Journal
INORGANIC CHEMISTRY
Volume 58, Issue 1, Pages 462-475Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b02681
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Funding
- China Scholarship Council
- French UT INSA
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Reactions in water of lanthanide chlorides with the sodium salt of 1,4-carboxyphenylboronic acid lead to two series of isostructural compounds with respective general chemical formulas [Ln(cpb)(3)(H2O)(2)](infinity) for Ln = La or Ce and [Ln(cpbOH)(H2O)(2)center dot(cpb)](infinity) for Ln = Pr-Lu (except Pm) plus Y. Heterolanthanide coordination polymers that are isostructural to the second series have been synthesized, and their photophysical properties have been studied. This study evidences that it is possible to design multiemissive lanthanide-based coordination polymers that could find their application as multigauge luminescent thermometric probes.
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