4.0 Article

Effects of the Chain Length of Tris(carboxyalkylamino)triazine on Corrosion Inhibition Properties

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 36, Issue 1, Pages 346-355

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/bkcs.10090

Keywords

Acid solutions; EIS; Polarization; Interface; Corrosion

Funding

  1. R&D Center for Valuable Recycling (Global-Top Environmental Technology Development Program) - Ministry of Environment, Korea [GT-11-C-01-270-0]

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The corrosion behavior of mild steel was studied in 1 M HCl solution containing varying amounts of triazine derivatives having amine groups and alkyl carboxylic acid groups. The synthesized triazine derivatives were characterized by Fourier transform infrared (FT-IR) spectroscopy, NMR, mass spectroscopy, and elemental analysis (EA), and their corrosion inhibition properties were determined by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. We found that the triazine derivatives acted as mixed-type inhibitors by their adsorption on the metal surface. We also proposed that the Langmuir adsorption isotherm model could be used to explain the adsorption of triazine derivatives. In addition, when the alkyl chain length of the triazine derivative was relatively long, we also obtained a high-adsorption equilibrium constant and low Gibbs free energy of adsorption. Thus, we conclude that the alkyl chain length plays an important role in the corrosion inhibition properties of triazine derivatives.

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