Journal
MOLECULES
Volume 23, Issue 12, Pages -Publisher
MDPI
DOI: 10.3390/molecules23123137
Keywords
dodecaborate; boron cluster; borane; amidine; amide; urea; isocyanate
Funding
- Natural Science Foundation of China [21472166]
- National Basic Research Program of China (973 project) [2015CB856500]
- Chinese 1000 Young Talents Plan
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The synthesis and structural characterization of new derivatives of [B12H12](2-) is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH3](-). Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
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