Journal
ORGANOMETALLICS
Volume 38, Issue 6, Pages 1361-1371Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00681
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Funding
- Austrian Science Fund (FWF) [P 30221]
- Christian Doppler Association (Austrian Federal Ministry for Digital and Economic Affairs)
- National Foundation for Research, Technology and Development
- OMV
- European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie Grant [745604]
- Deutsche Forschungsgemeinschaft [Wi1262/13-1]
- Marie Curie Actions (MSCA) [745604] Funding Source: Marie Curie Actions (MSCA)
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Thermal or photochemical metal-centered cycloaddition reactions of azidocobalto-cenium hexafluoridophosphate or azidoferrocene with (cyclooctadiene)(cyclopentadienyl)cobalt-(I) afforded the first metallocenyl-substituted tetrazene cyclopentadienyl cobalt complexes together with azocobaltocenium or azoferrocene as side products. The trimetallic CpCo compounds are highly conjugated, colored, and redox-active metallo-aromatic compounds, as shown by their spectroscopic, structural, and electrochemical properties. The CpCo-tetrazenido complex with two terminally appended cobaltocene units catalyzes electrochemical proton reduction from acetic acid at a mild overpotential (0.35 V). Replacing cobaltocene with ferrocene moieties rendered the complex inactive toward catalysis.
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