional group tolerance.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Amit Sil, Utsav Ghosh, Suman Dolai, Soumitra Manna, Apurba Maity, Sanjib K. Patra
Summary: A multifunctional push-pull arylene-vinylene conjugated terpyridine with tunable photophysical properties and remarkable chemosensing properties has been designed and developed.
MATERIALS ADVANCES
(2022)
Article
Chemistry, Multidisciplinary
Apurba Maity, Anirban Sarkar, Shivakiran B. N. Bhaktha, Sanjib K. Patra
NEW JOURNAL OF CHEMISTRY
(2020)
Article
Chemistry, Inorganic & Nuclear
Apurba Maity, Utsav Ghosh, Dipanjan Giri, Devdeep Mukherjee, Tapas Kumar Maiti, Sanjib K. Patra
DALTON TRANSACTIONS
(2019)
Article
Polymer Science
Yuanzhang Jiang, Xuyi Wang, Yanting Han, Dakai Gong, Yingchun Gu, Lin Tan
Summary: In this study, FeCl3 and poly(acrylic acid) (PAA) were doped into waterborne polyurethanes (WPUs) to create multifunctional materials with self-healing and antimicrobial properties. WPU/Fe/PAA-5.5, containing 5.5 wt % PAA, exhibited excellent mechanical properties, strong self-healing capabilities, and an impressive antimicrobial rate of over 90%. These supramolecular films were also highly recyclable through hot-pressing.
Article
Polymer Science
Longyu Tian, Min Wang, Guangming Liao, Baoliang Liu, Sujuan Zhang, Yucheng Sun, Zhen Meng, Jintao Zhang, Zaijun Lu
Summary: Two kinds of benzoxazine monomers were synthesized and used to prepare polybenzoxazine anion exchange membranes (AEMs) with quaternary ammonium functionalization. The LQPBZ AEM exhibited better ion conductivity and alkaline stability.
Article
Polymer Science
Claire A. Lemarchand
Summary: This study investigates the shock behavior of three different polymers through molecular dynamics simulations. The results reveal specificities in the shock behavior of polymers, including deviations from the linear relation between shock velocity and particle velocity, as well as differences in shear stress relaxation behind the shock front. It is found that the deviation of the Hugoniot locus is related to the change in the relative contribution of bonding and non-bonding potential energies, while polymers with higher glass transition temperatures exhibit slower shear stress relaxation.
Article
Polymer Science
Zengquan Liu, Xiaochun Yin, He Zhang, Shuo Gao, Qinglin Kuang, Yanhong Feng
Summary: A powder solid-state extension (PSSE) technology was proposed to address the high melt viscosity issue of UHMWPE. By uniaxial extension and sintering in the solid state, a highly self-reinforced material was prepared. X-ray diffraction and scattering techniques were used to study the structural evolution during the PSSE process, and a solid-phase induced transformation model was established.
Article
Polymer Science
Zhike Li, Anyu Luo, Rui Zhou, Xin Li, Haiyan Li
Summary: A novel high temperature resistance IL@SiO2 nanocapsules were successfully prepared and their friction and wear properties in PA6 composites were studied. The addition of IL@SiO2 nanocapsules reduced the friction coefficient and wear rate without affecting the mechanical properties of PA6. The synergy between the IL core and SiO2 wall in the nanocapsules improved the self-lubricating performance of the PA6 composites.
Article
Polymer Science
Xin Liu, Xuhong Guo, Qi Liao
Summary: In this study, an algorithm for accurately estimating viscosity is developed using molecular dynamics simulations and the Green-Kubo formula. This algorithm can be applied to complex systems with long correlations, such as macromolecular and biological simulation systems.
Article
Polymer Science
Hao Pu, Yun-Lei Hou, Jing -Zhou Chen, Dong -Lin Zhao
Summary: The use of modified graphene improves the interfacial adherence of carbon fibers to epoxy resin, resulting in enhanced interfacial and bending properties of CF and matrix in CF/EP composites, as well as increased interlaminar shear strength and flexural strength.
Article
Polymer Science
Wei-Chung Ke, Jin-Wei Lin, Manohar Reddy Busireddy, Yueh-Hsing Lee, Jiun-Tai Chen, Chain-Shu Hsu
Summary: This study introduces a crosslinkable monomer, TAIC, to synthesize three crosslinked polyimide films, which exhibit improved thermal, mechanical, and dielectric properties. The introduction of TAIC enhances the tensile strength, reduces the dielectric constant and dielectric loss, and decreases the coefficient of thermal expansion of the polyimide films.
Article
Polymer Science
Alex Kwasi Kumi, Ruiling Fan, Ye Chen, Yumei Zhang
Summary: The difference in leaching of amylopectin from cellulose/amylopectin/1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) blends during regeneration in water and aqueous ethanol has been studied. Molecular dynamics simulations showed that the dissolution and regeneration mechanisms of amylopectin in [Bmim][Cl] are similar to cellulose in ionic liquids. Water regeneration leads to weak electrostatic interactions, resulting in high leaching of amylopectin. In contrast, ethanol-water interactions enhance electrostatic interactions among amylopectin chains, limiting amylopectin leaching in aqueous ethanol.
Article
Polymer Science
Xi Zeng, Junwei Zhou, Junbiao Peng, Chunsheng Zhang, Danling Wang, Yihu Song, Qiang Zheng
Summary: This study utilizes an oligomer deep eutectic solvent (DES) based on polyethylene glycol to regulate the vulcanization kinetics of rubber. The results show that the DES can accelerate vulcanization at low temperatures without affecting the crosslinking density and Mullins effect.
Article
Polymer Science
Qianqian Yue, Yongfei Peng, Xingjian Liu, Aihua He, Huarong Nie
Summary: The addition of metal deactivators can effectively suppress the aging of TBIR, prolong its lifespan, and have no negative effects on its physical and processing properties. These research findings are of great importance for improving the stability and aging resistance of polymers.
Article
Polymer Science
J. Gomez-Caturla, J. Ivorra-Martinez, R. Tejada-Oliveros, V Moreno, D. Garcia-Garcia, R. Balart
Summary: This work focuses on the development of environmentally friendly PLA formulations by using different esters derived from geraniol as plasticizers. The results show that these esters have good compatibility with PLA, and they can effectively enhance the elongation and plasticity of PLA, reduce its glass transition temperature, and slightly improve its water absorption capabilities.
Article
Polymer Science
Dandan Li, Zhaohui Lu, Zhao Ke, Ke Xu, Fengna Dai, Youhai Yu, Guangtao Qian, Chunhai Chen
Summary: In this study, cross-linked PI aerogel membranes with low dielectric constant and high moisture resistance were prepared by co-polymerization and scraping coating technology. The incorporation of fluorinated blocks and benzimidazole ring structures resulted in novel PI aerogel membranes with fascinating dielectric properties and outstanding moisture resistance.
Article
Polymer Science
Zhaoyang Chu, Qing Zhang, Haihua Luo, Han Zhou, Fapei Zhang, Wei Chen, Wenhua Zhang
Summary: Multi-physical fields solution processing strategy is a universal and facile method for preparing various conjugated polymer films and high-performance devices. In this study, we employed a combined microfluidic flow and ultrasonication strategy (FU) for processing CP solutions, and found a pronounced synergetic effect in promoting the pre-ordering of chains in solution. The conformation order and anisotropy of the solution were revealed through various characterizations. A non-classical nucleation model for polymer crystallization in non-equilibrium solution processing was confirmed. The roles of microfluidic flow and ultrasonication in chain aggregation and crystallization were addressed through multi-physical simulations. Compared to pristine solutions, the FU strategy showed improved solution anisotropy and crystallization kinetics, resulting in higher crystallinity in films and increased mobilities in OFET devices. The FU processing strategy provides a universal approach for regulating chain conformation and aggregation in conjugated polymer solutions.