Article
Chemistry, Multidisciplinary
Marika Turek, Robert Biczak, Barbara Pawlowska, Ewa Rozycka-Sokolowska, Krzysztof Owsianik, Bernard Marciniak, Piotr Balczewski
Summary: The use of optically active forms of commercial chiral herbicides may be more effective and environmentally safer. This study synthesized a series of chiral quaternary ammonium salts and investigated their selective toxicity towards aquatic bacteria and terrestrial plants. The results showed that these salts exhibited enantioselective toxicity towards all tested organisms.
Review
Biochemistry & Molecular Biology
Ana R. P. Goncalves, Xavier Paredes, A. F. Cristino, F. J. V. Santos, Carla S. G. P. Queiros
Summary: Ionic liquids were initially touted as environmentally friendly replacements for traditional solvents, but research on their interactions with organisms is lacking. Lipophilicity and the type of cation play key roles in toxicity.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Chemistry, Physical
Lei Yuan, Hongshuai Gao, Haiyan Jiang, Shaojuan Zeng, Tao Li, Baozeng Ren, Xiangping Zhang
Summary: A novel type of dual-functionalized pyridinium-based ionic liquids were designed and synthesized for ammonia absorption, showing high NH3 solubility and obvious chemical reaction characteristics, with reaction enthalpy as the main driving force for NH3 absorption.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Shahid Hussain, Haifeng Dong, Shaojuan Zeng, Muhammad Umair Ahmad, Farooq Khurum Shehzad, Hui Wu, Yanqiang Zhang
Summary: In this study, ionic liquids with good biodegradability and low viscosity were synthesized using ether functionalized pyridinium ion [E1Py] as cation and ions containing cyano groups as anions, showing enhanced CO2 absorption capacity with increased cyano groups in ionic liquids. The physiochemical properties of these synthesized ionic liquids were characterized, and the CO2 absorption was systematically studied, with thermodynamic properties such as enthalpy, entropy, and Gibbs free energy also calculated.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Dimitrios Skarpalezos, Andromachi Tzani, Elpida Avraam, Christos Politidis, Apostolos Kyritsis, Anastasia Detsi
Summary: This study presents the design, synthesis, and biodegradability assessment of 14 protic ionic liquids (PILs), with nine of them being newly introduced in the bibliography. The physicochemical properties, thermal behavior, and viscosity of two important PILs were studied, along with the discussion on how the structural features of PILs ions impact these properties.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Green & Sustainable Science & Technology
Sergio S. de Jesus, Rubens Maciel Filho
Summary: Ionic liquids are molten salts with excellent chemical and thermal stability, which have the potential to replace traditional organic solvents. However, their synthesis, toxicity, and biodegradability pose challenges to their environmentally friendly use. Analyzing the processes of synthesis, recovery and recycling, toxicity, and biodegradability reveals the need for further improvements in ionic liquid design to meet the principles of green chemistry.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2022)
Article
Environmental Sciences
Juan Jose Parajo, Pablo Vallet, Luis Miguel Varela, Maria Villanueva, Josefa Salgado
Summary: The study found that aprotic ILs are more toxic than protic ILs, and aromatic ILs are more toxic than non-aromatic ILs. Mixing inorganic salts with ILs, especially certain salts like Al(NO3)(3)center dot 9H(2)O, significantly increases toxicity levels.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Biswajit Bhattacharyya, Christian Balischewski, Eric Sperlich, Christina Guenter, Stefan Mies, Alexandra Kelling, Andreas Taubert
Summary: A new solid-state material, N-butyl pyridinium diiodido argentate(I), was synthesized through a simple and effective one-pot method. It exhibits 1D chains stabilized by the N-butyl pyridinium cation and forms needle-like crystals. With a low melting point of 100-101 degrees C, as confirmed by differential scanning calorimetry, the compound shows a conductivity of 10(-6) S cm(-1) at room temperature, which increases to 10(-4) S cm(-1) at 70 degrees C. Compared to AgI, the current material has a highly anisotropic 1D arrangement, providing a promising prototype for highly conductive solid-state conductors in battery or solar cell applications.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Chemistry, Physical
Salhah H. Alrefaee
Summary: Through DFT computational study, it was found that imidazolium and pyridinium based ionic liquids exhibit good anticorrosive potential, with corrosion inhibition performance depending on the nature of alkyl groups and halide ions. Among the studied ionic liquids, certain compounds were found to show the best corrosion inhibition performance in both imidazolium and pyridinium based categories.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Estefania Zuriaga, Laura Lomba, Cristina B. Garcia, Marta Sofia Valero
Summary: Nowadays, the scientific community is seeking and developing green solvents, derived from biomass, that can replace traditional solvents. A study was conducted to analyze the cytotoxicity of eleven biomass-derived solvents in terms of biochemical pathways and cell morphology. Results showed that most solvents in the furfural family exhibited higher toxicity, while other solvents also caused cellular damage and stress responses.
Article
Multidisciplinary Sciences
Esraa Abdelhamid Moneer, Basant A. Bakr, Sara H. Akl, Yahya H. Shahin, Bassma H. Elwakil, Mohamed Hagar, Keshav Raj Paudel, Ateyatallah Aljuhani, Mohamed Reda Aouad, Nadjet Rezki
Summary: Focused bis-pyridinium based-ionic liquids were synthesized and characterized using NMR-spectroscopic techniques. Compound 5 exhibited higher antiparasitic activity against Toxoplasma gondii compared to other compounds, showing potential as a replacement for the known drug pyrimethamine. Histopathological study also demonstrated the effectiveness of compound 5 on various tissues with better histological features compared to pyrimethamine treated group, suggesting a promising antiparasitic profile and fewer side effects.
Article
Chemistry, Multidisciplinary
Abdelrahman O. Ezzat, Hamad A. Al-Lohedan, Ayman M. Atta
Summary: This study focuses on the preparation of new green oilfield chemicals based on ionic liquids with enhanced demulsification efficiency. Through modifications of the chemical structure, a new amphiphilic molecule was synthesized, showing promising demulsification performance at low doses and temperatures.
Article
Biochemistry & Molecular Biology
Rabia Hassan, Farzana Nazir, Mah Roosh, Arshemah Qaisar, Uzma Habib, Abdulrahim A. Sajini, Mudassir Iqbal
Summary: Ionic liquids (ILs) have emerged as promising alternatives to existing antibiotics and antiseptics due to their excellent antibacterial activity. In this study, three series of ILs were synthesized using a green-chemistry-synthesis method, and their structures were confirmed through spectroscopic analysis. The ILs exhibited significant antibacterial activity against various pathogenic bacteria, with imidazolium cations and NTf2- and HSO4- anions showing the highest efficacy. In silico studies further demonstrated that these ILs can potentially be used as antibiotics.
Article
Biochemistry & Molecular Biology
Oscar Forero-Doria, Cristobal Parra-Cid, Whitney Venturini, Carolina Espinoza, Ramiro Araya-Maturana, Felipe Valenzuela-Riffo, Cesar Saldias, Angel Leiva, Yorley Duarte, Javier Echeverria, Luis Guzman
Summary: This study reports the synthesis, characterization, and antibacterial activity of three novel series of ionic liquids derived from benzoic and hydroxybenzoic acids. The minimum inhibitory concentration and antibiofilm activity were tested in various bacterial strains, showing promising results. The cell viability in HaCaT cells was also determined, indicating the potential of these ionic liquids as alternative treatments for SSTIs.
BIOORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
J. L. Viesca, P. Oulego, R. Gonzalez, H. Guo, A. Hernandez Battez, P. Iglesias
Summary: The study found that the six types of protic ionic liquids have certain biodegradability and toxicity, but their environmental properties are significantly better than industrial lubricant additives. Five of the PILs showed no corrosive activity on steel, with only one exhibiting partial miscibility in ester-based oil.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Materials Science, Multidisciplinary
Sergiy Rogalsky, Oksana Tarasyuk, Alina Vashchuk, Valeriy Davydenko, Oleg Dzhuzha, Sviatoslav Motrunich, Tetiana Cherniavska, Oleksii Papeikin, Larysa Bodachivska, Jean-Francois Bardeau
Summary: Tertiary fatty amide DBUA is a promising eco-friendly plasticizer for PVC, which can improve the elasticity and elongation at break of PVC films, as well as reduce the glass transition temperature of PVC. DBUA exhibits good plasticizing efficacy towards PVC, but has a negative impact on thermal stability and migration. In addition, DBUA also shows higher biodegradability.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Infectious Diseases
Larysa O. Metelytsia, Diana M. Hodyna, Ivan Semenyuta, Vasyl V. Kovalishyn, Sergiy P. Rogalsky, Kateryna Yu Derevianko, Volodymyr S. Brovarets, Igor Tetko
Summary: This study utilized a previously developed model to evaluate the antibacterial activity of phosphonium ionic liquids, and newly developed models to assess their antioxidant potential. Experimental results confirmed the activity of phosphonium ionic liquids against Acinetobacter baumannii and their significant antioxidant properties.
Article
Chemistry, Physical
Sergiy P. Rogalsky, Oksana P. Tarasyuk, Oleg Dzhuzha, Diana M. Hodyna, Tetiana Cherniavska, Anastasiia Hubina, Mykhailo M. Filonenko, Larysa O. Metelytsia
Summary: In this study, the tertiary fatty amide N,N-dibutyloleamide (DBOA) was synthesized and evaluated as a dual functional additive for PVC. The results showed that DBOA can lower the glass transition temperature of PVC, improve its elasticity, and exhibit good resistance to water leaching and antimicrobial activity.
COLLOID AND POLYMER SCIENCE
(2022)
Article
Polymer Science
Sergiy Rogalsky, Oksana Tarasyuk, Natalia Babkina, Stanislav Makhno, Olexandra Pertko, Volodymyr Povazhnyi, Tetiana Cherniavska, Kateryna Fatyeyeva
Summary: A new proton conducting membrane was developed by impregnation of porous polyimide Matrimid (R) (PI) with hydrophobic protic ionic liquid triethylammonium bis(trifluoromethylsulfonyl)imide (TEA-TFSI). The mechanical properties of the membrane were improved by impregnating it with the solution of polyetheramine Jeffamine (R) D-400 in the TEA-TFSI. The resulting partially cross-linked PI showed promising performance as a polymer electrolyte membrane for fuel cells operating at elevated temperatures in water-free conditions.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Multidisciplinary Sciences
Pavlo Lishchuk, Alina Vashchuk, Sergiy Rogalsky, Lesia Chepela, Mykola Borovyi, David Lacroix, Mykola Isaiev
Summary: This paper investigates thermal transport in a nanocomposite system consisting of a porous silicon matrix filled with ionic liquid. The thermal conductivity and heat capacity of two imidazolium and one ammonium ionic liquids were evaluated using the photoacoustic approach and differential scanning calorimetry, respectively. The results demonstrated a significant enhancement of the thermal conductivity of the composite system, providing new paths for innovative solutions in the field of thermal management.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
Sergiy Rogalsky, Oksana Tarasyuk, Alina Vashchuk, Oleg Dzhuzha, Tetiana Cherniavska, Stanislav Makhno
Summary: This research developed low-cost proton-conducting electrolytes for fuel cells operating at high temperatures by preparing two room temperature protic ionic liquids (PILs), IM-DBP and IM-BEHP. The synthesized PILs were optimized using density functional theory and showed hydrogen bonding between the cation and anion. Both PILs exhibited low glass transition temperatures, high thermal degradation points, and viscosity that decreased with increasing temperature. The ionic conductivity of the PILs reached the desired level above 140 degrees C. The obtained results suggest that imidazolium dialkyl phosphates can be used as proton conducting electrolytes for medium temperature fuel cell applications.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Viktoriia Talaniuk, Marcin Godzierz, Alina Vashchuk, Maksym Iurhenko, Pawel Chaber, Wanda Sikorska, Anastasiia Kobyliukh, Valeriy Demchenko, Sergiy Rogalsky, Urszula Szeluga, Grazyna Adamus
Summary: This study investigates the effect of welding process and modification of PHB with DBUA on the structure and properties of PHB-based biopolymer materials and the formation of welded joints using ultrasonic welding technique. The results show that DBUA acts as an effective plasticizer, reducing the crystallinity of the PHB/DBUA mixture and increasing the degree of crystallinity through ultrasonic welding. The welding treatment also affects the melt crystallization process of PHB.
Article
Biochemistry & Molecular Biology
Olena V. Moshynets, Taras P. Baranovskyi, Olga S. Iungin, Nadiia P. Kysil, Larysa O. Metelytsia, Ianina Pokholenko, Viktoria V. Potochilova, Geert Potters, Kateryna L. Rudnieva, Svitlana Y. Rymar, Ivan V. Semenyuta, Andrew J. Spiers, Oksana P. Tarasyuk, Sergiy P. Rogalsky
Summary: The choice of effective biocides for routine hospital practice should consider their impact on the local resistome and antibiotic resistance gene transfer. This study investigated the effects of different biocides on the release of extracellular DNA (eDNA) from biofilms of Pseudomonas aeruginosa and Staphylococcus aureus. The results showed that most biocides caused substantial eDNA release, while PHMG-Cl was able to block biofilm development and inactivate DNA on surfaces.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Applied
Diana Hodyna, Vasyl Kovalishyn, Ivan Semenyuta, Sergiy Rogalsky, Olena Trokhimenko, Anastasiia Gryniukova, Larysa Metelytsia
Summary: By developing a QSAR model, the cytotoxicity of Ionic liquids was successfully predicted, and potential anticancer compounds were identified and validated through biological testing.
BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY
(2022)