Article
Chemistry, Inorganic & Nuclear
[Anonymous]
Summary: This article reviews the recent advances in the synthesis and applications of ferrocene-fused nitrogen heterocycles. The transfer of powerful transition-metal-catalyzed methodologies for C-H bond functionalization of benzene derivatives to ferrocene has played a significant role in this field.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Milica Feldt, Quan Manh Phung
Summary: The reaction profiles of a non-heme iron(IV)-oxo biomimetic catalyst were studied using different levels of theory. The accurate calculation of spin-state energetics was found to be challenging for these methods.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Anil Chandra, Saumya Prasad, Helena Iuele, Francesco Colella, Riccardo Rizzo, Eliana D'Amone, Giuseppe Gigli, Loretta L. del Mercato
Summary: The optical fluorescent pH sensors based on positively charged silica microparticles containing anionic pyranine molecules were developed using a modified Stober method, ensuring overly pH-sensitive nature of pyranine and long-term stability through silica shell coating. These cytocompatible ratiometric pH sensors can be individually observed and are suitable for pH sensing and tracking applications.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Harry Biller, Swantje Lerch, Katharina Tolke, Hans-Georg Stammler, Berthold Hoge, Thomas Strassner
Summary: New tunable aryl alkyl ionic liquids (TAAILs) based on imidazolium containing weakly coordinating anion [Ga(C2F5)(4)](-) were investigated for their viscosity, conductivity, and electrochemical stability. The gallate-TAAILs showed stability even at high electrochemical potentials and are considered promising candidates for electrolytes in electrochemical applications. More details can be found in the communication by B. Hoge, T. Strassner, et al. (DOI: 10.1002/chem.202102097).
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Organic
Anna-Lena Leistner, Zbigniew L. Pianowski
Summary: The Cover Feature showcases stimuli-responsive materials triggered with visible light, utilizing molecular photoswitches that can reversibly change their molecular properties upon illumination and elicit macroscopic light-triggered effects. Applications span from solar energy conversion to biocompatible drug-releasing compositions.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Organic
[Anonymous]
Summary: The article presents the structure and synthesis method of a hybrid catalytic material based on multiwalled carbon nanotubes. The material exhibits excellent catalytic activity in the Heck reaction.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Peter Arendas, Attila G. Csaszar
Summary: An alternative combinatorial expression for the Wigner numbers is presented, leading to a generating function and new identities. The introduction of an extended class of Wigner numbers of the lth order is also mentioned.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
S. Yang, Y. Hou
Summary: Ultraviolet ozone flushing (UVO) is used to oxidize the NiOx hole-transport layer, activating the Ni3+ at the top of the NiOx film and enhancing its electrical properties and hole extraction ability. Sequential deposition of perovskites leads to the formation of residual PbI2 at the bottom interface, preventing direct contact between the NiOx film and the perovskite layer and avoiding NiOx-related chemical reactions.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Hanbin Hu, Yixin Yang, Xiao Jiang, Jiaxin Wang, Dongwei Cao, Lei He, Wei Chen, Yu-Fei Song
Summary: The double-shelled hollow PMo12-SiO2@N-C anode material achieves excellent lithium storage, with the N-C outer shell improving electronic conductivity and promoting dispersion of PMo12 clusters, and the SiO2 inner shell efficiently avoiding loss of active components. The hollow structure helps buffer volume expansion and accelerate Li+ diffusion during lithiation/delithiation.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Samuel Suarez-Pantiga, Pablo Redero, Xaiza Aniban, Martin Simon, Christopher Golz, Ricardo A. Mata, Manuel Alcarazo
Summary: This study presents the synthesis of in-fjord substituted expanded helicenes and estimates their inversion barriers through state-of-the-art quantum calculations. The energetic profile of the inversions is found to be significantly influenced by the interplay of steric and attractive London dispersion interactions. More details can be found in the Full Paper by R. A. Mata, M. Alcarazo, et al. (DOI: 10.1002/chem.202102585).
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
[Anonymous]
Summary: This article introduces the versatility of a copper complex and its reactions with hydrogen peroxide and superoxide, as well as the catalytic oxidation activity towards phenol.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Organic
Ranjan Jana
Summary: This article discusses the importance of converting waste CO2 into value-added products under global decarbonization policies, as well as the modern development of carboxylation reactions using photo- and electrocatalysis.
ASIAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Area Studies
Ming-Sho Ho
Summary: The protests in Hong Kong led to a global wave of activism among overseas Hongkongers, even after the decline of the protest movement in the city. This article examines the pro-democracy campaign of the diaspora, which surpassed previous waves of mobilization and evolved into a global resistance against China's authoritarian expansion. However, efforts to localize their agenda in host countries were hindered by political polarization in Western democracies.
JOURNAL OF CONTEMPORARY ASIA
(2023)
Article
Education, Scientific Disciplines
Yasmim R. Jaconiano, Juliana S. Goulart, Jose C. Barros, Ricardo C. Michel
Summary: This work connects the subjects of periodic table and photochemistry by making periodic tables out of fluorescent jellies, allowing undergraduate students to discuss concepts of photophysics and photochemistry, as well as 3D-printing process and gelification, without the need for expensive reagents or equipment.
JOURNAL OF FOOD SCIENCE EDUCATION
(2021)
Editorial Material
Education, Scientific Disciplines
Mike Bracko
Summary: Nassen et al recommend a different hockey skating technique called 'angular momentum skating', but fail to provide concrete evidence that this technique offers benefits for players. Their suggestion lacks proof or certainty, with no objective support for the idea that angular momentum skating can make hockey players faster or more efficient skaters.
EUROPEAN JOURNAL OF PHYSICS
(2021)