Journal
INORGANIC CHEMISTRY
Volume 57, Issue 24, Pages 15414-15420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b02712
Keywords
-
Categories
Funding
- NSFC/China [21571019]
- STCSM [16XD1401000]
- Program for Changjiang Scholars and Innovative Research Team in University
Ask authors/readers for more resources
A new discrete hexagonal metallacycle M containing tris-[2]pseudorotaxane moiety has been successfully designed and synthesized via coordination-driven self-assembly. The newly designed tris-[2]pseudorotaxane metallacycle was well characterized with nuclear magnetic resonance and mass spectra analysis. Such tris-[2]pseudorotaxane metallacycle M and pillar[5]arene dimer (PD) could further form a new family of cross-linked redox-responsive supramolecular polymer M superset of(PD)(3) through a host guest interaction. Interestingly, the polymer M superset of(PD)(3) displayed redox-responsive behavior and showed tuned weight-average diffusion coefficients D upon redox stimuli, which is attributed to the changed coordination geometries of [Cu(phen)(2)](+) and [Cu(phen)(2)](2+) in such system.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available