Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 43, Pages 5935-5941Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800775
Keywords
[2+2+2] Cyclotrimerization; Mo(CO)(6); O-Xylylene dibromide; Propargyl halides; Spirorhodanine
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Funding
- Department of Science and Technology (DST), New Delhi [EMR/2015/002053]
- Council of Scientific and Industrial Research (CSIR)-New Delhi
- Department of Science and Technology (DST) [SR/S2/JCB-33/2010]
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Spirocyclic compounds have been increasingly utilized in drug discovery due to their inherent three-dimensional structural complexity. Here, we report a diversity oriented approach to spirorhodanines via a [2+2+2] cyclotrimerization reaction with propargyl halides as co-partners. In another sequence, we employed o-xylylene dibromide as a coupling partner to assemble spirorhodanines.
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