Article
Energy & Fuels
D. A. Mortari, D. Perondi, G. B. Rossi, J. L. Bonato, M. Godinho, F. M. Pereira
Summary: Water leaching pretreatment effectively removes water-soluble inorganic constituents from RGP and significantly impacts the combustion efficiency of WLGP chars, leading to lower burnout efficiency and increased gas emissions.
Article
Energy & Fuels
Xuecheng Tang, Qian Liu, Wenqi Zhong, Tao Wang
Summary: The combination of biomass and oxy-fuel combustion technology is regarded as a key technology for eliminating atmospheric emissions and achieving long-term decarbonization. However, problems such as ash deposition and corrosion caused by alkali metals in biomass have hindered its development. This study analyzed the deposits during biomass oxy-fuel combustion to understand the effects of different factors on ash deposition. It was found that coarse-grained fuels produced more complete inner layer of deposits, while fine-grained fuels increased the mass of deposits. Combustion temperatures below 800°C and higher oxygen fraction showed positive effects on reducing ash deposition.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Thermodynamics
Jiaye Zhang, Chongming Chen, Ao Zhou, Zia Ur Rahman, Xuebin Wang, Dragoslava Stojiljkovic, Nebojsa Manic, Milan Vujanovic, Houzhang Tan
Summary: This study investigated the pyrolysis behavior of coal at elevated pressure using a pressurized drop tube furnace, revealing that pressure, atmosphere, and coal rank significantly affect volatile releasing and char evolution.
Article
Thermodynamics
Prashik Manwatkar, Lekha Dhote, Ram Avtar Pandey, Anirban Middey, Sunil Kumar
Summary: The study investigated the co-combustion of coal with distillery sludge waste (DSW) in a laboratory-scale Drop Tube Furnace (DTF) plant. Preliminary testing methods were used to examine the feasibility of combustion and identify burnout efficiency, emitted pollutants, and metal constituents in the ash. The study showed a high degree of correlation between gaseous emissions, combustion efficiency, and the optimal sludge proportion in the DTF under given combustion conditions.
Article
Chemistry, Multidisciplinary
Alain Brillard, Patrick Gilot, Jean-Francois Brilhac, Valerie Tschamber
Summary: This study presents a simple model for simulating combustion processes in a drop tube furnace, which is much simpler than other available models. The model assumes that a coal char particle remains spherical during combustion and is based on two differential equations describing the evolution of particle temperature and oxygen concentration with respect to time. This model also provides access to local quantities to characterize the combustion process, and its validity is demonstrated through comparisons with experimental data.
APPLIED SCIENCES-BASEL
(2023)
Article
Energy & Fuels
Qian Li, Hengdi Ye, Zhihua Wang, Haoyu Zhou, Jinchao Wei
Summary: The drop tube furnace was used to investigate the characteristics of coal pyrolysis product, showing that pyrolysis could increase the specific surface area and total pore volume of coal, while producing syngas with high H2+CO content at high temperatures, suitable for synthetic chemical industry raw materials.
JOURNAL OF THE ENERGY INSTITUTE
(2021)
Article
Energy & Fuels
Christoph Schneider, Stella Walker, Aekjuthon Phounglamcheik, Kentaro Umeki, Thomas Kolb
Summary: This study investigates the thermal deactivation of beech wood chars during secondary pyrolysis, showing that the initial conversion rate Ro decreases linearly from 1000 degrees C to 1400 degrees C, but increases significantly at 1600 degrees C. Graphitization of the carbon matrix and CaO dispersion were also analyzed, indicating the formation of thin CaO layers at 1600 degrees C, which greatly affect the char reactivity.
Article
Thermodynamics
Changya Deng, Sui Boon Liaw, Hongwei Wu
Summary: This study analyzed the emission characteristics of leaf and wood biochar pyrolysis at 1300 degrees C in argon atmosphere, finding that the char yield and element retention were influenced by the chlorine content.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Chemistry, Analytical
Jinzheng Chen, Zhimin Lu, Jie Jian, Zhengyan Bao, Jianfeng Cai, Shunchun Yao
Summary: Torrefaction pretreatment significantly affects the physicochemical characteristics of pyrolyzed char from cellulose, xylan, and lignin in lignocellulosic biomass. The torrefaction temperature strongly influences the char's yields, oxidative reactivities, and physicochemical structure. The accumulated char yield and reactivity show different sensitivity to the torrefaction temperature depending on the constituents, with a decreasing deviation from 2.4 wt% to 0.6 wt% as the torrefaction temperature increases. Raman spectra demonstrate a strong correlation between the relative amount of small and large aromatic rings and the accumulated char yield of torrefied samples, with high determination coefficients for cellulose, xylan, and lignin.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Article
Polymer Science
Jiayu Yao, Jian Wang, Zhongzhou Zhang, Fei Chen, Yuhong Liu
Summary: Catalytic graphitization particles are widely used to improve the thermal stability and char yields of conventional phenolic resins. The direct addition of inorganic particles may cause phase separation and reduce the crosslinking density. In this study, a formaldehyde-free phenolic resin was synthesized using a non-hazardous dialdehyde, terephthalaldehyde (TPA). By co-curing ferrocenecarboxaldehyde (Fc) and the TPA resin, a high char yield modified resin was obtained with improved thermal properties due to the formation of a more ordered carbide structure.
Article
Thermodynamics
Biswajit Samal, Kumar Raja Vanapalli, Brajesh Kumar Dubey, Jayanta Bhattacharya, Subhash Chandra, Isha Medha
Summary: The potential of chars derived from the co-pyrolysis of waste polystyrene and eucalyptus biomass as a solid fuel was evaluated. Results showed that the quality and energy density of the char were optimal at specific temperatures and WPS content conditions. Additionally, the energy yield of the char was higher than the mass yield, and its properties were similar to certain types of coal.
Article
Energy & Fuels
Mattia Bartoli, Chengyong Zhu, Justice Asomaning, Michael Chae, David C. Bressler
Summary: This study tested the catalytic performance of a biosolids-based catalyst in a fuel solution containing sulphur compounds and sulphur-rich products. The biosolids-based catalyst showed superior performance at low temperature and remained recyclable after multiple uses.
Article
Energy & Fuels
Xiaojun Ning, Wang Liang, Guangwei Wang, Runsheng Xu, Peng Wang, Jianliang Zhang, Xingmin Guo, Chunhe Jiang, Jinhua Li, Chuan Wang
Summary: This research investigates the impact of pyrolysis temperature on the metallurgical properties of biochar and provides a theoretical reference for preparing biochar suitable for blast furnace injection. By analyzing the physical and chemical properties of biochar, the study reveals that higher pyrolysis temperature improves the fuel performance of biochar, increases carbonization degree, and weakens combustion performance and reactivity. Additionally, the application of the Coats-Redfern kinetic equation in fitting the combustion process of biochar has yielded favorable results.
Article
Environmental Sciences
Lolita Cueva Zepeda, Gregory Griffin, Kalpit Shah, Suresh Bhargava, Rajarathinam Parthasarathy
Summary: This study examines the properties of biochar-based slurry as an alternative to coal-water slurries. The results show that the physicochemical composition of biochar and particle-particle interactions significantly affect the stability, rheology, and heating value of the slurry. Additionally, different particle size distributions have an impact on these properties.
ENVIRONMENTAL RESEARCH
(2023)
Article
Energy & Fuels
Hassan Mohanna, Jean-Michel Commandre, Bruno Piriou, Benoit Taupin, Gilles Vaitilingom, David Honore
Summary: Experimental combustion and numerical modeling of raw and torrefied pine and demolition wood particles were conducted to determine the kinetics of devolatilization and oxidation. Different scenarios tested showed minor variations in devolatilization activation energy but significant differences in char oxidation activation energy. The influence of particle volume evolution and drag force models on the derived kinetic parameters were examined, revealing noticeable differences in particle temperature and other properties along the reactor axis.
Article
Thermodynamics
Xujun Chen, Hongwei Wu
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2019)
Article
Thermodynamics
Chao Feng, Hongwei Wu
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2019)
Article
Thermodynamics
Hongwei Wu, Yi Li
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2019)
Article
Thermodynamics
Xujun Chen, Sui Boon Liaw, Hongwei Wu
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2019)
Article
Energy & Fuels
Changya Deng, Sui Boon Liaw, Hongwei Wu
Article
Energy & Fuels
Song Zhou, Tahereh Hosseini, Jie Zhao, Xiwang Zhang, Hongwei Wu, Lian Zhang
Article
Energy & Fuels
Bing Song, Yun Yu, Hongwei Wu
Review
Agricultural Engineering
Samreen Hameed, Abhishek Sharma, Vishnu Pareek, Hongwei Wu, Yun Yu
BIOMASS & BIOENERGY
(2019)
Article
Energy & Fuels
Qiqing Shen, Sui Boon Liaw, Mario Costa, Hongwei Wu
Article
Thermodynamics
Jinxiu Cao, Sui Boon Liaw, Yu Long, Yun Yu, Hongwei Wu
Summary: This study aims to understand the fundamental reaction mechanisms during fast pyrolysis of acid-impregnated cellulose, showing how different temperatures affect the formation of key compounds in the reaction intermediates and primary volatiles. The results indicate that acid impregnation reduces the onset reaction temperature of cellulose pyrolysis, leading to the production of different major products at varying temperatures. The study also suggests that condensation reactions play an important role during acid-catalysed cellulose pyrolysis, with char formation becoming the favored pathway at higher temperatures.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Thermodynamics
Sui Boon Liaw, Hongwei Wu
Summary: Laboratory-scale experiments on PF combustion are usually conducted in droptube furnaces, investigating the effect of flue gas cooling conditions on PM10 properties from biomass combustion. The study found that cooling rate and biomass feeding rate have significant impacts on particle size and composition, showing different trends in particle diameter and component distribution.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Energy & Fuels
Qiqing Shen, Sui Boon Liaw, Hongwei Wu
Summary: Rapid pyrolysis of mallee and pine wood particles was conducted in a drop-tube furnace to investigate char yield, evolution of AAEM species, and char particle morphology. The results showed that char yield decreased with particle residence time, and mallee wood exhibited stronger resistance to deformation compared to pine wood due to the maintenance of its original elongated shape.