Phosphazene Bases as Organocatalysts for Ring-Opening Polymerization of Cyclic Esters

Organic Ring-Opening Polymerization Catalysts: Reactivity Control by Balancing Acidity

(2018) Binhong Lin et al.   MACROMOLECULES

Fast and Controlled Ring-Opening Polymerization of Cyclic Esters by Alkoxides and Cyclic Amides

(2018) Chen Tan et al.   MACROMOLECULES

Block Copolymers of Macrolactones/Small Lactones by a “Catalyst-Switch” Organocatalytic Strategy. Thermal Properties and Phase Behavior

(2018) Viko Ladelta et al.   MACROMOLECULES

Preparation of biorenewable poly(γ-butyrolactone)-b-poly(l-lactide) diblock copolyesters via one-pot sequential metal-free ring-opening polymerization

(2018) Yong Shen et al.   Polymer Chemistry

Stereoselective Ring-Opening Polymerization of rac-Lactide Using Organocatalytic Cyclic Trimeric Phosphazene Base

(2018) Shaofeng Liu et al.   ACS Macro Letters

Synthesis of polyesters by an efficient heterogeneous phosphazene (P1)-Porous Polymeric Aromatic Framework catalyzed-Ring Opening Polymerization of lactones

(2017) Marta Liras et al.   EUROPEAN POLYMER JOURNAL

Controlled random copolymerization of rac -lactide and ɛ -caprolactone by well-designed phenoxyimine Al complexes

(2017) Tong Shi et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Urea Anions: Simple, Fast, and Selective Catalysts for Ring-Opening Polymerizations

(2017) Binhong Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Nonstrained” γ-Butyrolactone-Based Copolyesters: Copolymerization Characteristics and Composition-Dependent (Thermal, Eutectic, Cocrystallization, and Degradation) Properties

(2017) Miao Hong et al.   MACROMOLECULES

Synthesis of dinuclear aluminum complexes bearing bis-phenolate ligand and application in ring-opening polymerization of ε-caprolactone

(2017) Jie Zhang et al.   NEW JOURNAL OF CHEMISTRY

Well-Designed Unsymmetrical Salphen-Al Complexes: Synthesis, Characterization, and Ring-Opening Polymerization Catalysis

(2017) Wenlong Luo et al.   ORGANOMETALLICS

Squaramide and amine binary H-bond organocatalysis in polymerizations of cyclic carbonates, lactones, and lactides

(2017) Jingjing Liu et al.   Polymer Chemistry

Ring-opening polymerization of ω-pentadecalactone catalyzed by phosphazene superbases

(2017) Viko Ladelta et al.   Polymer Chemistry

Synthesis of linear and star poly(ε-caprolactone) with controlled and high molecular weights via cyclic trimeric phosphazene base catalyzed ring-opening polymerization

(2017) Huaike Li et al.   Polymer Chemistry

Macromolecular architectures through organocatalysis

(2017) Shuangyan Hu et al.   PROGRESS IN POLYMER SCIENCE

Triclocarban: Commercial Antibacterial and Highly Effective H-Bond Donating Catalyst for Ring-Opening Polymerization

(2017) Nayanthara U. Dharmaratne et al.   ACS Macro Letters

Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters

(2017) Shaofeng Liu et al.   Polymers

Towards Truly Sustainable Polymers: A Metal-Free Recyclable Polyester from Biorenewable Non-Strained γ-Butyrolactone

(2016) Miao Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-to-Base Organocatalytic Approach for One-Pot Construction of Poly(ethylene oxide)-Based Macromolecular Structures

(2016) Yening Xia et al.   MACROMOLECULES

Fast and selective ring-opening polymerizations by alkoxides and thioureas

(2016) Xiangyi Zhang et al.   Nature Chemistry

Update and challenges in organo-mediated polymerization reactions

(2016) Winnie Nzahou Ottou et al.   PROGRESS IN POLYMER SCIENCE

Staudinger’s phosphazene as an efficient esterifying reagent

(2016) Murugan Dinesh et al.   SYNTHETIC COMMUNICATIONS

Bis- and Tris-Urea H-Bond Donors for Ring-Opening Polymerization: Unprecedented Activity and Control from an Organocatalyst

(2016) Kurt V. Fastnacht et al.   ACS Macro Letters

Synthesis of Polyurethanes Using Organocatalysis: A Perspective

(2015) Haritz Sardon et al.   MACROMOLECULES

Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone

(2015) Miao Hong et al.   Nature Chemistry

N-Heterocyclic carbenes as organocatalysts for polymerizations: trends and frontiers

(2015) Stefan Naumann et al.   Polymer Chemistry

Two C2-symmetric chelating P2-bisphosphazene superbases connected via a binaphthyl backbone – synthesis, structural features and preparation of a cationic alkyl aluminum complex

(2014) Julius F. Kögel et al.   CHEMICAL COMMUNICATIONS

Binaphthol-derived phosphoric acids as efficient chiral organocatalysts for the enantiomer-selective polymerization of rac-lactide

(2014) Kosuke Makiguchi et al.   CHEMICAL COMMUNICATIONS

A “Catalyst Switch” Strategy for the Sequential Metal-Free Polymerization of Epoxides and Cyclic Esters/Carbonate

(2014) Junpeng Zhao et al.   MACROMOLECULES

Organocatalytic Ring-Opening Polymerization of Cyclic Esters Mediated by Highly Active Bifunctional Iminophosphorane Catalysts

(2014) Anna M. Goldys et al.   MACROMOLECULES

High-speed organocatalytic polymerization of a renewable methylene butyrolactone by a phosphazene superbase

(2014) Meghan Schmitt et al.   Polymer Chemistry

Phosphazene-catalyzed ring-opening polymerization of ε-caprolactone: influence of solvents and initiators

(2014) Haleema Alamri et al.   Polymer Chemistry

Sequential polymerization of ethylene oxide, ε-caprolactone and l-lactide: a one-pot metal-free route to tri- and pentablock terpolymers

(2014) Junpeng Zhao et al.   Polymer Chemistry

Implementation of metal-free ring-opening polymerization in the preparation of aliphatic polycarbonate materials

(2014) Laetitia Mespouille et al.   PROGRESS IN POLYMER SCIENCE

Zwitterionic Ring-Opening Polymerization for the Synthesis of High Molecular Weight Cyclic Polymers

(2013) Hayley A. Brown et al.   ACCOUNTS OF CHEMICAL RESEARCH

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

(2013) Maréva Fèvre et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Electron-Rich Sterically Hindered P1Phosphazene Bases by the Staudinger Reaction

(2013) Anastasia V. Alexandrova et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich Reaction

(2013) Marta G. Núñez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Synthetic Pathway to the Second and Third Generation of Superbasic Bisphosphazene Proton Sponges: The Run for the Best Chelating Ligand for a Proton

(2013) Julius F. Kögel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization Using B(C6F5)3 as a Catalyst: Copolymerization of Vinyl Ethers and Isobutylene Oxide via Crossover Propagation Reactions

(2013) Arihiro Kanazawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphazene-promoted anionic polymerization

(2013) Junpeng Zhao et al.   POLIMERY

Recent progress in organocatalytic group transfer polymerization

(2013) Keita Fuchise et al.   Polymer Chemistry

One-step synthesis of hyperbranched biodegradable polymer

(2013) Hongjun Yang et al.   RSC Advances

Synthesis of Poly(ϵ-caprolactone-co-methacrylic acid) Copolymer via Phosphazene-Catalyzed Hybrid Copolymerization

(2012) Jinbao Xu et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Controlled ROP of β-Butyrolactone Simply Mediated by Amidine, Guanidine, and Phosphazene Organocatalysts

(2012) Cédric G. Jaffredo et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Hybrid Copolymerization of ε-Caprolactone and Methyl Methacrylate

(2012) Hongjun Yang et al.   MACROMOLECULES

Synthesis and enzymatic degradation of poly(ε-caprolactone-co-ethylene carbonate-co-ethylene oxide) copolymer

(2012) Manqing Yan et al.   POLYMER BULLETIN

Advanced chemical recycling of poly(ethylene terephthalate) through organocatalytic aminolysis

(2012) Kazuki Fukushima et al.   Polymer Chemistry

Organic Catalysis for Ring-Opening Polymerization

(2012) Andrew P. Dove   ACS Macro Letters

Controlled Anionic Graft Polymerization of Ethylene Oxide Directly from Poly(N-isopropylacrylamide)

(2011) Junpeng Zhao et al.   MACROMOLECULES

Core-First Synthesis of Three-, Four-, and Six-Armed Star-Shaped Poly(methyl methacrylate)s by Group Transfer Polymerization Using Phosphazene Base

(2011) Yougen Chen et al.   MACROMOLECULES

Nylon 3 synthesized by ring opening polymerization with a metal-free catalyst

(2011) Hongjun Yang et al.   Polymer Chemistry

Activation in anionic polymerization: Why phosphazene bases are very exciting promoters

(2011) S. Boileau et al.   PROGRESS IN POLYMER SCIENCE

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

(2010) Noureddine Ajellal et al.   DALTON TRANSACTIONS

Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

(2010) Joseph J. Bozell et al.   GREEN CHEMISTRY

High Molecular Weight Poly(α,α′,β-trisubstituted β-lactones) As Generated by Metal-Free Phosphazene Catalysts.

(2010) Julien De Winter et al.   MACROMOLECULES

Polycarbonates Derived from Green Acids: Ring-Opening Polymerization of Seven-Membered Cyclic Carbonates

(2010) Pierre Brignou et al.   MACROMOLECULES

Organocatalysis: Opportunities and Challenges for Polymer Synthesis

(2010) Matthew K. Kiesewetter et al.   MACROMOLECULES

The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts†

(2010) Manfred Bochmann   ORGANOMETALLICS

Metal-Free Activation in the Anionic Ring-Opening Polymerization of Cyclopropane Derivatives

(2009) Nicolas Illy et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Why δ-Valerolactone Polymerizes and γ-Butyrolactone Does Not

(2008) K. N. Houk et al.   JOURNAL OF ORGANIC CHEMISTRY

Ring-opening polymerization of decamethylcyclopentasiloxane initiated by a superbase: Kinetics and rheology

(2007) Guillaume Pibre et al.   POLYMER