4.5 Article

Magnetic properties, thermal stabilities and microstructures of melt-spun Misch-Metal-Fe-B alloys

Journal

PHYSICA B-CONDENSED MATTER
Volume 567, Issue -, Pages 118-121

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2018.11.056

Keywords

Misch-metal; Magnetic properties; Thermal stability; MM-Fe-B

Funding

  1. National Natural Science Foundation of China [51661011, 51564037, 51671097]
  2. Postdoctoral Research Project of Jiangxi Province, China [2017KY12]
  3. start-up fund of Qingjiang Scholarship [3208600001]
  4. Ph.D. start-up foundation, Jiangxi University of Science and Technology [3401223239]

Ask authors/readers for more resources

The magnetic properties, thermal stabilities and microstructures of misch-metal (MM) alloys with nominal composition of MM2.0+xFe14B (x = 0-0.6) prepared using melt-spun technique are investigated. The XRD pattern showed that the ribbons consist of the MM2Fe14B main phase, alpha-Fe, Fe3B and ReFe7 phases. The coercivity of all ribbons enhances with increasing the content of MM, while the remanence gradually decreases. Interestingly, there is an increase in remanence of MM2.2Fe14B ribbon, which is attributed to the strong inter-granular exchange coupling effect. The Curie temperature of all the ribbons is around 546 K, which does not change with the content of MM. By the EDS analysis, we have clarified that the changes of the temperature stability are mainly related to the distribution of rare earth content in the main phase. This study shows that the magnetic properties of the alloys can be improved by optimizing the content of rare earth elements. The ribbons in the optimum condition exhibit a coercivity of 899 kA/m and a (BH)(max) of 116 kJ/m(3), which can be used to produce high cost performance MM-Fe-B magnets.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Physics, Applied

Giant exchange bias effect in all-3d-metal Ni38.8Co2.9Mn37.9Ti20.4 thin film

K. Liu, S. C. Ma, Z. S. Zhang, X. W. Zhao, B. Yang, D. H. Wang, S. Ur Rehman, Z. C. Zhong

APPLIED PHYSICS LETTERS (2020)

Article Engineering, Electrical & Electronic

Evolution of Microstructure, Magnetic Properties, and Thermal Stabilities of Isotropic Alnico Ribbons

Sajjad Ur Rehman, Qingzheng Jiang, Qiulan Tan, Kai Liu, Anwar ul Haq, Zhenchen Zhong

IEEE TRANSACTIONS ON MAGNETICS (2020)

Article Metallurgy & Metallurgical Engineering

Uneven Evolution of Microstructure, Magnetic Properties and Coercivity Mechanism of Mo-Substituted Nd-Ce-Fe-B Alloys

Li-Li Zhang, Jie Song, Sajjad Ur Rehman, Jia-Jie Li, Lei Wang, Mu-Nan Yang, Ren-Hui Liu, Qing-Zheng Jiang, Zhen-Chen Zhong

Summary: This study found that the addition of Mo can enhance the magnetic properties of designated alloys, mainly attributed to the synergistic impact of grain refinement, pinning effects, and microstructural homogenization.

ACTA METALLURGICA SINICA-ENGLISH LETTERS (2021)

Article Chemistry, Physical

Tailoring the microstructure, magnetic properties and interaction mechanisms of Alnico-Ta alloys by magnetic field treatment

Sajjad Ur Rehman, Chen Wei, Qingfang Huang, Qingzheng Jiang, Anwar ul Haq, Jun Wang, Zhenchen Zhong

Summary: Reducing the spatial dimensions of spinodally decomposed phases and introducing Ta element can enhance the magnetic properties of Alnico alloys. The addition of Ta improved the intrinsic coercivity of the alloy while maintaining nearly unchanged remanence. Scanning electron microscopy confirmed the unique structure of rod-like Fe-Co rich phase embedded in the matrix phase and the suppression effect of gamma-phase at grain boundaries and triple junctions.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Physics, Applied

Giant topological Hall effect around room temperature in noncollinear ferromagnet NdMn2Ge2 single crystal

Xianming Zheng, Xuanwei Zhao, Ji Qi, Xiaohua Luo, Shengcan Ma, Changcai Chen, Hai Zeng, Guang Yu, Nao Fang, Sajjad Ur Rehman, Weijun Ren, Bing Li, Zhenchen Zhong

Summary: This study reports the observation of a giant topological Hall effect in NdMn2Ge2 single crystal, which is attributed to the complex magnetic structure and noncollinear spin configuration of the compound. The results indicate that this material could be a promising candidate for spintronic applications at room temperature.

APPLIED PHYSICS LETTERS (2021)

Article Engineering, Electrical & Electronic

Hybrid Effect of Exchange Coupling in Ce-Pr-Nd-Fe-B SPSed Magnets by Adding Pr-Fe-B Alloys

Lei He, Jiajie Li, Xiaoqiang Yu, Sajjad Ur Rehman, Pengpeng Qu, Feifei Li, Yuting Hu, Qingfang Huang

Summary: The introduction of Pr-Fe-B alloys through the dual-alloy method significantly enhances the magnetic properties and thermal stability of Ce-Pr-Nd-Fe-B sintered magnets. Scanning electron microscopy analysis indicates that the addition of Pr-Fe-B alloys optimizes the microstructure and enhances the exchange coupling among grains of SPSed magnets.

IEEE TRANSACTIONS ON MAGNETICS (2021)

Article Chemistry, Physical

Structural and magnetic properties of multiferroic hexagonal Lu0.5(Sc1-xInx)0.5 FeO3 ceramics

Kai Yang, Yuan Yuan, Changcai Chen, Guang Yu, Xiaohua Luo, Shengcan Ma, Sajjad Ur Rehman, Zhenchen Zhong

Summary: In this study, we investigated the structural and magnetic properties of hexagonal Lu-0.5(Sc1xInx)(0.5)FeO3 ceramics synthesized by solid state reaction. With increasing In-substitution, the lattice parameters and c/a ratio increased, leading to higher magnetic anomaly temperatures. The results suggest a more complex magnetic order with potential for room temperature multiferroics in hexagonal RFeO3 systems.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Materials Science, Multidisciplinary

The diffusion behavior and striking coercivity enhancement by Dip-coating TbH3 powders in sintered NdFeB magnets

Renhui Liu, Pengpeng Qu, Toujun Zhou, WeiMao Pan, MianFu Li, Qingfang Huang, Zhenchen Zhong

Summary: Grain boundary diffusion of Tb can improve the microstructural and magnetic properties of NdFeB magnets. The rapid increase in coercivity after diffusion is mainly attributed to the formation of a Tb-rich shell around (PrNd)2Fe14B grains. The diffusion of Tb into the interior of the magnet plays a key role in enhancing coercivity.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2021)

Article Materials Science, Multidisciplinary

Large magnetocaloric effect and magnetoresistance in ErNi single crystal

Xuanwei Zhao, Xianming Zheng, Xiaohua Luo, Fei Gao, Hai Zeng, Guang Yu, Sajjad Ur Rehman, Changcai Chen, Shengcan Ma, Weijun Ren, Zhenchen Zhong

Summary: The magnetic properties, magnetocaloric effect, and magnetoresistance of ErNi single crystal have been investigated. The single crystal undergoes magnetic transitions at specific temperatures, showing potential for magnetic refrigeration at liquid-helium temperatures. Additionally, complex transport behavior is observed in the crystal.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Retaining the Curie temperature of Ce substituted Nd-Fe-B nano-ribbons by Alnico elements substitution

Sajjad Ur Rehman, Haihua Liu, Shuwei Zhong, Hui Liang, Renhui Liu, Qingzheng Jiang, Munan Yang, Zhenchen Zhong

Summary: By introducing Alnico elements into Nd-Ce-Fe-B alloys, this study effectively increased the Curie temperature and energy density of the magnetic alloy, which are comparable to Ce-free Nd-Fe-B melt spun alloys.

INTERMETALLICS (2022)

Article Chemistry, Physical

Tailoring the magnetic properties and microstructure of Alnico 8 magnets by various Ti contents and processing conditions

Sajjad Ur Rehman, Chen Wei, Ruibiao Zhang, Haihua Liu, Shaoxiong Li, Minglong Zhong, Munan Yang, Qingzheng Jiang, Jun Wang, Zhenchen Zhong

Summary: This paper investigates the development of spinodal structure in Alnico 8 alloys and its effects on magnetic properties. By varying the titanium content and using directional solidification, the magnetic properties of the magnets are significantly improved.

INTERMETALLICS (2022)

Article Physics, Applied

Magnetic Properties and Microstructural Modifications of Sm-Co-Hf Alloy Ribbons by B Addition

Minglong Zhong, Weicheng Xie, Sajjad Ur Rehman

Summary: Microstructure optimization is crucial for improving the magnetic properties of permanent magnetic materials. In this study, Hf-added Sm-Co alloys were fabricated and it was found that the addition of Hf can optimize the microstructure and magnetic properties. Among the alloys, SmCo6.8Hf0.2B0.4 ribbon exhibited the best magnetic properties, with high coercivity and low temperature coefficient.

JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM (2022)

Article Materials Science, Multidisciplinary

Honeycomb-like structured ZnFe2O4@C derived from ZnFe2O4@ZIF-8 for electromagnetic wave absorption

Fenglan Long, Lei Wang, Sajjad Ur Rehman, Jun Zhang, Shuqi Shen, Biyun Peng, Mengjia Wei, Wenmiao Zhang, Yifeng Hu, Gang Fu, Tongxiang Liang

Summary: ZnFe2O4@Zeolitic imidazolate framework-8 (ZIF-8) composites were prepared using Sol-Gel self-propagating combustion method and in situ growth method. The honeycomb-like structured ZnFe2O4@C composites obtained through carbonization at 800°C in Ar atmosphere exhibited enhanced electromagnetic wave absorption properties. The carbon content of the composites could be adjusted by the ZIF-8 coating. The composites with 5% and 10% ZIF-8 (wt%) showed excellent reflection loss values and wide effective absorption bandwidth in the frequency range of 7.6-11.3 GHz.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2023)

Article Chemistry, Physical

Improvement of corrosion resistance and research on corrosion mechanism after depositing Ni-Y2O3/Ni-graphene composite coatings on NdFeB magnets

Yaru Zou, Yaojun Lu, Sajjad Ur Rehman, Xuehui Zhang, Sangen Luo, Chaoxiang Jin, Zhenggang Zou, Bin Yang, Munan Yang

Summary: This study investigated the corrosion resistance of composite deposits of yttrium (III) oxide and graphene on a nickel coating, and revealed the mechanism behind the enhanced corrosion resistance. The deposition of the graphene composite reduced the surface roughness of the coating and significantly decreased the contact area between the coating and the medium. Additionally, the composite deposition led to grain refinement and improved the formation of the passivation film.

SURFACE INNOVATIONS (2022)

Article Chemistry, Physical

Optimization of microwave absorption properties of flaky FeSiAl magnetic alloy by surface modification

Lili Zhang, Wenmiao Zhang, Sajjad Ur Rehman, Shuqi Shen, Yongxian Liu, Fenglan Long, Hongzhang Du, Weiwei Dong, Yifeng Hu, Haiping Zou, Tongxiang Liang

Summary: The surface modified flaky FeSiAl magnetic microwave absorbing material was prepared by controlled oxidation heat treatment and was compounded with MOFs material. The dielectric polarization characteristics and the microwave loss mechanism for the heterogeneous structure are analyzed. The obtained MOFs@FeSiAl balances the electromagnetic wave attenuation ability and the impedance matching, thus achieving excellent microwave absorbing properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Physics, Condensed Matter

Electronic and optical properties of CdSe/ZnSe core/shell QDs within centered hydrogenic impurity and their tunability when subjected to an external electric field

A. Jbeli, N. Zeiri, N. Yahyaoui, P. Baser, M. Said

Summary: The electronic and optical properties of CdSe/ZnSe semiconductor core/shell quantum dots with hydrogenic donor impurity were investigated theoretically. The perturbation and variational methods were used to calculate the binding energy, photoionization cross-section, polarizability, and diamagnetic susceptibility of the excited impurity under various conditions. A significant stark shift in the binding energy was observed under the influence of an external electric field.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A computational study of alkali (Na, K, Cs) doped methylammonium lead iodide perovskite

Rahat Batool, Tariq Mahmood, Sajid Mahmood, Abdul Aziz Bhatti

Summary: This study investigates the effects of alkali metal doping (Na, K, Cs) on MAPbI3 through compositional engineering. The results show that doping Na, K, and Cs can improve the phase stability, thermodynamic stability, and optical absorption of MAPbI3.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Influence of Hubbard U correction on the structural, electronic and optical properties of Kesterite Cu2XSnS4 (X= Zn, Fe)

N. A. N. M. Nor, M. A. H. Razali, W. H. A. W. K. Annuar, N. N. Alam, F. N. Sazman, N. H. M. Zaki, A. S. Kamisan, A. I. Kamisan, M. H. Samat, A. M. M. Ali, O. H. Hassan, B. U. Haq, M. Z. A. Yahya, M. F. M. Taib

Summary: This study investigates the potential of quaternary chalcogenides semiconductors as thin film solar cell absorbers using density functional theory (DFT) and density functional theory plus Hubbard U (DFT + U) approach. The results show that by applying Hubbard U terms, the electronic band gaps can be accurately predicted, providing valuable insights for finding cost-effective new thin film solar cell materials.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A modified drop-casting technique for efficient lead-free, environment-friendly thin film CsBi3I10 perovskite solar cells

Ashwani Kumar, Anuj Kumar, Mohaseen S. Tamboli, Mohd Ubaidullah, J. Jayarubi, S. K. Tripathi

Summary: In this study, lead-based perovskite solar cells are replaced by bismuth-based perovskite cells to overcome their instability and toxicity. CsBi3I10 perovskite films are fabricated using a modified drop-casting process, and the effects of post-annealing temperature on the morphological, structural, and optical properties are investigated. The photovoltaic performance of the cells without a hole transport layer is also quantitatively evaluated.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Phase stability, elastic properties, and hardness of Ti1-xAlxN from first-principles calculations

Yang Gao, Shu-Ming Chen, Shuo Cao, Shang-Zhou Zhang, Philippe Djemia, Qing-Miao Hu

Summary: This study investigates the phase stability, elastic modulus, and hardness of ternary nitride Ti1-xAlxN. It is found that the hardness increases with the Al content x. The cubic B1 structure is more stable for x < about 0.75, while the hexagonal structure (B4) is more stable for x > about 0.75. The composition dependent hardness and phase decomposition contribute to the convex shaped hardness curve of Ti1-xAlxN.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Piezoelectric response enhancement of w-AlN by Hf (or Zr) and Sc co-alloying: A first principles study

Fengqi Wang, Qinyan Ye, Xulin He, Kun Luo, Xiaolong Ran, Xingping Zheng, Cheng Liao, Ru Li

Summary: This report uses rigorous calculations based on density functional theory to study the piezoelectric and elastic properties of wurtzite aluminum nitride (w-AlN) with single- and co-alloying by Hf (or Zr) and Sc. The research finds that the (HfSc)0.375Al0.625N and (ZrSc)0.375Al0.625N with stable wurtzite phase have a large piezoelectric coefficient d33 of 49.18 pC/N and 47.00 pC/N, respectively. However, the piezoelectric voltage constant g33 and electromechanical coupling constant k233 of HfAlN, ZrAlN, HfScAlN, and ZrScAlN are smaller than that of ScAlN, which is attributed to the large dielectric constant epsilon 33 of Hf (or Zr) alloying samples. Furthermore, the calculations of internal parameter u and bond angle alpha elucidate the brittle-to-ductile transformation in alloying w-AlN crystal structure. Electronic structure calculations show that the bandgap decreases almost linearly with the increase of alloying concentration, and the Hf (or Zr) alloying compounds become n-type semiconductors due to the existing high-charge states.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Ho6FeSb2: Potential magnetic refrigerant with improved magnetocaloric effect

S. R. Athul, K. Arun, S. Swathi, U. D. Remya, Andrea Dzubinska, Marian Reiffers, Nagalakshmi Ramamoorthi

Summary: The magnetic and magnetocaloric characteristics of Ho6FeSb2 have been studied. The compound exhibits two second-order ferromagnetic transitions, enabling hysteresis-free magnetocaloric effect across a wide temperature range. The alloy has high relative cooling power and magnetoresistance, making it suitable for hysteresis-free magnetocaloric applications.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Structural, dielectric and magnetic study of double perovskite La2CoMnO6

Reena Sharma, Neelam Hooda, Ashima Hooda, Satish Khasa

Summary: A polycrystalline double perovskite La2CoMnO6 sample was prepared and its structural, dielectric and magnetic properties were investigated. The sample exhibited complex structures and magnetic behavior, and showed good conductivity and dielectric performance. Its multi-domain magnetic structure suggests its suitability for memory device applications.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

DFT study of RhTiP half Heusler semiconductor: Revealing its mechanical, optoelectronic, and thermoelectric properties

Shubha Dubey, Jisha A. Abraham, Kumud Dubey, Vineet Sahu, Anchit Modi, G. Pagare, N. K. Gaur

Summary: This study investigates the optoelectronic, thermodynamic, thermoelectric, and mechanical stability properties of RhTiP Half Heusler semiconductors. The results show that RhTiP is a non-magnetic material with confirmed mechanical stability. It is found to be an indirect-bandgap semiconductor with a good Seebeck coefficient. This study suggests that RhTiP has promising applications in the thermoelectric and optoelectronic fields.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Designing vibrant and bright transmission colors with multilayer film structures

Xun Xie, Jiong-Ju Hao, Hong-Wei Yang

Summary: This work presents a multilayer film structure that uses optical resonance to prepare highly efficient and saturated red, green, and blue transmittance colors. Numerical simulations and analysis show that the structure can produce R, G, and B colors with a purity comparable to standard RGB colors, while maintaining efficient transmission efficiency and obtaining a rich variety of structural colors. Additionally, a metallic interlayer is introduced to selectively suppress resonances in the short-wavelength region, improving the purity of the red color. The study also investigates the effect of the incidence angle on color purity and transmission efficiency.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Prediction of binary mutual solubility via liquid-liquid interfacial tension

Yueqiang Zhao

Summary: Solubility property is of great interest in chemical, physical, pharmaceutical, material, and environmental sciences. Understanding the intrinsic reason behind solubility behavior is a fascinating task. The theoretical relation between binary mutual solubility and liquid-liquid interfacial tension has been derived, where the partitioning of solute molecules between two coexisting liquid phases is determined by the transfer free energy per unit segment for a chain-like solute molecule expressed in terms of solute-solvent interfacial tension. This general theory of solubility is in good agreement with experimental results for binary mutual solubility and molar transfer free energy of solute molecules.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Producing ZnO films that exhibited near-infrared (NIR) luminescence with a templated design procedure

Osama K. M. Bashiar, R. E. Kroon, H. C. Swart, R. A. Harris

Summary: ZnO thin films with near-infrared emission were successfully fabricated using pulsed laser deposition under vacuum conditions, without the need for additional gases or implantation methods. The NIR emission was hypothesized to be caused by defects in the ZnO film due to high energy particle impacts on the sample surface.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Influence of dielectric matrix stoichiometry on electrical and magnetoresistive properties of Fe-Zr-O nanocomposites

O. Stognei, A. Berezutskii, I. Anisimov, A. Deryabin

Summary: The influence of ZrOn matrix stoichiometry on the electrical and magnetoresistive properties of Fe-Zr-O nanocomposites has been studied. It was found that the magnetoresistive effect is not observed in composites with oxygen lack, while composites with oxygen excess show magnetoresistive effect and increased resistivity. Magnetoresistivity in composites with oxygen lack only appears after heat treatment. These results can be explained by the difference in the density of localized states in the oxide matrix of the composites and the ratio between two types of conductivity.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

A study about the relationships between surface structures and electrical impedance characteristics in single-walled carbon nanotube/ polyester composites

Mehmet Bayirli, Aykut Ilgaz, Orhan Zeybek

Summary: The present study aims to understand the relationship between impedance characteristics and fractal behaviors. By producing neat and carbon nanotube doped composite specimens, the researchers investigated the electrical properties and surface heteromorphology using Nyquist plots and fractal analysis.

PHYSICA B-CONDENSED MATTER (2024)

Article Physics, Condensed Matter

Enhancing perovskite solar cells: Tailoring the properties of Ti-doped MAPbBr3 for reduced recombination and improved efficiency

M. I. Khan, Saddam Hussain, Muhamad Saleem, Fatimah Mohammed Alzahrani, Muhammad Siddique, M. S. Hassan, Allah Ditta Khalid, Munawar Iqbal

Summary: The sol-gel method was used to deposit Ti-doped MAPbBr3 films on FTO-glass substrates with different doping ratios (0%, 4%, and 6%). XRD analysis confirmed the cubic structure of all films, and the 4% Ti-doped film exhibited a large grain size, low band gap energy, and high refractive index. Solar cells fabricated using the 4% Ti-doped MAPbBr3 film showed improved performance in terms of current density, open circuit voltage, fill factor, and efficiency.

PHYSICA B-CONDENSED MATTER (2024)